A7575741072067-44-7

[2,2'-Bis(4-tert-butylpyridine)]bis[2-(2,4-difluorophenyl)pyridine]iridium(III) hexafluorophosphate

A785897808142-88-3

Iridium(1 ), [4,4'-bis(1,1-dimethylethyl)-2,2'-bipyridine-κN1,κN1']bis[5-fluoro-2-(5-methyl-2-pyridinyl-κN)phenyl-κC]-, (OC-6-33)-, hexafluorophosphate(1-) (1:1)

A125846922775-90-2

(2,2'-Bipyridine)nickel dichloride

A12584701894189-67-3

Nickel, [4,4′-bis(1,1-dimethylethyl)-2,2′-bipyridine-κN1,κN1′]dibromo-, (SP-4-2)-

A193262387827-64-7

2-(2,4-Difluorophenyl)-5-(trifluoromethyl)pyridine

A983643583052-21-5

2-(2,4-Difluorophenyl)-5-methylpyridine

Technical Notes:

1.Catalyst for cross-coupling of potassium alkoxyalkyl-/benzyltrifluoroborates with aryl bromides.

2.Catalyst for sp3 –sp2 cross-coupling of amino acids with aryl halides.

3.Catalyst for carbon–oxygen coupling reaction of abundant alcohols and aryl bromides.

4.Catalyst for arylation of saccharide motifs.

5.Catalyst for coupling reaction between allylic carbonates and vinyl triflates to furnish both E- and Z-configured 1, 4-dienes.

6.Catalyst for three-component cross-coupling reaction involving aryl halides, sodium sulfinates and alkynes.

7.Catalyst for cross-coupling of electron-deficient alkenes with α-silyl amines and aryl halides.

Catalyst for cross-coupling of potassium alkoxyalkyl-/benzyltrifluoroborates with aryl bromides.[1]

Catalyst for sp3 –sp2 cross-coupling of amino acids with aryl halides.[2]

Catalyst for carbon–oxygen coupling reaction of abundant alcohols and aryl bromides.[3]

Catalyst for arylation of saccharide motifs.[4]

Catalyst for coupling reaction between allylic carbonates and vinyl triflates to furnish both E- and Z-configured 1, 4-dienes.[5]

Catalyst for three-component cross-coupling reaction involving aryl halides, sodium sulfinates and alkynes.[6]

Catalyst for cross-coupling of electron-deficient alkenes with α-silyl amines and aryl halides.[7]

Reference: [1] Science, 2014, 345, 433. [2] Science, 2014, 345, 6195. [3] Nature, 2015, 524, 330. [4] Angew. Chem. Int. Ed., 2018, 57, 6614. [5] Angew. Chem. Int. Ed., 2019, 59, 177. [6] Nature Catalysis, 2019, 2, 678. [7] 10.1002/anie.202006439.