Alternatived Products of [ 92739-63-4 ]
Product Details of [ 92739-63-4 ]
CAS No. : | 92739-63-4 |
MDL No. : | MFCD09039048 |
Formula : |
C44H38Cl4N8
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Boiling Point : |
- |
Linear Structure Formula : | - |
InChI Key : | QAJDBICYDICFCM-UHFFFAOYSA-K |
M.W : |
820.64
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Pubchem ID : | 135509775 |
Synonyms : |
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Application In Synthesis of [ 92739-63-4 ]
* All experimental methods are cited from the reference, please refer to the original source for details. We do not guarantee the accuracy of the content in the reference.
- Downstream synthetic route of [ 92739-63-4 ]
- 1
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[ 36951-72-1 ]
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[ 92739-63-4 ]
Yield | Reaction Conditions | Operation in experiment |
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With Dowex 1*8-100 anionite (Cl form) In water column; |
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With Dowex 1X2-200 |
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Reference:
[1]Blinova, I. A.; Vasil'ev, V. V.
[Russian Journal of Physical Chemistry, 1995, vol. 69, # 6, p. 995 - 999][Zhurnal Fizicheskoi Khimii, 1995, vol. 69, # 6, p. 1097 - 1101]
[2]Location in patent: experimental part
Mosinger, Jii; Slavtinska, Lenka; Lang, Kamil; Coufal, Pavel; Kubat, Pavel
[Organic and Biomolecular Chemistry, 2009, vol. 7, # 18, p. 3797 - 3804]
- 2
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[ 92739-63-4 ]
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5,10,15,20-tetrakis(1-methylpyridinium-4-yl)porphyrin[6] tetrakis(hexafluorophosphate)
[ No CAS ]
Yield | Reaction Conditions | Operation in experiment |
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With ammonium hexafluorophosphate In water; acetonitrile |
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- 3
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[ 16834-13-2 ]
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[ 74-88-4 ]
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[ 92739-63-4 ]
Yield | Reaction Conditions | Operation in experiment |
82% |
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Methyl iodide (2mL, 32.11mmol) was added to a solution of 5,10,15,20-tetrakis-(4-pyridyl)porphyrin (500mg, 0.80mmol) in N-methylpyrrolidinone (100mL). The resulting solution was stirred at 40C for 12h. Reaction mixtures were then allowed to cool to room temperature and were treated with diethyl ether (300mL). The supernatant was decanted and the precipitate was washed three more times with diethyl ether and the supernatant was decanted each time. The solid was dissolved in water and the resulting solution was treated with 10% aqueous NH4PF6 (5mL). The solid was recovered by centrifugation, dissolved in acetone and treated with 10% tetrabutylammonium chloride in acetone (2mL). The precipitate was collected by centrifugation and crystallised from methanol and diethyl ether to yield the desired compound (855mg, 82%). Spectroscopic data were in agreement with the data reported in the literature. |
- 4
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[ 92739-63-4 ]
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5,10,15,20-tetrakis(1-methylpyridinium-4-yl)porphyrin-Fe(III) pentachloride
[ No CAS ]
Yield | Reaction Conditions | Operation in experiment |
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With iron(II) chloride for 2h; Heating; |
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- 5
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[ 92739-63-4 ]
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[ 7585-39-9 ]
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C42H70O35*C44H38N8(4+)*4Cl(1-)
[ No CAS ]
Yield | Reaction Conditions | Operation in experiment |
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In water |
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- 6
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[ 92739-63-4 ]
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[ 55216-11-0 ]
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C44H38N8(4+)*C63H112O35*4Cl(1-)
[ No CAS ]
Yield | Reaction Conditions | Operation in experiment |
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In water |
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- 7
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[ 74-87-3 ]
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[ 16834-13-2 ]
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[ 92739-63-4 ]
Yield | Reaction Conditions | Operation in experiment |
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As shown in Scheme E2, pyrrole, pyridine-4-carbaldehyde and salicylic acid are refluxed in xylene to give porphyrin E2-a. E2-a is further reacted with MeCl to afford E2- b. E2-b is reacted with diethyl aluminum chloride and then with five equivalents ofNaCo(CO)4 in THF to afford the active Al(III)-salen catalyst E2-d. |
- 8
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[ 92739-63-4 ]
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[ 96-10-6 ]
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C44H36AlClN8(4+)*4Cl(1-)
[ No CAS ]
Yield | Reaction Conditions | Operation in experiment |
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2
As shown in Scheme E2, pyrrole, pyridine-4-carbaldehyde and salicylic acid are refluxed in xylene to give porphyrin E2-a. E2-a is further reacted with MeCl to afford E2- b. E2-b is reacted with diethyl aluminum chloride and then with five equivalents ofNaCo(CO)4 in THF to afford the active Al(III)-salen catalyst E2-d. |
- 9
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[ 92739-63-4 ]
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[ 39050-26-5 ]
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meso-tetrakis(4-N-methylpyridinio)porphine meso-tetrakis(4-sulfonatophenyl)porphine
[ No CAS ]
Yield | Reaction Conditions | Operation in experiment |
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In methanol at 20℃; for 1h; |
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- 10
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[ 92739-63-4 ]
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[ 5970-45-6 ]
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5,10,15,20-tetrakis-(N-methylpyridinium-4-yl)porphyrinato zinc(II) tetrachloride
[ No CAS ]
Yield | Reaction Conditions | Operation in experiment |
84% |
In water at 20℃; |
5,10,15,20-tetrakis-(N-methylpyridinium-4-yl)porphyrinato zinc(II) tetrachloride (3).
A solution of 1 (208mg, 0.25mmol) in water (240mL) was treated with Zn(OAc)22H2O (280mg, 1.27mmol) at room temperature. The mixture was stirred at room temperature until complete conversion was achieved (monitored by UV-visible spectroscopy and MS spectrometry). It was then diluted with water (80mL) and treated with 10% aqueous NH4PF6 (2mL). The solid was recovered by centrifugation, dissolved in acetone (30mL) and treated with 10% tetrabutylammonium chloride in acetone (2mL). The precipitate was collected by centrifugation and crystallised from methanol and diethyl ether to yield the desired compound (188mg, 84%). Spectroscopic data were in agreement with data reported in the literature [37]. ESI-MS+: [M-4Cl]4+/4, 185.03 |
Reference:
[1]Giuntini, Francesca; Foglietta, Federica; Marucco, Arianna M.; Troia, Adriano; Dezhkunov, Nikolai V.; Pozzoli, Alessandro; Durando, Gianni; Fenoglio, Ivana; Serpe, Loredana; Canaparo, Roberto
[Free Radical Biology and Medicine, 2018, vol. 121, p. 190 - 201]
Yield | Reaction Conditions | Operation in experiment |
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With potassium chloride |
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