Alternatived Products of [ 10058-44-3 ]
Product Details of [ 10058-44-3 ]
CAS No. : | 10058-44-3 |
MDL No. : | MFCD00016091 |
Formula : |
Fe4O21P6
|
Boiling Point : |
- |
Linear Structure Formula : | - |
InChI Key : | CADNYOZXMIKYPR-UHFFFAOYSA-B |
M.W : |
745.21
|
Pubchem ID : | 24877 |
Synonyms : |
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Application In Synthesis of [ 10058-44-3 ]
* All experimental methods are cited from the reference, please refer to the original source for details. We do not guarantee the accuracy of the content in the reference.
- Downstream synthetic route of [ 10058-44-3 ]
- 1
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iron(III) chloride
[ No CAS ]
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[ 124-43-6 ]
-
[ 10058-44-3 ]
Yield | Reaction Conditions | Operation in experiment |
|
In water |
3
In 60 kg of ion-exchanged water was dissolved 13 kg of ferric chloride hexahydrate to prepare an iron solution. To a solution prepared by dissolving 20 kg of tetrasodium pyrophosphate decahydrate in 500 kg of ion-exchanged water was gradually added the above iron solution with stirring. The pH of the resulting mixture was adjusted to 3 using a handy pH meter manufactured by HORIBA, Ltd. After forming of the salt of ferric pyrophosphate by neutralization reaction was terminated, the resulting reaction mixture was subjected to solid-liquid separation by centrifugation (3000×g, for 5 minutes), and ferric pyrophosphate of the solid phase portion was collected. The ferric pyrophosphate was resuspended in ion-exchanged water, to give a slurry containing particles (average particle size: about 0.21 μm) of ferric pyrophosphate with a solid content of 4% by weight. Fifty kilograms of the slurry was transferred to another stainless beaker, and 0.8 kg of diglycerol monopalmitate (HLB=7.3, monoester content: 80% by weight; specific gravity: 0.9; manufactured by Taiyo Kagaku Co., Ltd.) was added and dissolved therein. The solution was heated until the temperature thereof was 45° C., and then subjected to a treatment in a homogenizer for 15 minutes. Thereafter, the temperature of the solution was further increased to 75° C., and then kept at 75° C. for 10 minutes. Following the above procedure, a ferric pyrophosphate dispersion composition having a solid content of 4% by weight (Inventive Product C) was obtained (average particle size of fine metal particles: about 0.25 μm). The dispersion was filled in a clear container, and stored at normal temperatures. |
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With SUNLECITHIN A In water |
1
In 60 kg of ion-exchanged water were dissolved 13 kg of ferric chloride hexahydrate and 0.3 kg of an enzymatically decomposed lecithin (trade name: “SUNLECITHIN A”; HLB=15; specific gravity: 0.9; manufactured by Taiyo Kagaku Co., Ltd.) to prepare an iron solution. To a solution prepared by dissolving 20 kg of tetrasodium pyrophosphate decahydrate in 500 kg of ion-exchanged water was gradually added the above iron solution with stirring. The pH of the resulting mixture was adjusted to 3 using a handy pH meter manufactured by HORIBA, Ltd. After forming of the salt of ferric pyrophosphate by neutralization reaction was terminated, the resulting reaction mixture was subjected to solid-liquid separation by centrifugation (3000×g, for 5 minutes), and ferric pyrophosphate of the solid phase portion was collected. The ferric pyrophosphate was resuspended in ion-exchanged water, to give a slurry containing particles (average particle size: about 0.21 μm) of ferric pyrophosphate with a solid content of 4% by weight. Fifty kilograms of the slurry was transferred to another stainless beaker, and 0.4 kg of decaglycerol monomyristate (HLB=14; specific gravity: 0.9; manufactured by Taiyo Kagaku Co., Ltd.) was added and dissolved therein. The solution was heated until the temperature thereof was 45° C., and then subjected to a treatment in a homogenizer for 15 minutes. Thereafter, the temperature of the solution was further increased to 75° C., and then kept at 75° C. for 10 minutes. Following the above procedure, a ferric pyrophosphate dispersion composition having a solid content of 4% by weight (Comparative Product A) was obtained (average particle size of fine metal particles: about 0.28 μm). The dispersion was filled in a clear container, and stored at normal temperatures. |
- 2
-
[ 765207-04-3 ]
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iron metaphosphate
[ No CAS ]
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[ 10058-44-3 ]
Yield | Reaction Conditions | Operation in experiment |
|
In neat (no solvent, solid phase) Fe(PO3)3 and FePO4 were heated at 940°C for 72 h under O2, annealed for 15 d under vac. at 900°C; |
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- 3
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[ 10058-44-3 ]
-
[ 765207-04-3 ]
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phosphoric acid
[ No CAS ]
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Fe(3+)*HP2O7(3-)*1.5H2O
[ No CAS ]
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oxonium iron(III) orthophosphate hydrate
[ No CAS ]
Yield | Reaction Conditions | Operation in experiment |
|
With H2O In water powdered FePO4 is added during 3-4 d to H3PO4 (85%); boiling under reflux; ppt. washed with distd. water for 3-4 d and then vac. dried; elem. anal.; |
|
- 4
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iron(III) oxide
[ No CAS ]
-
[ 7722-76-1 ]
-
[ 10058-44-3 ]
Yield | Reaction Conditions | Operation in experiment |
|
In neat (no solvent) calcining (900°C); |
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- 5
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phosphoric acid
[ No CAS ]
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[ 7782-61-8 ]
-
[ 10058-44-3 ]
Yield | Reaction Conditions | Operation in experiment |
|
In water evapn. of soln. Fe(NO3)3 and H3PO4, annealing (400°C, N2 atmosphere, 24 h); |
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- 6
-
[ 7722-76-1 ]
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Ammonium iron sulfate
[ No CAS ]
-
[ 10058-44-3 ]
-
[ 765207-04-3 ]
Yield | Reaction Conditions | Operation in experiment |
|
With H2O2 In ethanol; water soln. of Fe(NH4)2(SO4)2*6H2O (pH 4.9) added at ambient temp. to stirred soln. of (NH4)H2PO4 in water-EtOH (1.5:1, v/v) in 1:1 vol. proportion; concd. soln. of H2O2 added; ppt. kept in contact with mother liquor for 30 min without stirring; ppt. collected on membrane filter; washed (H2O); dried at room temp. in air for 2 ds; calcined in air at 750°C for 10 h; monitored by X-ray diffraction; |
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- 7
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[ 10058-44-3 ]
-
[ 124-43-6 ]
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sodium iron(III) pyrophosphate*99H2O
[ No CAS ]
Yield | Reaction Conditions | Operation in experiment |
|
with Fe4(P2O7)3 satd. soln. of Na4P2O7; evapn. in vacuum over H2SO4; |
|
|
with Fe4(P2O7)3 satd. soln. of Na4P2O7; evapn. in vacuum over H2SO4; |
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- 8
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4Fe(3+)*3P2O7(4-)*4H2O=Fe4(P2O7)3*4H2O
[ No CAS ]
-
[ 10058-44-3 ]
Yield | Reaction Conditions | Operation in experiment |
|
In neat (no solvent, solid phase) heated in Pt crucible under air at 900°C; |
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Reference:
[1]Masquelier, Christian; Reale, Priscilla; Wurm, Calin; Morcrette, Mathieu; Dupont, Loic; Larcher, Dominique
[Journal of the Electrochemical Society, 2002, vol. 149, # 8, p. A1037-A1044]
- 9
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iron(III) phosphite * 9 H2O
[ No CAS ]
-
[ 10058-44-3 ]
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iron(II) phosphate
[ No CAS ]
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[ 7803-51-2 ]
Yield | Reaction Conditions | Operation in experiment |
|
In neat (no solvent) calcination Fe2(HPO3)3*9H2O; generation of PH3 and formation of Fe4(P2O7)3 and Fe3(PO4)2 as residue;; |
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Reference:
[1]Rammelsberg, C.
[Annalen der Physik, 1867, vol. 132, p. 491 - 491]
Rammelsberg, C.
[Journal fur praktische Chemie (Leipzig 1954), 1867, vol. 100, p. 18 - 18]
Rose, H.
[Annalen der Physik, 1827, vol. 9, p. 37 - 37]
[Gmelin Handbuch der Anorganischen Chemie, Gmelin Handbook: Fe: MVol.B4, 38, page 769 - 771]
- 10
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[ 10058-44-3 ]
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iron(II) pyrophosphate
[ No CAS ]
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triiron bis(diphosphate)
[ No CAS ]
Yield | Reaction Conditions | Operation in experiment |
|
In neat (no solvent, solid phase) mixt. annealed at 900°C for 3 days (gold containers placed in a evacuated silica tubes); |
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- 11
-
[ 10058-44-3 ]
-
iron(II) pyrophosphate
[ No CAS ]
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Fe7(16+)*4P2O7(4-)=Fe7(P2O7)4
[ No CAS ]
Yield | Reaction Conditions | Operation in experiment |
|
In neat (no solvent, solid phase) heating (vac., 900°C, ratio of Fe2P2O7/Fe4(P2O7)3 5:1, sealed tube, FeCl2 as mineralizer agent); |
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- 12
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[(S)-C5H14N2][Fe4(C2O4)3(HPO4)2(H2O)2]
[ No CAS ]
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[ 80937-33-3 ]
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[ 10058-44-3 ]
Yield | Reaction Conditions | Operation in experiment |
|
In neat (no solvent) byproducts: Fe2O3, C5H12N2, H2O; thermal decomposition in flowing oxygen at 700 °C; detn. by powder XRD, TGA; |
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- 13
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(C2H10N2)(2+)*3Fe(2+)*4HPO3(2-)=(C2H10N2)[Fe3(HPO3)4]
[ No CAS ]
-
[ 10058-44-3 ]
-
[ 765207-04-3 ]
-
[ 765207-04-3 ]
Yield | Reaction Conditions | Operation in experiment |
|
In neat (no solvent, solid phase) heating from room temp. up to 815°C; detd. by time-resolved X-ray thermal diffractometry in air; |
|
Reference:
[1]Chung, U-Chan; Mesa, Jose L.; Pizarro, Jose L.; Lezama, Luis; Garitaonandia, Jose S.; Chapman, Jon P.; Arriortua, Maria I.
[Journal of Solid State Chemistry, 2004, vol. 177, # 8, p. 2705 - 2713]
- 14
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ammonium iron(III) orthophosphate
[ No CAS ]
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[ 10058-44-3 ]
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iron(III) polyphosphate
[ No CAS ]
Yield | Reaction Conditions | Operation in experiment |
|
In neat (no solvent, solid phase) NH4Fe(HPO4)2 heated to 900°C in air; |
|
Reference:
[1]Alfonso, Belen F.; Blanco, Jesus A.; Fernandez-Diaz, M. Teresa; Trobajo, Camino; Khainakov, Sergei A.; Garcia, Jose R.
[Dalton Transactions, 2010, vol. 39, # 7, p. 1791 - 1796]
- 15
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iron(III) phosphate hydrate
[ No CAS ]
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iron(III) polyphosphate
[ No CAS ]
-
[ 10058-44-3 ]
Yield | Reaction Conditions | Operation in experiment |
|
In neat (no solvent, solid phase) stoich. mixt. was heated for 12 h at 800°C, then 72 h at 940°C; obtained phosphates were pulverized; XRD; |
|
- 16
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iron(III) oxide
[ No CAS ]
-
[ 7722-76-1 ]
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iron(III) phosphate hydrate
[ No CAS ]
-
[ 10058-44-3 ]
Yield | Reaction Conditions | Operation in experiment |
|
In neat (no solvent, solid phase) mixt. was heated at 800°C in air for 12 h, then at 940°C in air for 24-48 h; XRD; |
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- 17
-
[ 765207-04-3 ]
-
[ 10058-44-3 ]
Yield | Reaction Conditions | Operation in experiment |
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at 500℃; for 3h; Inert atmosphere; |
|
Reference:
[1]Yang, Dan; Lu, Ziyang; Rui, Xianhong; Huang, Xiao; Li, Hai; Zhang, Wenyu; Lam, Yeng Ming; Hng, Huey Hoon; Zhang, Hua; Yan, Qingyu; Zhu, Jixin
[Angewandte Chemie - International Edition, 2014, vol. 53, # 35, p. 9352 - 9355,4][Angew. Chem., 2014, vol. 126, # 35, p. 9506 - 9509,4][Angewandte Chemie, 2014, vol. 126, # 35, p. 9506 - 9509,4]
- 18
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Iron(III) nitrate nonahydrate
[ No CAS ]
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ammonium dihydrogen phosphate
[ No CAS ]
-
[ 10058-44-3 ]
Yield | Reaction Conditions | Operation in experiment |
|
Stage #1: Iron(III) nitrate nonahydrate; ammonium dihydrogen phosphate With malic acid
Stage #2: In neat (no solvent, solid phase) at 850℃; for 5h; Calcination; |
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