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[ CAS No. 952182-25-1 ] {[proInfo.proName]}

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3d Animation Molecule Structure of 952182-25-1
Chemical Structure| 952182-25-1
Chemical Structure| 952182-25-1
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Product Details of [ 952182-25-1 ]

CAS No. :952182-25-1 MDL No. :MFCD09841653
Formula : C7H6F3NO2 Boiling Point : -
Linear Structure Formula :- InChI Key :PQFWTUPLKUNQPO-UHFFFAOYSA-N
M.W : 193.12 Pubchem ID :45073280
Synonyms :

Safety of [ 952182-25-1 ]

Signal Word:Warning Class:N/A
Precautionary Statements:P261-P264-P270-P271-P280-P301+P312-P302+P352-P304+P340-P305+P351+P338-P330-P332+P313-P337+P313-P362-P403+P233-P405-P501 UN#:N/A
Hazard Statements:H302-H315-H319-H335 Packing Group:N/A
GHS Pictogram:

Application In Synthesis of [ 952182-25-1 ]

* All experimental methods are cited from the reference, please refer to the original source for details. We do not guarantee the accuracy of the content in the reference.

  • Downstream synthetic route of [ 952182-25-1 ]

[ 952182-25-1 ] Synthesis Path-Downstream   1~1

  • 1
  • [ 1193-62-0 ]
  • [ 2314-97-8 ]
  • [ 952182-25-1 ]
YieldReaction ConditionsOperation in experiment
80% With tris(bipyridine)ruthenium(II) dichloride hexahydrate; N,N,N,N,-tetramethylethylenediamine; In acetonitrile; at 20℃;Inert atmosphere; General experimental procedure An oven-dried resealable test tube equipped with a magnetic stir bar was charged with a heterocycle (0.3 mmol) and Ru(bpy)3Cl2·6H2O (1 mol%, 0.003 mmol), and sealed with a screw-cap. Acetonitrile (1.2 mL, 0.25 M) and N,N,N,N-tetramethylethylenediamine (0.6 mmol) were added to it under argon. CF3I (0.9 mmol-1.2 mmol) was then bubbled into the reaction mixture by using a gastight syringe. The test tube was placed under 24 W household light bulb or blue LEDs at room temperature. The reaction was allowed to proceed for 10-24 h while its progress was checked by TLC. The reaction mixture was then diluted with diethylether, filtered through a plug of silica gel to remove all solids, concentrated in vacuo, and purified by flash column chromatography to give the trifluoromethylated compound. An oven-dried resealable test tube equipped with a magnetic stir bar was charged with a heterocycle (0.3 mmol) and Ru(bpy)3Cl2·6H2O (1 mol%, 0.003 mmol), and sealed with a screw-cap. Acetonitrile (1.2 mL, 0.25 M) and N,N,N,N-tetramethylethylenediamine (0.6 mmol) were added to it under argon. CF3I (0.9 mmol-1.2 mmol) was then bubbled into the reaction mixture by using a gastight syringe. The test tube was placed under 24 W household light bulb or blue LEDs at room temperature. The reaction was allowed to proceed for 10-24 h while its progress was checked by TLC. The reaction mixture was then diluted with diethylether, filtered through a plug of silica gel to remove all solids, concentrated in vacuo, and purified by flash column chromatography to give the trifluoromethylated compound.
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