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[ CAS No. 99-68-3 ]

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3d Animation Molecule Structure of 99-68-3
Chemical Structure| 99-68-3
Chemical Structure| 99-68-3
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Product Details of [ 99-68-3 ]

CAS No. :99-68-3 MDL No. :MFCD00002720
Formula : C6H8O6S Boiling Point : -
Linear Structure Formula :- InChI Key :N/A
M.W :208.19 g/mol Pubchem ID :-
Synonyms :

Safety of [ 99-68-3 ]

Signal Word:Warning Class:
Precautionary Statements:P261-P280-P301+P312-P302+P352-P305+P351+P338 UN#:
Hazard Statements:H302-H315-H319-H335 Packing Group:
GHS Pictogram:

Application In Synthesis of [ 99-68-3 ]

* All experimental methods are cited from the reference, please refer to the original source for details. We do not guarantee the accuracy of the content in the reference.

  • Downstream synthetic route of [ 99-68-3 ]

[ 99-68-3 ] Synthesis Path-Downstream   1~24

  • 2
  • [ 71-23-8 ]
  • [ 99-68-3 ]
  • propoxycarbonylmethylsulfanyl-succinic acid dipropyl ester [ No CAS ]
YieldReaction ConditionsOperation in experiment
With sulfuric acid; benzene unter Entfernen des entstehenden Wassers;
  • 3
  • [ 99-68-3 ]
  • [ 64-17-5 ]
  • ethoxycarbonylmethylsulfanyl-succinic acid diethyl ester [ No CAS ]
YieldReaction ConditionsOperation in experiment
With toluene in Gegenwart eines sauren Katalysators;
With benzene in Gegenwart eines sauren Katalysators;
  • 4
  • [ 99-68-3 ]
  • [ 104-76-7 ]
  • [ 103398-98-7 ]
YieldReaction ConditionsOperation in experiment
With sodium hydrogen sulfate; benzene unter Entfernen des entstehenden Wassers;
  • 5
  • [ 99-68-3 ]
  • [ 78-83-1 ]
  • isobutoxycarbonylmethylsulfanyl-succinic acid diisobutyl ester [ No CAS ]
YieldReaction ConditionsOperation in experiment
With sodium hydrogen sulfate; benzene unter Entfernen des entstehenden Wassers;
  • 6
  • [ 99-68-3 ]
  • [ 97-95-0 ]
  • (2-ethyl-butoxycarbonylmethylsulfanyl)-succinic acid bis-(2-ethyl-butyl ester) [ No CAS ]
YieldReaction ConditionsOperation in experiment
With sodium hydrogen sulfate; benzene unter Entfernen des entstehenden Wassers;
  • 8
  • [ 99-68-3 ]
  • [ 100-44-7 ]
  • furan-2,3,5(4H)-trione pyridine (1:1) [ No CAS ]
  • [ 103-46-8 ]
  • [ 110-17-8 ]
YieldReaction ConditionsOperation in experiment
at 70℃;
  • 9
  • [ 68-11-1 ]
  • [ 110-16-7 ]
  • [ 99-68-3 ]
YieldReaction ConditionsOperation in experiment
With water
  • 10
  • [ 644-87-1 ]
  • [ 79-11-8 ]
  • [ 99-68-3 ]
YieldReaction ConditionsOperation in experiment
With alkali levorotatory form;
  • 11
  • [ 99-68-3 ]
  • [ 71-36-3 ]
  • butoxycarbonylmethylsulfanyl-succinic acid dibutyl ester [ No CAS ]
YieldReaction ConditionsOperation in experiment
With toluene in Gegenwart eines sauren Katalysators;
With benzene in Gegenwart eines sauren Katalysators;
With hydrogenchloride In water at 90℃; for 2h;
  • 12
  • [ 99-68-3 ]
  • [ 111-27-3 ]
  • [ 102809-05-2 ]
YieldReaction ConditionsOperation in experiment
With sodium hydrogen sulfate; benzene unter Entfernen des entstehenden Wassers;
  • 13
  • [ 3261-85-6 ]
  • [ 99-68-3 ]
YieldReaction ConditionsOperation in experiment
(hydrolysis);
  • 14
  • [ 92371-99-8 ]
  • [ 99-68-3 ]
YieldReaction ConditionsOperation in experiment
(i) KOH, EtOH, (ii) aq. H2SO4, Et2O; Multistep reaction;
  • 15
  • [ 99-68-3 ]
  • [ 644-87-1 ]
  • [ 64-19-7 ]
YieldReaction ConditionsOperation in experiment
In water examination of further solvents; electrolysis;
YieldReaction ConditionsOperation in experiment
at 90℃; Geschwindigkeit der Racemisierung; levorotatory form;
YieldReaction ConditionsOperation in experiment
at 90℃; Geschwindigkeit der Racemisierung; levorotatory form;
YieldReaction ConditionsOperation in experiment
at 90℃; Geschwindigkeit der Racemisierung; levorotatory form;
  • 20
  • [ 79-11-8 ]
  • [ 99-68-3 ]
YieldReaction ConditionsOperation in experiment
With sodium hydroxide
  • 21
  • rhodium(III) chloride trihydrate [ No CAS ]
  • [ 99-68-3 ]
  • Rh(3+)*(C6H5O6S)(3-)*3Cl(1-)={Rh(C6H5O6S)Cl3}(3-) [ No CAS ]
YieldReaction ConditionsOperation in experiment
In water pH=1 to 6;
  • 22
  • [ 99-68-3 ]
  • Ni(2+)*H(1+)*O2CCH2CH(SCH2CO2)CO2(3-)*3H2O={Ni(O2CCH2CH(SCH2CO2H)CO2)(H2O)3} [ No CAS ]
YieldReaction ConditionsOperation in experiment
With Ni salt; H2O In water pH:3-10;
  • 23
  • [ 68-11-1 ]
  • [ 110-17-8 ]
  • [ 99-68-3 ]
YieldReaction ConditionsOperation in experiment
With sodium hydroxide In water at 90℃; for 48h;
  • 24
  • [ 99-68-3 ]
  • 2-(2-chloro-2-oxoethyl)sulfanylbutanedioyl dichloride [ No CAS ]
YieldReaction ConditionsOperation in experiment
With thionyl chloride In N,N-dimethyl-formamide at 20 - 150℃; Schlenk technique; Inert atmosphere; 1.d (d) Synthesis of2-(2-chloro-2-oxo-ethyl)sulfanylbutanedioyl dichloride (Acyl Chloride 4) In a Schlenk tube, previously dried in an oven at 150°C, SOCh (10.0 mL, 138 mmol) and 3 drops of DMF were added to 2-(carboxymethylsulfanyl)butanedioic acid (4.30 g, 20 mmol, origin: Alfa Aesar). The reaction mixture was stirred at room temperature over the week-end under a flow of nitrogen, which was neutralised through a wash bottle containing an aqueous solution of NaOH (10%). An aliquot of the reaction mixture (0.1 mL) was pipetted off and placed in a small vial. After evaporating the SOCI2 and flushing with argon, the sample (38 mg) was analyzed by NMR spectroscopy. The SOCI2 of the rest of the sample was evaporated and flushed with argon to afford the target compound. ^-NMR: 4.43 (d, J = 17.3 Hz, 1 H); 4.31-4.24 (m, 1 H), 4.21 (d, J = 17.3 Hz, 1 H), 3.44 (dd, J = 18.9, 9.9 Hz, 1 H), 2.94-2.79 (m, 1 H). 13C-NMR: 171.65, 170.49, 169.21, 45.20, 40.64, 35.75.
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