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Chemical Structure| 103788-65-4 Chemical Structure| 103788-65-4

Structure of 103788-65-4

Chemical Structure| 103788-65-4

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Product Details of [ 103788-65-4 ]

CAS No. :103788-65-4
Formula : C12H13NO2
M.W : 203.24
SMILES Code : CC1=C(CCO)N=C(O1)C1=CC=CC=C1
MDL No. :MFCD00100006
InChI Key :JYWHQBLLIBQGCU-UHFFFAOYSA-N
Pubchem ID :725585

Safety of [ 103788-65-4 ]

GHS Pictogram:
Signal Word:Warning
Hazard Statements:H315-H319-H335
Precautionary Statements:P261-P280-P302+P352-P305+P351+P338

Application In Synthesis of [ 103788-65-4 ]

* All experimental methods are cited from the reference, please refer to the original source for details. We do not guarantee the accuracy of the content in the reference.

  • Downstream synthetic route of [ 103788-65-4 ]

[ 103788-65-4 ] Synthesis Path-Downstream   1~1

  • 1
  • [ 66495-88-3 ]
  • [ 103788-65-4 ]
  • [ 652980-83-1 ]
YieldReaction ConditionsOperation in experiment
45% With diamide; triphenylphosphine; In tetrahydrofuran; at 20℃; for 72h; To a flask containing <strong>[66495-88-3]3-hydroxy-2-methoxybenzaldehyde</strong> (0.2 g, 1.3 [MMOL),] [2- (5-] methyl-2-phenyl-1, 3-oxazol-4-yl) ethanol (0.29 g, 1.5 [MMOL),] TMAD (0.45 g, 2.6 [MMOL),] and triphenyphosphine (0.69 g, 2.6 [MMOL)] was added with THF (2 mL) under argon. The reaction was stirred at rt for 72 h. The reaction mixture was filtered through a silica-gel plug and solvents were evaporated under vacuum. The residue was purified by Biotage to obtain [2-METHOXY-3- [2- (5-METHYL-2-PHENYL-1, 3-OXAZOL-4-YL)] ethoxy] [BENZALDEHYDE] (0.2 g, 0.6 [MMOL)] in 45% [YIELD. 1H] NMR [(CDCI3)] [5] 2.4 (s, 3H), 3.1 (t, 2H), 3.9 (s, 3H), 4.3 (t, 2H), 7.2 (m, 2H), 7.4 (m, 4H), 7.9 (m, 2H), 10.4 (s, [1H)] ; GC-MS (ES) 338 (M+1) +.
 

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