Alternatived Products of [ 84796-70-3 ]
Product Details of [ 84796-70-3 ]
CAS No. : | 84796-70-3 |
MDL No. : | MFCD14525506 |
Formula : |
C9H9F3
|
Boiling Point : |
- |
Linear Structure Formula : | - |
InChI Key : | - |
M.W : |
174.16
|
Pubchem ID : | - |
Synonyms : |
|
Safety of [ 84796-70-3 ]
Signal Word: | |
Class: | |
Precautionary Statements: | |
UN#: | |
Hazard Statements: | |
Packing Group: | |
Application In Synthesis of [ 84796-70-3 ]
* All experimental methods are cited from the reference, please refer to the original source for details. We do not guarantee the accuracy of the content in the reference.
- Upstream synthesis route of [ 84796-70-3 ]
- Downstream synthetic route of [ 84796-70-3 ]
- 1
-
[ 41818-96-6 ]
-
[ 84796-70-3 ]
-
[ 80245-28-9 ]
-
[ 78164-31-5 ]
Yield | Reaction Conditions | Operation in experiment |
|
In acetonitrile for 1.33333h; Irradiation; |
|
- 2
-
[ 445-01-2 ]
-
[ 676-58-4 ]
-
4,4'-dichloro-3,3'-bis-trifluoromethyl-biphenyl
[ No CAS ]
-
[ 98-08-8 ]
-
[ 84796-70-3 ]
-
[ 80245-27-8 ]
- 3
-
[ 84796-70-3 ]
-
[ 1483-47-2 ]
- 4
-
[ 106-42-3 ]
-
[ 2926-30-9 ]
-
[ 84796-70-3 ]
Yield | Reaction Conditions | Operation in experiment |
17% |
With C46H91N3O4; dimethylglyoxal In ethyl acetate at 20℃; for 24h; Irradiation; |
4.3.2. General Procedure for Intragel Reactions and Product Analysis
General procedure: An oven-dried 5 mL vial was loaded with sodium triflate (62.4 mg, 0.4 mmol), the desired arene(0.1 mmol) and G-1 gelator (25.0 g L1). The vial was equipped with a septum through which EtOAc(0.8 mL) and diacetyl (0.2 mL) were added with a syringe. The resulting mixture was homogenizedin an ultrasonic bath (USC200TH, 45 kHz, 120 Watt, VWR, Leicestershire, England) at constanttemperature (23 2 C) for ca. 1 min and heated with a heat gun (heating level 3 of 10) until the gelatorwas completely dissolved. The gel was formed during sonication or after cooling down the mixtureto RT. Then, the vials were placed under LED (l = 400 nm or 455 nm, as indicated) light irradiationduring the specified time (vide infra). Subsequently, the vials were heated up with a heat gun (heatinglevel 3 of 10) until dissolution of the gel phase. At this point, EtOAc (1.0 mL) and hexafluorobenzene(11.6 L, 0.1 mmol, NMR internal standard) were added into the hot solution and 5 drops of the crudesolution were taken out for NMR analysis. Notes: (1) Reactions using different gelators, light source,gelator concentration and/or reactants concentration were performed following the same procedureusing the amounts given in the main text. (2) Gelator G-3 required 5 min sonication for complete dissolution in the reaction mixture, and gelation occurred during this process. |