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[ CAS No. 10058-44-3 ] {[proInfo.proName]}

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Chemical Structure| 10058-44-3
Chemical Structure| 10058-44-3
Structure of 10058-44-3 * Storage: {[proInfo.prStorage]}
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Product Details of [ 10058-44-3 ]

CAS No. :10058-44-3 MDL No. :MFCD00016091
Formula : Fe4O21P6 Boiling Point : -
Linear Structure Formula :- InChI Key :CADNYOZXMIKYPR-UHFFFAOYSA-B
M.W : 745.21 Pubchem ID :24877
Synonyms :

Safety of [ 10058-44-3 ]

Signal Word:Warning Class:N/A
Precautionary Statements:P261-P305+P351+P338 UN#:N/A
Hazard Statements:H302-H315-H319-H335 Packing Group:N/A
GHS Pictogram:

Application In Synthesis of [ 10058-44-3 ]

* All experimental methods are cited from the reference, please refer to the original source for details. We do not guarantee the accuracy of the content in the reference.

  • Downstream synthetic route of [ 10058-44-3 ]

[ 10058-44-3 ] Synthesis Path-Downstream   1~18

  • 1
  • iron(III) chloride [ No CAS ]
  • [ 124-43-6 ]
  • [ 10058-44-3 ]
YieldReaction ConditionsOperation in experiment
In water 3 In 60 kg of ion-exchanged water was dissolved 13 kg of ferric chloride hexahydrate to prepare an iron solution. To a solution prepared by dissolving 20 kg of tetrasodium pyrophosphate decahydrate in 500 kg of ion-exchanged water was gradually added the above iron solution with stirring. The pH of the resulting mixture was adjusted to 3 using a handy pH meter manufactured by HORIBA, Ltd. After forming of the salt of ferric pyrophosphate by neutralization reaction was terminated, the resulting reaction mixture was subjected to solid-liquid separation by centrifugation (3000×g, for 5 minutes), and ferric pyrophosphate of the solid phase portion was collected. The ferric pyrophosphate was resuspended in ion-exchanged water, to give a slurry containing particles (average particle size: about 0.21 μm) of ferric pyrophosphate with a solid content of 4% by weight. Fifty kilograms of the slurry was transferred to another stainless beaker, and 0.8 kg of diglycerol monopalmitate (HLB=7.3, monoester content: 80% by weight; specific gravity: 0.9; manufactured by Taiyo Kagaku Co., Ltd.) was added and dissolved therein. The solution was heated until the temperature thereof was 45° C., and then subjected to a treatment in a homogenizer for 15 minutes. Thereafter, the temperature of the solution was further increased to 75° C., and then kept at 75° C. for 10 minutes. Following the above procedure, a ferric pyrophosphate dispersion composition having a solid content of 4% by weight (Inventive Product C) was obtained (average particle size of fine metal particles: about 0.25 μm). The dispersion was filled in a clear container, and stored at normal temperatures.
With SUNLECITHIN A In water 1 In 60 kg of ion-exchanged water were dissolved 13 kg of ferric chloride hexahydrate and 0.3 kg of an enzymatically decomposed lecithin (trade name: “SUNLECITHIN A”; HLB=15; specific gravity: 0.9; manufactured by Taiyo Kagaku Co., Ltd.) to prepare an iron solution. To a solution prepared by dissolving 20 kg of tetrasodium pyrophosphate decahydrate in 500 kg of ion-exchanged water was gradually added the above iron solution with stirring. The pH of the resulting mixture was adjusted to 3 using a handy pH meter manufactured by HORIBA, Ltd. After forming of the salt of ferric pyrophosphate by neutralization reaction was terminated, the resulting reaction mixture was subjected to solid-liquid separation by centrifugation (3000×g, for 5 minutes), and ferric pyrophosphate of the solid phase portion was collected. The ferric pyrophosphate was resuspended in ion-exchanged water, to give a slurry containing particles (average particle size: about 0.21 μm) of ferric pyrophosphate with a solid content of 4% by weight. Fifty kilograms of the slurry was transferred to another stainless beaker, and 0.4 kg of decaglycerol monomyristate (HLB=14; specific gravity: 0.9; manufactured by Taiyo Kagaku Co., Ltd.) was added and dissolved therein. The solution was heated until the temperature thereof was 45° C., and then subjected to a treatment in a homogenizer for 15 minutes. Thereafter, the temperature of the solution was further increased to 75° C., and then kept at 75° C. for 10 minutes. Following the above procedure, a ferric pyrophosphate dispersion composition having a solid content of 4% by weight (Comparative Product A) was obtained (average particle size of fine metal particles: about 0.28 μm). The dispersion was filled in a clear container, and stored at normal temperatures.
  • 2
  • [ 765207-04-3 ]
  • iron metaphosphate [ No CAS ]
  • [ 10058-44-3 ]
YieldReaction ConditionsOperation in experiment
In neat (no solvent, solid phase) Fe(PO3)3 and FePO4 were heated at 940°C for 72 h under O2, annealed for 15 d under vac. at 900°C;
  • 3
  • [ 10058-44-3 ]
  • [ 765207-04-3 ]
  • phosphoric acid [ No CAS ]
  • Fe(3+)*HP2O7(3-)*1.5H2O [ No CAS ]
  • oxonium iron(III) orthophosphate hydrate [ No CAS ]
YieldReaction ConditionsOperation in experiment
With H2O In water powdered FePO4 is added during 3-4 d to H3PO4 (85%); boiling under reflux; ppt. washed with distd. water for 3-4 d and then vac. dried; elem. anal.;
  • 4
  • iron(III) oxide [ No CAS ]
  • [ 7722-76-1 ]
  • [ 10058-44-3 ]
YieldReaction ConditionsOperation in experiment
In neat (no solvent) calcining (900°C);
  • 5
  • phosphoric acid [ No CAS ]
  • [ 7782-61-8 ]
  • [ 10058-44-3 ]
YieldReaction ConditionsOperation in experiment
In water evapn. of soln. Fe(NO3)3 and H3PO4, annealing (400°C, N2 atmosphere, 24 h);
  • 6
  • [ 7722-76-1 ]
  • Ammonium iron sulfate [ No CAS ]
  • [ 10058-44-3 ]
  • [ 765207-04-3 ]
YieldReaction ConditionsOperation in experiment
With H2O2 In ethanol; water soln. of Fe(NH4)2(SO4)2*6H2O (pH 4.9) added at ambient temp. to stirred soln. of (NH4)H2PO4 in water-EtOH (1.5:1, v/v) in 1:1 vol. proportion; concd. soln. of H2O2 added; ppt. kept in contact with mother liquor for 30 min without stirring; ppt. collected on membrane filter; washed (H2O); dried at room temp. in air for 2 ds; calcined in air at 750°C for 10 h; monitored by X-ray diffraction;
  • 7
  • [ 10058-44-3 ]
  • [ 124-43-6 ]
  • sodium iron(III) pyrophosphate*99H2O [ No CAS ]
YieldReaction ConditionsOperation in experiment
with Fe4(P2O7)3 satd. soln. of Na4P2O7; evapn. in vacuum over H2SO4;
with Fe4(P2O7)3 satd. soln. of Na4P2O7; evapn. in vacuum over H2SO4;
  • 8
  • 4Fe(3+)*3P2O7(4-)*4H2O=Fe4(P2O7)3*4H2O [ No CAS ]
  • [ 10058-44-3 ]
YieldReaction ConditionsOperation in experiment
In neat (no solvent, solid phase) heated in Pt crucible under air at 900°C;
  • 9
  • iron(III) phosphite * 9 H2O [ No CAS ]
  • [ 10058-44-3 ]
  • iron(II) phosphate [ No CAS ]
  • [ 7803-51-2 ]
YieldReaction ConditionsOperation in experiment
In neat (no solvent) calcination Fe2(HPO3)3*9H2O; generation of PH3 and formation of Fe4(P2O7)3 and Fe3(PO4)2 as residue;;
  • 10
  • [ 10058-44-3 ]
  • iron(II) pyrophosphate [ No CAS ]
  • triiron bis(diphosphate) [ No CAS ]
YieldReaction ConditionsOperation in experiment
In neat (no solvent, solid phase) mixt. annealed at 900°C for 3 days (gold containers placed in a evacuated silica tubes);
  • 11
  • [ 10058-44-3 ]
  • iron(II) pyrophosphate [ No CAS ]
  • Fe7(16+)*4P2O7(4-)=Fe7(P2O7)4 [ No CAS ]
YieldReaction ConditionsOperation in experiment
In neat (no solvent, solid phase) heating (vac., 900°C, ratio of Fe2P2O7/Fe4(P2O7)3 5:1, sealed tube, FeCl2 as mineralizer agent);
  • 12
  • [(S)-C5H14N2][Fe4(C2O4)3(HPO4)2(H2O)2] [ No CAS ]
  • [ 80937-33-3 ]
  • [ 10058-44-3 ]
YieldReaction ConditionsOperation in experiment
In neat (no solvent) byproducts: Fe2O3, C5H12N2, H2O; thermal decomposition in flowing oxygen at 700 °C; detn. by powder XRD, TGA;
  • 13
  • (C2H10N2)(2+)*3Fe(2+)*4HPO3(2-)=(C2H10N2)[Fe3(HPO3)4] [ No CAS ]
  • [ 10058-44-3 ]
  • [ 765207-04-3 ]
  • [ 765207-04-3 ]
YieldReaction ConditionsOperation in experiment
In neat (no solvent, solid phase) heating from room temp. up to 815°C; detd. by time-resolved X-ray thermal diffractometry in air;
  • 14
  • ammonium iron(III) orthophosphate [ No CAS ]
  • [ 10058-44-3 ]
  • iron(III) polyphosphate [ No CAS ]
YieldReaction ConditionsOperation in experiment
In neat (no solvent, solid phase) NH4Fe(HPO4)2 heated to 900°C in air;
  • 15
  • iron(III) phosphate hydrate [ No CAS ]
  • iron(III) polyphosphate [ No CAS ]
  • [ 10058-44-3 ]
YieldReaction ConditionsOperation in experiment
In neat (no solvent, solid phase) stoich. mixt. was heated for 12 h at 800°C, then 72 h at 940°C; obtained phosphates were pulverized; XRD;
  • 16
  • iron(III) oxide [ No CAS ]
  • [ 7722-76-1 ]
  • iron(III) phosphate hydrate [ No CAS ]
  • [ 10058-44-3 ]
YieldReaction ConditionsOperation in experiment
In neat (no solvent, solid phase) mixt. was heated at 800°C in air for 12 h, then at 940°C in air for 24-48 h; XRD;
  • 18
  • Iron(III) nitrate nonahydrate [ No CAS ]
  • ammonium dihydrogen phosphate [ No CAS ]
  • [ 10058-44-3 ]
YieldReaction ConditionsOperation in experiment
Stage #1: Iron(III) nitrate nonahydrate; ammonium dihydrogen phosphate With malic acid Stage #2: In neat (no solvent, solid phase) at 850℃; for 5h; Calcination;
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