Alternatived Products of [ 1023558-03-3 ]
Product Details of [ 1023558-03-3 ]
CAS No. : | 1023558-03-3 |
MDL No. : | N/A |
Formula : |
C13H10N2S
|
Boiling Point : |
No data available |
Linear Structure Formula : | - |
InChI Key : | ZXZRMFGGDBQQRR-UHFFFAOYSA-N |
M.W : |
226.30
|
Pubchem ID : | 4111881 |
Synonyms : |
|
Safety of [ 1023558-03-3 ]
Application In Synthesis of [ 1023558-03-3 ]
* All experimental methods are cited from the reference, please refer to the original source for details. We do not guarantee the accuracy of the content in the reference.
- Downstream synthetic route of [ 1023558-03-3 ]
- 1
-
[ 127-19-5 ]

-
[ 1023558-03-3 ]

-
[ 1415584-22-3 ]
- 2
-
[ 95-54-5 ]

-
[ 6937-35-5 ]

-
[ 1023558-03-3 ]
Yield | Reaction Conditions | Operation in experiment |
86% |
With silica gel; In tetrahydrofuran; at 50℃; for 5h; |
General procedure: In a 10-mL reaction vial, nitroolefin (0.50 mmol), o-phenylenediamine (0.50 mmol), silica gel (200 mg) and solvents (3.0 mL) were mixed and then capped. The mixture was stirred for a given time and temperature (Tables 1-4). Upon completion as shown by TLC monitoring, the reaction mixture was cooled to room temperature and exacted with ethyl acetate (5.0 mL x 3). The combined organic layer was dried over Na2SO4, and concentrated in vacuum. The resulting residue was purified by columnchromatography on silica gel with the eluent (ethyl acetate/petroleum ether = 1:20~1:4) to givethe pure product. |
- 3
-
[ 98-03-3 ]

-
[ 79-24-3 ]

-
[ 95-54-5 ]

-
[ 1023558-03-3 ]
Yield | Reaction Conditions | Operation in experiment |
39% |
With silica gel; In tetrahydrofuran; at 100℃; for 24h; |
General procedure: In a 10-mL reaction vial, nitroolefin (0.50 mmol), o-phenylenediamine (0.50 mmol), silica gel (200 mg) and solvents (3.0 mL) were mixed and then capped. The mixture was stirred for a given time and temperature (Tables 1-4). Upon completion as shown by TLC monitoring, the reaction mixture was cooled to room temperature and exacted with ethyl acetate (5.0 mL x 3). The combined organic layer was dried over Na2SO4, and concentrated in vacuum. The resulting residue was purified by columnchromatography on silica gel with the eluent (ethyl acetate/petroleum ether = 1:20~1:4) to givethe pure product. |
- 4
-
[ 1023558-03-3 ]

-
C13H14N2S
[ No CAS ]

-
C13H14N2S
[ No CAS ]