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Chemical Structure| 569-58-4 Chemical Structure| 569-58-4
Chemical Structure| 569-58-4

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Product Details of Aluminon

CAS No. :569-58-4
Formula : C22H23N3O9
M.W : 473.43
SMILES Code : O=C(C=C/1)C(C([O-])=O)=CC1=C(C2=CC(C([O-])=O)=C(O)C=C2)\C3=CC(C([O-])=O)=C(O)C=C3.[NH4+].[NH4+].[NH4+]
English Name :Ammonium 5,5'-((3-carboxylato-4-oxocyclohexa-2,5-dien-1-ylidene)methylene)bis(2-hydroxybenzoate)
MDL No. :MFCD00040925

Safety of Aluminon

Application In Synthesis of Aluminon

* All experimental methods are cited from the reference, please refer to the original source for details. We do not guarantee the accuracy of the content in the reference.

  • Downstream synthetic route of [ 569-58-4 ]

[ 569-58-4 ] Synthesis Path-Downstream   1~12

YieldReaction ConditionsOperation in experiment
Herstellung von <α-14<i>C</i>>Aluminon;
  • 2
  • [ CAS Unavailable ]
  • [ 569-58-4 ]
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YieldReaction ConditionsOperation in experiment
86% With air In water for 12h; Irradiation;
  • 3
  • [ CAS Unavailable ]
  • [ 569-58-4 ]
  • [ CAS Unavailable ]
YieldReaction ConditionsOperation in experiment
In water
  • 4
  • [ 569-58-4 ]
  • [ CAS Unavailable ]
  • [ CAS Unavailable ]
YieldReaction ConditionsOperation in experiment
0.53% In ethanol; water at 75℃; for 0.3h; 2.2 Synthesis of alkaline earth metal ion complexes General procedure: A simple strategy was utilized to prepare the targeted alkaline earth metal ion complexes (Scheme 1S). By using, 1:2M ratio from ATA ligand (dark red) and each colorless metal salt that was mixed in EtOH/H2O solvent (3:1). O.947g (2mmol) of ATA ligand was dissolved in 10mL bi-distilled H2O and then mixed with each salt such as, MgCl2 (0.381g), CaCl2 (0.444g), SrCl2 (0.634g) or BaCl2 (0.833g), which dissolved in 30mL EtOH. A colored precipitates were appeared during reflux at 75°C up to 3h, then filtered off and dried in desiccators over CaCl2. The yields of Sr(II) and Ba(II) complexes around 70%, while the yields of Ca(II) and Mg(II) complexes up to 53%.
  • 5
  • [ 569-58-4 ]
  • [ CAS Unavailable ]
  • [ CAS Unavailable ]
YieldReaction ConditionsOperation in experiment
0.53% In ethanol; water at 75℃; for 0.3h; 2.2 Synthesis of alkaline earth metal ion complexes General procedure: A simple strategy was utilized to prepare the targeted alkaline earth metal ion complexes (Scheme 1S). By using, 1:2M ratio from ATA ligand (dark red) and each colorless metal salt that was mixed in EtOH/H2O solvent (3:1). O.947g (2mmol) of ATA ligand was dissolved in 10mL bi-distilled H2O and then mixed with each salt such as, MgCl2 (0.381g), CaCl2 (0.444g), SrCl2 (0.634g) or BaCl2 (0.833g), which dissolved in 30mL EtOH. A colored precipitates were appeared during reflux at 75°C up to 3h, then filtered off and dried in desiccators over CaCl2. The yields of Sr(II) and Ba(II) complexes around 70%, while the yields of Ca(II) and Mg(II) complexes up to 53%.
  • 6
  • [ 569-58-4 ]
  • [ CAS Unavailable ]
  • [ CAS Unavailable ]
YieldReaction ConditionsOperation in experiment
0.7% In ethanol; water at 75℃; for 0.3h; 2.2 Synthesis of alkaline earth metal ion complexes General procedure: A simple strategy was utilized to prepare the targeted alkaline earth metal ion complexes (Scheme 1S). By using, 1:2M ratio from ATA ligand (dark red) and each colorless metal salt that was mixed in EtOH/H2O solvent (3:1). O.947g (2mmol) of ATA ligand was dissolved in 10mL bi-distilled H2O and then mixed with each salt such as, MgCl2 (0.381g), CaCl2 (0.444g), SrCl2 (0.634g) or BaCl2 (0.833g), which dissolved in 30mL EtOH. A colored precipitates were appeared during reflux at 75°C up to 3h, then filtered off and dried in desiccators over CaCl2. The yields of Sr(II) and Ba(II) complexes around 70%, while the yields of Ca(II) and Mg(II) complexes up to 53%.
  • 7
  • [ 569-58-4 ]
  • [ CAS Unavailable ]
  • [ CAS Unavailable ]
YieldReaction ConditionsOperation in experiment
0.7% In ethanol; water at 75℃; for 0.3h; 2.2 Synthesis of alkaline earth metal ion complexes General procedure: A simple strategy was utilized to prepare the targeted alkaline earth metal ion complexes (Scheme 1S). By using, 1:2M ratio from ATA ligand (dark red) and each colorless metal salt that was mixed in EtOH/H2O solvent (3:1). O.947g (2mmol) of ATA ligand was dissolved in 10mL bi-distilled H2O and then mixed with each salt such as, MgCl2 (0.381g), CaCl2 (0.444g), SrCl2 (0.634g) or BaCl2 (0.833g), which dissolved in 30mL EtOH. A colored precipitates were appeared during reflux at 75°C up to 3h, then filtered off and dried in desiccators over CaCl2. The yields of Sr(II) and Ba(II) complexes around 70%, while the yields of Ca(II) and Mg(II) complexes up to 53%.
  • 8
  • [ 569-58-4 ]
  • [ CAS Unavailable ]
YieldReaction ConditionsOperation in experiment
With ammonia; water; selenium tetrachloride In methanol at 65℃; for 3h; 2.3. Synthesis of the AAS complexes General procedure: To a solution of AAS (1mmol) dissolved in 25 mL of CH3OH solvent,solution containing 3 mmol of the chloride salt (AuCl3, TaCl5, NbCl5,SeCl4 or TeCl4) dissolved in 25mL of CH3OHwas added, and pHwas optimizedat ~8 using drops of ammoniumsolution (5%). After stirring theresultingmixtures of each chloride at 65 °C for 3 h, colored solid precipitateswere harvested by slow evaporation. The Au(III) ions formed abrownish-red-colored precipitate with AAS, Ta(V) formed red-coloredprecipitate, Nb(V)formed reddish-brown-colored precipitate, Se(IV)formed brown-colored precipitate, where Te (IV) formed orangecoloredprecipitate. These colored precipitates were isolated from thesolutions, thoroughly washed, and dried in an oven at 70°. Complex ofAAS with Au(III) was formulated as [Au3L(H2O)2Cl4], Complexes ofAAS with Se(IV) and Te(IV) ions were formulated as [Se3L(H2O)5Cl7]and [Te3L(H2O)5Cl7], respectively, where the complexes with Nb(V) and Ta(V) ions were formulated as [Nb3L(H2O)2Cl10] and [Ta3L(H2O)2Cl10], respectively (where L5- is the ligand; C22H9O9]. Thesecomplexes were next characterized by elemental, thermal andspectral data.
  • 9
  • [ 569-58-4 ]
  • [ CAS Unavailable ]
YieldReaction ConditionsOperation in experiment
With ammonia; water; tellurium tetrachloride In methanol at 65℃; for 3h; 2.3. Synthesis of the AAS complexes General procedure: To a solution of AAS (1mmol) dissolved in 25 mL of CH3OH solvent,solution containing 3 mmol of the chloride salt (AuCl3, TaCl5, NbCl5,SeCl4 or TeCl4) dissolved in 25mL of CH3OHwas added, and pHwas optimizedat ~8 using drops of ammoniumsolution (5%). After stirring theresultingmixtures of each chloride at 65 °C for 3 h, colored solid precipitateswere harvested by slow evaporation. The Au(III) ions formed abrownish-red-colored precipitate with AAS, Ta(V) formed red-coloredprecipitate, Nb(V)formed reddish-brown-colored precipitate, Se(IV)formed brown-colored precipitate, where Te (IV) formed orangecoloredprecipitate. These colored precipitates were isolated from thesolutions, thoroughly washed, and dried in an oven at 70°. Complex ofAAS with Au(III) was formulated as [Au3L(H2O)2Cl4], Complexes ofAAS with Se(IV) and Te(IV) ions were formulated as [Se3L(H2O)5Cl7]and [Te3L(H2O)5Cl7], respectively, where the complexes with Nb(V) and Ta(V) ions were formulated as [Nb3L(H2O)2Cl10] and [Ta3L(H2O)2Cl10], respectively (where L5- is the ligand; C22H9O9]. Thesecomplexes were next characterized by elemental, thermal andspectral data.
  • 10
  • [ CAS Unavailable ]
  • [ 7732-18-5 ]
  • [ 569-58-4 ]
  • [ CAS Unavailable ]
YieldReaction ConditionsOperation in experiment
With ammonia In methanol at 65℃; for 3h; 2.3. Synthesis of the AAS complexes General procedure: To a solution of AAS (1mmol) dissolved in 25 mL of CH3OH solvent,solution containing 3 mmol of the chloride salt (AuCl3, TaCl5, NbCl5,SeCl4 or TeCl4) dissolved in 25mL of CH3OHwas added, and pHwas optimizedat ~8 using drops of ammoniumsolution (5%). After stirring theresultingmixtures of each chloride at 65 °C for 3 h, colored solid precipitateswere harvested by slow evaporation. The Au(III) ions formed abrownish-red-colored precipitate with AAS, Ta(V) formed red-coloredprecipitate, Nb(V)formed reddish-brown-colored precipitate, Se(IV)formed brown-colored precipitate, where Te (IV) formed orangecoloredprecipitate. These colored precipitates were isolated from thesolutions, thoroughly washed, and dried in an oven at 70°. Complex ofAAS with Au(III) was formulated as [Au3L(H2O)2Cl4], Complexes ofAAS with Se(IV) and Te(IV) ions were formulated as [Se3L(H2O)5Cl7]and [Te3L(H2O)5Cl7], respectively, where the complexes with Nb(V) and Ta(V) ions were formulated as [Nb3L(H2O)2Cl10] and [Ta3L(H2O)2Cl10], respectively (where L5- is the ligand; C22H9O9]. Thesecomplexes were next characterized by elemental, thermal andspectral data.
  • 11
  • [ 7732-18-5 ]
  • [ 569-58-4 ]
  • [ 7721-01-9 ]
  • [ CAS Unavailable ]
YieldReaction ConditionsOperation in experiment
With ammonia In methanol at 65℃; for 3h; 2.3. Synthesis of the AAS complexes General procedure: To a solution of AAS (1mmol) dissolved in 25 mL of CH3OH solvent,solution containing 3 mmol of the chloride salt (AuCl3, TaCl5, NbCl5,SeCl4 or TeCl4) dissolved in 25mL of CH3OHwas added, and pHwas optimizedat ~8 using drops of ammoniumsolution (5%). After stirring theresultingmixtures of each chloride at 65 °C for 3 h, colored solid precipitateswere harvested by slow evaporation. The Au(III) ions formed abrownish-red-colored precipitate with AAS, Ta(V) formed red-coloredprecipitate, Nb(V)formed reddish-brown-colored precipitate, Se(IV)formed brown-colored precipitate, where Te (IV) formed orangecoloredprecipitate. These colored precipitates were isolated from thesolutions, thoroughly washed, and dried in an oven at 70°. Complex ofAAS with Au(III) was formulated as [Au3L(H2O)2Cl4], Complexes ofAAS with Se(IV) and Te(IV) ions were formulated as [Se3L(H2O)5Cl7]and [Te3L(H2O)5Cl7], respectively, where the complexes with Nb(V) and Ta(V) ions were formulated as [Nb3L(H2O)2Cl10] and [Ta3L(H2O)2Cl10], respectively (where L5- is the ligand; C22H9O9]. Thesecomplexes were next characterized by elemental, thermal andspectral data.
  • 12
  • [ 7732-18-5 ]
  • [ 10026-12-7 ]
  • [ 569-58-4 ]
  • [ CAS Unavailable ]
YieldReaction ConditionsOperation in experiment
With ammonia In methanol at 65℃; for 3h; 2.3. Synthesis of the AAS complexes General procedure: To a solution of AAS (1mmol) dissolved in 25 mL of CH3OH solvent,solution containing 3 mmol of the chloride salt (AuCl3, TaCl5, NbCl5,SeCl4 or TeCl4) dissolved in 25mL of CH3OHwas added, and pHwas optimizedat ~8 using drops of ammoniumsolution (5%). After stirring theresultingmixtures of each chloride at 65 °C for 3 h, colored solid precipitateswere harvested by slow evaporation. The Au(III) ions formed abrownish-red-colored precipitate with AAS, Ta(V) formed red-coloredprecipitate, Nb(V)formed reddish-brown-colored precipitate, Se(IV)formed brown-colored precipitate, where Te (IV) formed orangecoloredprecipitate. These colored precipitates were isolated from thesolutions, thoroughly washed, and dried in an oven at 70°. Complex ofAAS with Au(III) was formulated as [Au3L(H2O)2Cl4], Complexes ofAAS with Se(IV) and Te(IV) ions were formulated as [Se3L(H2O)5Cl7]and [Te3L(H2O)5Cl7], respectively, where the complexes with Nb(V) and Ta(V) ions were formulated as [Nb3L(H2O)2Cl10] and [Ta3L(H2O)2Cl10], respectively (where L5- is the ligand; C22H9O9]. Thesecomplexes were next characterized by elemental, thermal andspectral data.
 

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