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Chemical Structure| 1023558-03-3 Chemical Structure| 1023558-03-3

Structure of 1023558-03-3

Chemical Structure| 1023558-03-3

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Product Details of [ 1023558-03-3 ]

CAS No. :1023558-03-3
Formula : C13H10N2S
M.W : 226.30
SMILES Code : CC1=NC2=CC=CC=C2N=C1C3=CC=CS3
MDL No. :N/A
InChI Key :ZXZRMFGGDBQQRR-UHFFFAOYSA-N
Pubchem ID :4111881

Safety of [ 1023558-03-3 ]

GHS Pictogram:
Signal Word:Warning
Hazard Statements:H302-H315-H319-H335
Precautionary Statements:P261-P280-P301+P312-P302+P352-P305+P351+P338

Application In Synthesis of [ 1023558-03-3 ]

* All experimental methods are cited from the reference, please refer to the original source for details. We do not guarantee the accuracy of the content in the reference.

  • Downstream synthetic route of [ 1023558-03-3 ]

[ 1023558-03-3 ] Synthesis Path-Downstream   1~4

  • 1
  • [ 127-19-5 ]
  • [ 1023558-03-3 ]
  • [ 1415584-22-3 ]
  • 2
  • [ 95-54-5 ]
  • [ 6937-35-5 ]
  • [ 1023558-03-3 ]
YieldReaction ConditionsOperation in experiment
86% With silica gel; In tetrahydrofuran; at 50℃; for 5h; General procedure: In a 10-mL reaction vial, nitroolefin (0.50 mmol), o-phenylenediamine (0.50 mmol), silica gel (200 mg) and solvents (3.0 mL) were mixed and then capped. The mixture was stirred for a given time and temperature (Tables 1-4). Upon completion as shown by TLC monitoring, the reaction mixture was cooled to room temperature and exacted with ethyl acetate (5.0 mL x 3). The combined organic layer was dried over Na2SO4, and concentrated in vacuum. The resulting residue was purified by columnchromatography on silica gel with the eluent (ethyl acetate/petroleum ether = 1:20~1:4) to givethe pure product.
  • 3
  • [ 98-03-3 ]
  • [ 79-24-3 ]
  • [ 95-54-5 ]
  • [ 1023558-03-3 ]
YieldReaction ConditionsOperation in experiment
39% With silica gel; In tetrahydrofuran; at 100℃; for 24h; General procedure: In a 10-mL reaction vial, nitroolefin (0.50 mmol), o-phenylenediamine (0.50 mmol), silica gel (200 mg) and solvents (3.0 mL) were mixed and then capped. The mixture was stirred for a given time and temperature (Tables 1-4). Upon completion as shown by TLC monitoring, the reaction mixture was cooled to room temperature and exacted with ethyl acetate (5.0 mL x 3). The combined organic layer was dried over Na2SO4, and concentrated in vacuum. The resulting residue was purified by columnchromatography on silica gel with the eluent (ethyl acetate/petroleum ether = 1:20~1:4) to givethe pure product.
  • 4
  • [ 1023558-03-3 ]
  • C13H14N2S [ No CAS ]
  • C13H14N2S [ No CAS ]
 

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