Product Details of [ 91004-40-9 ]
CAS No. : | 91004-40-9 | MDL No. : | |
Formula : | C9H9NO4 | Boiling Point : | - |
Linear Structure Formula : | - | InChI Key : | - |
M.W : | 195.17 | Pubchem ID : | - |
Synonyms : |
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Computed Properties of [ 91004-40-9 ]
TPSA :Topological Polar Surface Area |
- |
H-Bond Acceptor Count : |
- |
XLogP3 : |
- |
H-Bond Donor Count : |
- |
SP3 : |
- |
Rotatable Bond Count : |
- |
Safety of [ 91004-40-9 ]
Signal Word: | | Class | |
Precautionary Statements: | | UN#: | |
Hazard Statements: | | Packing Group: | |
Application In Synthesis of [ 91004-40-9 ]
- Downstream synthetic route of [ 91004-40-9 ]
- 2
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[ 91004-40-9 ]

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[ 100-46-9 ]

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[ 142071-84-9 ]
- 3
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[ 5781-53-3 ]

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[ 95-55-6 ]

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[ 91004-40-9 ]
Yield | Reaction Conditions | Operation in experiment |
1.2 g |
With triethylamine; In N,N-dimethyl-formamide; for 0.166667h;Cooling with ice; |
A mixture of 2.25 g of methyl chloroglyoxylate and5 ml of DMF was added dropwise to a mixture of 2.0 g of2-aminophenol, 2.23 g of triethylamine, and 20 ml of DMF under ice cooling, followed by stirring for 10 minutes. Water and 1 M hydrochloric acid were added thereto, and the precipitated solids were collected by filtration. The obtained solids were washed with water and dried under reduced pressure, thereby obtaining 1.2 g of methyl 2-[(2-hydroxyphenyl) amino] -2-oxo-acetate.11217] ?H-NMR (DMSO-D5) oe: 10.24 (s, 1H), 9.62 (br s,1H), 7.95-7.92 (m, 1H), 7.05-7.00 (m, 1H), 6.94-6.90 (m,1H), 6.86-6.80 (m, 1H), 3.85 (s, 3H) |