[ CAS No. 10544-50-0 ] {[proInfo.proName]}

,{[proInfo.pro_purity]}

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Quality Control of [ 10544-50-0 ]

COA NMR CNMR HPLC LC-MS

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SDS Specification

Alternatived Products of [ 10544-50-0 ]

Product Details of [ 10544-50-0 ]

CAS No. :	10544-50-0	MDL No. :	MFCD23103447
Formula :	S₈	Boiling Point :	-
Linear Structure Formula :	-	InChI Key :	JLQNHALFVCURHW-UHFFFAOYSA-N
M.W :	256.52	Pubchem ID :	66348
Synonyms :

Safety of [ 10544-50-0 ]

Signal Word:	Danger	Class:	9
Precautionary Statements:	P501-P273-P260-P270-P264-P280-P391-P314-P337+P313-P305+P351+P338-P301+P312+P330	UN#:	3077
Hazard Statements:	H302-H319-H372-H410	Packing Group:	Ⅲ
GHS Pictogram:

Application In Synthesis of [ 10544-50-0 ]

* All experimental methods are cited from the reference, please refer to the original source for details. We do not guarantee the accuracy of the content in the reference.

Upstream synthesis route of [ 10544-50-0 ]
Downstream synthetic route of [ 10544-50-0 ]

[ 10544-50-0 ] Synthesis Path-Upstream 1~8

1
[ 182499-80-5 ]
[ 75-15-0 ]
[ 10544-50-0 ]
[ 51618-30-5 ]

Reference： [1] Green Chemistry, 2017, vol. 19, # 4, p. 1102 - 1108

2
[ 75-15-0 ]
[ 31183-89-8 ]
[ 10544-50-0 ]
[ 51618-29-2 ]

Reference： [1] Green Chemistry, 2017, vol. 19, # 4, p. 1102 - 1108

3
[ 75-15-0 ]
[ 7732-36-7 ]
[ 10544-50-0 ]
[ 2182-73-2 ]

Reference： [1] Green Chemistry, 2017, vol. 19, # 4, p. 1102 - 1108

4
[ 75-15-0 ]
[ 31183-91-2 ]
[ 10544-50-0 ]
[ 2268-79-3 ]

Reference： [1] Green Chemistry, 2017, vol. 19, # 4, p. 1102 - 1108

5
[ 10544-50-0 ]
[ 108-94-1 ]
[ 105-56-6 ]
[ 4506-71-2 ]

Reference： [1] Synlett, 2014, vol. 25, # 20, p. 2918 - 2922

6
[ 10544-50-0 ]
[ 589-92-4 ]
[ 105-56-6 ]
[ 76981-71-0 ]

Reference： [1] Synlett, 2014, vol. 25, # 20, p. 2918 - 2922

7
[ 10544-50-0 ]
[ 108-94-1 ]
[ 105-34-0 ]
[ 108354-78-5 ]

Reference： [1] Synlett, 2014, vol. 25, # 20, p. 2918 - 2922

8
[ 75-15-0 ]
[ 63755-09-9 ]
[ 154327-24-9 ]
[ 10544-50-0 ]

Reference： [1] Green Chemistry, 2017, vol. 19, # 4, p. 1102 - 1108

[ 10544-50-0 ] Synthesis Path-Downstream 1~56

1
[ 10544-50-0 ]
copper [ No CAS ]
[ 22205-45-4 ]

Yield	Reaction Conditions	Operation in experiment
	In solid Cu and S8 were mixed, heated at 46-450°C; study of influence of:mechanical treatment, mixing with a spatula, pressure (0.12-1.38 GPa), milling time (1-120 min), particle size of copper (32-112 μm), ageing, heating rate (1-40 K/min); detected by X-ray diffraction;
	In neat (no solvent) react. Cu and S in evacuated sealed silica tube at 700°C for 3 days, temp. was raised slowly between 400 and 700°C after 12 h soakat 400°C; powder X-ray diffraction;

Reference： [1]Blachnik; Muller [Thermochimica Acta, 2000, vol. 361, # 1-2, p. 31 - 52]
[2]Hyett, Geoffrey; Barrier, Nicolas; Clarke, Simon J.; Hadermann, Joke [Journal of the American Chemical Society, 2007, vol. 129, # 36, p. 11192 - 11201]

2
[ 10544-50-0 ]
copper [ No CAS ]
[ 1317-40-4 ]

Reference： [1]Journal of the American Chemical Society,1990,vol. 112,p. 4043 - 4044

3
[ 10544-50-0 ]
bis(η5-i-propylcyclopentadienyl) titanium (III) chloride dimer [ No CAS ]
[ 12130-65-3 ]
bis(η5-i-propylcyclopentadienyl) titana (TiIV) cyclohexasulfane [ No CAS ]

Yield	Reaction Conditions	Operation in experiment
1: 49% 2: 51%	In tetrahydrofuran adding ((iPrCp)2TiCl)2 in THF to freshly sublimated S8 under stirring at room temp. , react. time: 3d ; argon atmosphere, equil.; flash chromatography, elem. anal.;

Reference： [1]Tainturier, G.; Gautheron, B. [Phosphorus and Sulfur and the Related Elements, 1988, vol. 36, p. 11 - 14]

4
triammonium 1,3,5,2,4,6-trithiatriazine-1,1,3,3,5,5-hexoxide [ No CAS ]
[ 10544-50-0 ]
thionyl imide [ No CAS ]
[ 7803-58-9 ]

Reference： [1]Monatshefte fur Chemie,
Monatshefte fuer Chemie,1973,vol. 104,p. 1131 - 1138
[2]Gmelin Handbuch der Anorganischen Chemie,Gmelin Handbook: S: S-N-Verb.1, 1.8, page 8 - 9

5
[ 10544-50-0 ]
[ 2273-43-0 ]
[ 4559-70-0 ]
{(n-BuSn(S)(O₂PPh₂))3O}2Sn [ No CAS ]

Reference： [1]Journal of the American Chemical Society,1988,vol. 110,p. 7543 - 7544

6
[ 10544-50-0 ]
[ 18421-48-2 ]
[ 201230-82-2 ]
PtCl(C₆H₅CO)(P(C₆H₅)3)(CO) [ No CAS ]
[ 3878-45-3 ]

Reference： [1]Organometallics,1990,vol. 9,p. 2612 - 2620

7
[ 14973-89-8 ]
[ 10544-50-0 ]
4Rh⁽¹⁺⁾*4P(C₆H₅)3*4S₃*4Br^(1-)={Rh(P(C₆H₅)3)(S₃)Br}4 [ No CAS ]

Yield	Reaction Conditions	Operation in experiment
	In benzene standing in benzene at room temp.; pptd.;

Reference： [1]Ginsberg; Lindsell; Sprinkle; West; Cohen [Inorganic Chemistry, 1982, vol. 21, # 10, p. 3666 - 3681] [Gmelin Handbuch der Anorganischen Chemie, Gmelin Handbook: Rh: SVol.B3, 4.24.11, page 145 - 147]

8
[ 10544-50-0 ]
[ 14760-22-6 ]
[ 22693-41-0 ]
[ 999-97-3 ]
((iron)4(sulfur)4((2,4,6-triisopropylphenyl)thiolate)2((N,N,N',N'-tetramethylthiourea)2)) [ No CAS ]

Reference： [1]Journal of the American Chemical Society,2003,vol. 125,p. 4052 - 4053

9
[ 10544-50-0 ]
[ 11136-36-0 ]
bis(η5-pentamethylcyclopentadienyl)(trisulfido)titanium(IV) [ No CAS ]

Reference： [1]Organometallics,1984,vol. 3,p. 1823 - 1829

10
[ 10544-50-0 ]
[ 13463-40-6 ]
[ 68-05-3 ]
Fe(C₄H₈O)6⁽²⁺⁾*Fe₄S₄I₄^(2-)*4C₄H₈O={Fe(C₄H₈O)6}{Fe₄S₄I₄}*4C₄H₈O [ No CAS ]

Reference： [1]Zeitschrift fur Naturforschung, Teil B: Anorganische Chemie, Organische Chemie,1985,vol. 40,p. 1105 - 1112

11
[ 10544-50-0 ]
[ 16940-66-2 ]
[ 55124-35-1 ]

Yield	Reaction Conditions	Operation in experiment
95%	With di-i-propylamine In acetone to NaBH4 in a flask is added a mixt. of acetonitrile and i-Pr2NH, then slowly sulfur is added (15 h, 60°C); amine and acetone are removed, elem. anal.;

Reference： [1]Binder, Herbert; Diamantikos, Wassilios [Zeitschrift fur Naturforschung, Teil B: Anorganische Chemie, Organische Chemie, 1983, vol. 38, # 2, p. 203 - 207]

12
[ 10544-50-0 ]
[ 7632-51-1 ]
[ CAS Unavailable ]
[ 18891-71-9 ]
[ 18822-50-9 ]

Yield	Reaction Conditions	Operation in experiment
0%	In not given sublimation in a high-vac.;;

Reference： [1]Preuss, Fritz; Noichl, Harald [Zeitschrift fur Naturforschung, B: Chemical Sciences, 1987, vol. 42, # 2, p. 121 - 129]

13
[ 10544-50-0 ]
lithium triethyl borodeuteride [ No CAS ]
[ 36995-20-7 ]
{5,10,15,20-tetrakis(p-methoxyphenyl)porphyrinato}(deuteriosulfido)iron(III) [ No CAS ]

Yield	Reaction Conditions	Operation in experiment
	In tetrahydrofuran; 1,1,2-trichloroethane an excess of a soln. containing Li2S (prepd. from 1 equiv of sulfur and 2 equiv of LiBEt3D in THF) was added to Fe(porphyrinato)Cl in dry CHCl2CH2Cl under N2; structure of the resulting complex was confirmed by (1)H NMR spectroscopy;

Reference： [1]English, Daniel R.; Hendrickson, David N.; Suslick, Kenneth S. [Journal of the American Chemical Society, 1984, vol. 106, p. 7258 - 7259]

14
[ 10544-50-0 ]
[ 39836-45-8 ]
[ 3244-41-5 ]
3Co⁽³⁺⁾*3C₆H₄CHNC₆H₄CHNC₆H₄O₂^(2-)*3S₂^(1-)*3C₄H₈O*K⁽¹⁺⁾*B(C₆H₅)4^(1-)={(Co(C₆H₄CHNC₆H₄CHNC₆H₄O₂)S₂(C₄H₈O))3K}B(C₆H₅)4 [ No CAS ]

Reference： [1]Journal of the Chemical Society, Dalton Transactions,1987,p. 1367 - 1376

15
[ 10544-50-0 ]
[ 15604-36-1 ]
[ 152076-40-9 ]
{(1R,1'S)-2,6-bis{1-(diphenylphosphino)ethyl}phenyl}chloroplatinum(II) [ No CAS ]

Reference： [1]Organometallics,1994,vol. 13,p. 43 - 54

16
[ 10544-50-0 ]
[ 68-05-3 ]
[ 930-69-8 ]
ferrous iodide [ No CAS ]
[ 94499-94-2 ]

Reference： [1]Journal of the American Chemical Society,1985,vol. 107,p. 953 - 961

17
[ 14973-89-8 ]
[ 10544-50-0 ]
[ 82522-29-0 ]

Yield	Reaction Conditions	Operation in experiment
75%	In benzene (N2 or Ar); S8 soln. added to complex soln., left at room temp. for 12 h; filtered, concd. (vac.), pptd. (Et2O), re-pptd. from C6H6 with ether, washed with ether, dried at 82°C (vac.); elem. anal.;

Reference： [1]Ginsberg; Lindsell; Sprinkle; West; Cohen [Inorganic Chemistry, 1982, vol. 21, # 10, p. 3666 - 3681]

18
[ 10544-50-0 ]
[ 161727-97-5 ]
[ 22693-41-0 ]
[ 999-97-3 ]
(Fe4S3(N(SiMe3)2)(tetramethylthiourea))2(μ6-S)(μ-N(SiMe3)2)2 [ No CAS ]

Reference： [1]Journal of the American Chemical Society,2003,vol. 125,p. 4052 - 4053

19
[ 10544-50-0 ]
[ 11136-36-0 ]
[ 486420-92-2 ]
[ 486420-94-4 ]

Reference： [1]Chemical Communications,2002,p. 1918 - 1919
[2]Bulletin of the Chemical Society of Japan,2003,vol. 76,p. 1043 - 1054

20
[ 10544-50-0 ]
[ 11136-36-0 ]
[ 486420-93-3 ]
[ 486421-00-5 ]

Reference： [1]Chemical Communications,2002,p. 1918 - 1919
[2]Bulletin of the Chemical Society of Japan,2003,vol. 76,p. 1043 - 1054

21
[ 10544-50-0 ]
[ 14760-22-6 ]
[ 22693-41-0 ]
[ 999-97-3 ]
(Fe4S3(N(SiMe3)2)(tetramethylthiourea))2(μ6-S)(μ-N(SiMe3)2)2 [ No CAS ]

Reference： [1]Journal of the American Chemical Society,2003,vol. 125,p. 4052 - 4053

22
[ 10544-50-0 ]
[ 72954-06-4 ]
[ 72954-09-7 ]

Yield	Reaction Conditions	Operation in experiment
95%	In dichloromethane N2-atmosphere; elem. anal.;

Reference： [1]Honeyman, Charles H.; Foucher, Daniel A.; Dahmen, Francisco Y.; Rulkens, Rudy; Lough, Alan J.; Manners, Ian [Organometallics, 1995, vol. 14, # 12, p. 5503 - 5512]

23
[ 10544-50-0 ]
[ 12030-24-9 ]
[ 7440-02-0 ]
[ 10424-38-1 ]
[Ni(1,2-diaminopropane)3]0.5[InS₂] [ No CAS ]

Yield	Reaction Conditions	Operation in experiment
47%	In water High Pressure; In2S3, Ni, S8, diamine and H2O were placed in a thick Pyrex tube, the sealed tube was heated at 157°C for 6 days; crystals were washed with ethanol and diethyl ether, dried, stored undervac.; elem. anal.;

Reference： [1]Zhou, Jian; Bian, Guo-Qing; Zhang, Yong; Zhu, Qin-Yu; Li, Chun-Yin; Dai, Jie [Inorganic Chemistry, 2007, vol. 46, # 16, p. 6347 - 6352]

24
[ 10544-50-0 ]
[ 2782-91-4 ]
Fe3(N(SiMe3)2)2(μ-S(2,4,6-(i)Pr3C6H3)4*toluene [ No CAS ]
[(N(SiMe3)2)(tetramethylthiourea)Fe4S3]2(μ6-S)(.mu-N(SiMe3)2)2*toluene [ No CAS ]

Yield	Reaction Conditions	Operation in experiment
73%	With HS(2,4,6-(i)Pr₃C₆H₂) In toluene (N2 or Ar); addn. of a soln. of tetramethylthiourea in toluene to a soln. of Fe complex in toluene, addn. of a soln. of thiol in toluene, addn. of a soln. of S8 in toluene, stirring at 30°C for 12 h, standing at room temp.;

Reference： [1]Ohki, Yasuhiro; Imada, Motosuke; Murata, Ayuro; Sunada, Yusuke; Ohta, Shun; Honda, Masaru; Sasamori, Takahiro; Tokitoh, Norihiro; Katada, Motomi; Tatsumi, Kazuyuki [Journal of the American Chemical Society, 2009, vol. 131, # 36, p. 13168 - 13178]

25
[ 10544-50-0 ]
[ 557-34-6 ]
[ 638-39-1 ]
[ 13395-16-9 ]
copper zinc tin sulfide [ No CAS ]

Reference： [1]Journal of the American Chemical Society,2009,vol. 131,p. 12054 - 12055

26
[ 10544-50-0 ]
[ 59831-02-6 ]
tetraethylammonium stanna-closo-dodecaborate [ No CAS ]
[Et₄N]2[Pd(dppp)(SSnB₁₁H₁₁)2] [ No CAS ]

Yield	Reaction Conditions	Operation in experiment
59.4%	In acetonitrile byproducts: Cl(1-); (Ar, exclusion of light, Schlenk technique); stirring suspn. of sulfur and stannadodecaborate deriv. in CH3CN for 24 h, addn. of palladium compd., stirring for 24 h; slow diffusion of diethyl ether, isolation of crystals, elem. anal.;

Reference： [1]Dimmer, Joerg-Alexander; Hornung, Martin; Weigend, Florian; Wesemann, Lars [Dalton Transactions, 2010, vol. 39, # 32, p. 7504 - 7512]

27
copper(II) choride dihydrate [ No CAS ]
[ 15718-46-4 ]
[ 10544-50-0 ]
[ 1269634-02-7 ]
(9[Cu(bis(2-pyrimidyl)trisulfide)(chloride)2]2*[Cu(bis(2-pyrimidyl)disulfide)(chloride)2]2) [ No CAS ]

Yield	Reaction Conditions	Operation in experiment
1: 8% 2: 40%	In dichloromethane; acetonitrile byproducts: SO4(2-); other Radiation; mixing Cu compd., S compd. in CH2Cl2/MeCN (1:1), sealing in autoclave, irradiation in microwave oven (2*800 W, 2.45 GHz), heating to 90°Cin 20 min, storage for 1 h, various times (1 h or 3-20 h), various temp . (60 or 90°C); slow cooling to room temp. over 9 h, isolation of crystals after storageat 0°C for 2 weeks, manually separation of crystals, washing wit h Et2O, air drying, elem. anal.;

Reference： [1]Delgado, Salome; Gallego, Almudena; Castillo, Oscar; Zamora, Felix [Dalton Transactions, 2011, vol. 40, # 4, p. 847 - 852]

28
copper(II) choride dihydrate [ No CAS ]
[ 15718-46-4 ]
[ 10544-50-0 ]
[ 1269634-02-7 ]

Yield	Reaction Conditions	Operation in experiment
51%	In dichloromethane; acetonitrile byproducts: SO4(2-); High Pressure; mixing Cu compd., S compd. in CH2Cl2/MeCN (1:1), stirring at room temp. for 30 min, sealing in autoclave, heating at 90°C for 20 h, various temp. (60 or 90°C), various times (1 h or 3-20 h); slow cooling (2.5°C/h) to ambient temp., isolation of crystals after storage at 0°C for 2 weeks, washing with Et2O, air drying, elem. anal.;

Reference： [1]Delgado, Salome; Gallego, Almudena; Castillo, Oscar; Zamora, Felix [Dalton Transactions, 2011, vol. 40, # 4, p. 847 - 852]

29
copper dichloride [ No CAS ]
[ 15718-46-4 ]
[ 10544-50-0 ]
[ 820978-24-3 ]

Yield	Reaction Conditions	Operation in experiment
	In dichloromethane; acetonitrile High Pressure; Schlenk techniques; mixing Cu compd., S compd. in CH2Cl2/MeCN, sealing in autoclave, heating at 90°C for 20 h;

Reference： [1]Delgado, Salome; Gallego, Almudena; Castillo, Oscar; Zamora, Felix [Dalton Transactions, 2011, vol. 40, # 4, p. 847 - 852]

30
[ 10544-50-0 ]
[ 36995-20-7 ]
[ 92763-27-4 ]
μ-,10,15,20-tetrakis(p-methoxyphenyl)porphyrinato}iron(III)} [ No CAS ]

Yield	Reaction Conditions	Operation in experiment
0%	With LiB(C₂H₅)3H In tetrahydrofuran; 1,1,2-trichloroethane an excess of a soln. containing Li2S (prepd. from 1 equiv of sulfur and 2 equiv of LiBEt3H in THF) was added to Fe(porphyrinato)Cl in dry CHCl2CH2Cl under N2; no bridged sulfide complex was observed; the solvent was immediately pulled off in vacuo at room temp., the residue taken into an inert atmosphere box, dissolved in CH2Cl2, filtered through a plug of Celite, filtrate was concd. with concominant addn. of hexane, crystals were dried in vacuo;

Reference： [1]English, Daniel R.; Hendrickson, David N.; Suslick, Kenneth S. [Journal of the American Chemical Society, 1984, vol. 106, p. 7258 - 7259]

31
[ 10544-50-0 ]
[ 14174-08-4 ]
sodium amalgam [ No CAS ]
(K[Mo⁽¹³⁾C(N(CH₃(C⁽²⁾H₃)2C)(C₆H₃(CH₃)2))3])2 [ No CAS ]
Na⁽¹⁺⁾*2(C₄H₄(C₂O)(C₂H₄O)3)*[Mo⁽¹³⁾CS(N(CH₃(C⁽²⁾H₃)2C)(C₆H₃(CH₃)2))3]^(1-)=[Na(C₂₄H₃₂O₈)][Mo⁽¹³⁾CS(N(C₄H₃⁽²⁾H₆)(C₈H₉))3] [ No CAS ]

Reference： [1]Journal of the American Chemical Society,2001,vol. 123,p. 5003 - 5013

32
[ 10544-50-0 ]
[ 14760-22-6 ]
[ 2782-91-4 ]
[ 108-88-3 ]
[(N(SiMe3)2)(tetramethylthiourea)Fe4S3]2(μ6-S)(.mu-N(SiMe3)2)2*toluene [ No CAS ]

Yield	Reaction Conditions	Operation in experiment
82%	With HS(2,4,6-(i)Pr₃C₆H₂) In toluene (N2 or Ar); addn. of a soln. of tetramethylthiourea in toluene to Fe compd., addn. of a soln. of thiol in toluene, addn. of a soln. of S8 in toluene, stirring at 30°C for 12 h, standing at room temp. for 10 d; sepn. of crystals, washing with hexane, drying in vac.; elem. anal.;

33
[ 10544-50-0 ]
[ 19190-91-1 ]
[ 117056-97-0 ]

Reference： [1]European Journal of Inorganic Chemistry,2013,p. 427 - 437

34
[ 10544-50-0 ]
[ 90272-84-7 ]
[ 1431880-00-0 ]

Reference： [1]Chemical Communications,2013,vol. 49,p. 4343 - 4345

35
[ 10544-50-0 ]
[ 583-60-8 ]
[ 105-56-6 ]
[ 95211-67-9 ]

Yield	Reaction Conditions	Operation in experiment
	With 4-methyl-morpholine In neat (no solvent) at 75℃; for 1h;	General Procedure for the Preparation of Alkyl 2-Aminobenzo[b]thiophene-3-carboxylates 7a-j. General procedure: A mixture of cyclohexanone (0.196 g,2.0 mmol), methyl cyanoacetate (0.198 g, 2.0 mmol),elemental sulfur (0.064 g, 2.0 mmol) and morpholine (0.174g, 2.0 mmol) was heated at 75 °C for 1 h. After nearlycomplete conversion to the corresponding 2-aminothiophene, as was indicated by TLC monitoring, thereaction mixture was cooled to r.t. and the solid residue was recrystallized from EtOH to afford methyl 2-amino-4,5,6,7-tetrahydrobenzo[b]thiophene-3-carboxylate (6a). Then asolution of 6a (0.211 g, 1 mmol) in benzonitrile (2 mL) was heated within a flask equipped with an air-filled balloon at 200 °C for 24 h in a silicone oil bath. Progress of the reaction was monitored by TLC. After completion of the reaction, the mixture was cooled to r.t. and the excess of benzonitrile was removed under the reduced pressure. The crude product was purified by column chromatography using n-hexane-EtOAc(8:1) as eluent. The solvent was evaporated under the reduced pressure and the residue was crystallized from nhexane-EtOAc (5:1) to afford the pure product 7a as paleyellow crystals.

Reference： [1]Adib, Mehdi; Bayanati, Maryam; Soheilizad, Mehdi; Ghazvini, Helia Janatian; Tajbakhsh, Mahmood; Amanlou, Massoud [Synlett, 2014, vol. 25, # 20, p. 2918 - 2922]

36
[ 10544-50-0 ]
[ 108-94-1 ]
[ 105-34-0 ]
[ 108354-78-5 ]

Yield	Reaction Conditions	Operation in experiment
	With 4-methyl-morpholine; In neat (no solvent); at 75℃; for 1h;	General procedure: A mixture of cyclohexanone (0.196 g,2.0 mmol), methyl cyanoacetate (0.198 g, 2.0 mmol),elemental sulfur (0.064 g, 2.0 mmol) and morpholine (0.174g, 2.0 mmol) was heated at 75 C for 1 h. After nearlycomplete conversion to the corresponding 2-aminothiophene, as was indicated by TLC monitoring, thereaction mixture was cooled to r.t. and the solid residue was recrystallized from EtOH to afford methyl 2-amino-4,5,6,7-tetrahydrobenzo[b]thiophene-3-carboxylate (6a). Then asolution of 6a (0.211 g, 1 mmol) in benzonitrile (2 mL) was heated within a flask equipped with an air-filled balloon at 200 C for 24 h in a silicone oil bath. Progress of the reaction was monitored by TLC. After completion of the reaction, the mixture was cooled to r.t. and the excess of benzonitrile was removed under the reduced pressure. The crude product was purified by column chromatography using n-hexane-EtOAc(8:1) as eluent. The solvent was evaporated under the reduced pressure and the residue was crystallized from nhexane-EtOAc (5:1) to afford the pure product 7a as paleyellow crystals.

Reference： [1]Synlett,2014,vol. 25,p. 2918 - 2922

37
[ 10544-50-0 ]
tin(II) iodide [ No CAS ]
[ 598-54-9 ]
[ 557-05-1 ]
mohite [ No CAS ]
CZTS [ No CAS ]

Yield	Reaction Conditions	Operation in experiment
		General procedure: All the chemicals were analytical-grade reagents and were used without further purification. In a typical synthesis, 122.6 mg <strong>[598-54-9]copper(I) acetate</strong> (Cu(Ac)), 347.7 mg Zinc stearate (ZNO) and 186.3 mg Tin(II) iodide (SnI2) were added into a 50 mL three-neck flask containing30 mL of Hexane, and then 2mL oleylamine (OLA) and 2mL oleic acid (OA) was added. The mixture was degassed under vacuum for 10 min and then purged with nitrogen for 10 min. After that, the mixture was heated to 65 C forming a transparent solution. A mixture of elemental sulfur powder (S) (4 mmol) and OLA(4 mL) separately were loaded into a 25 mL three-neck flask and heated to 130 C maintaining for 30 min to obtain a brown OLA-S solution under nitrogen atmosphere. When the solution was cooled down to 65 C naturally, it was rapidly injected into the mixture. After the injection, the mixture turned to black and formed a colloidal solution. The colloidal solution was transferred into a 50 mL Teflon-lined stainless-steel autoclave. After being sealed, the autoclave was maintained at 200 C for 24 h in a heating furnace, and then the furnace was cooled down to 60 C naturally.Then the solution was added into a mixture of toluene and isopropanol(1:1) to precipitate the product. The black precipitate CZTS nanoparticles were centrifuged several times at 7000 rpm for 5 min to ensure removal all of the excess capping agent. After then,the CZTS nanocrystals were dispersed in toluene for the further study.

Reference： [1]Journal of Alloys and Compounds,2016,vol. 663,p. 617 - 623

38
[ 10544-50-0 ]
tin(II) iodide [ No CAS ]
[ 598-54-9 ]
[ 557-05-1 ]
CZTS [ No CAS ]

Yield	Reaction Conditions	Operation in experiment
		General procedure: All the chemicals were analytical-grade reagents and were used without further purification. In a typical synthesis, 122.6 mg <strong>[598-54-9]copper(I) acetate</strong> (Cu(Ac)), 347.7 mg Zinc stearate (ZNO) and 186.3 mg Tin(II) iodide (SnI2) were added into a 50 mL three-neck flask containing30 mL of Hexane, and then 2mL oleylamine (OLA) and 2mL oleic acid (OA) was added. The mixture was degassed under vacuum for 10 min and then purged with nitrogen for 10 min. After that, the mixture was heated to 65 C forming a transparent solution. A mixture of elemental sulfur powder (S) (4 mmol) and OLA(4 mL) separately were loaded into a 25 mL three-neck flask and heated to 130 C maintaining for 30 min to obtain a brown OLA-S solution under nitrogen atmosphere. When the solution was cooled down to 65 C naturally, it was rapidly injected into the mixture. After the injection, the mixture turned to black and formed a colloidal solution. The colloidal solution was transferred into a 50 mL Teflon-lined stainless-steel autoclave. After being sealed, the autoclave was maintained at 200 C for 24 h in a heating furnace, and then the furnace was cooled down to 60 C naturally.Then the solution was added into a mixture of toluene and isopropanol(1:1) to precipitate the product. The black precipitate CZTS nanoparticles were centrifuged several times at 7000 rpm for 5 min to ensure removal all of the excess capping agent. After then,the CZTS nanocrystals were dispersed in toluene for the further study.

Reference： [1]Journal of Alloys and Compounds,2016,vol. 663,p. 617 - 623

39
[ 10544-50-0 ]
stannous Stearate [ No CAS ]
[ 598-54-9 ]
[ 557-05-1 ]
CZTS [ No CAS ]

Yield	Reaction Conditions	Operation in experiment
		General procedure: All the chemicals were analytical-grade reagents and were used without further purification. In a typical synthesis, 122.6 mg <strong>[598-54-9]copper(I) acetate</strong> (Cu(Ac)), 347.7 mg Zinc stearate (ZNO) and 186.3 mg Tin(II) iodide (SnI2) were added into a 50 mL three-neck flask containing30 mL of Hexane, and then 2mL oleylamine (OLA) and 2mL oleic acid (OA) was added. The mixture was degassed under vacuum for 10 min and then purged with nitrogen for 10 min. After that, the mixture was heated to 65 C forming a transparent solution. A mixture of elemental sulfur powder (S) (4 mmol) and OLA(4 mL) separately were loaded into a 25 mL three-neck flask and heated to 130 C maintaining for 30 min to obtain a brown OLA-S solution under nitrogen atmosphere. When the solution was cooled down to 65 C naturally, it was rapidly injected into the mixture. After the injection, the mixture turned to black and formed a colloidal solution. The colloidal solution was transferred into a 50 mL Teflon-lined stainless-steel autoclave. After being sealed, the autoclave was maintained at 200 C for 24 h in a heating furnace, and then the furnace was cooled down to 60 C naturally.Then the solution was added into a mixture of toluene and isopropanol(1:1) to precipitate the product. The black precipitate CZTS nanoparticles were centrifuged several times at 7000 rpm for 5 min to ensure removal all of the excess capping agent. After then,the CZTS nanocrystals were dispersed in toluene for the further study.

Reference： [1]Journal of Alloys and Compounds,2016,vol. 663,p. 617 - 623

40
[ 10544-50-0 ]
[ 638-39-1 ]
[ 598-54-9 ]
[ 557-05-1 ]
CZTS [ No CAS ]

Yield	Reaction Conditions	Operation in experiment
		General procedure: All the chemicals were analytical-grade reagents and were used without further purification. In a typical synthesis, 122.6 mg <strong>[598-54-9]copper(I) acetate</strong> (Cu(Ac)), 347.7 mg Zinc stearate (ZNO) and 186.3 mg Tin(II) iodide (SnI2) were added into a 50 mL three-neck flask containing30 mL of Hexane, and then 2mL oleylamine (OLA) and 2mL oleic acid (OA) was added. The mixture was degassed under vacuum for 10 min and then purged with nitrogen for 10 min. After that, the mixture was heated to 65 C forming a transparent solution. A mixture of elemental sulfur powder (S) (4 mmol) and OLA(4 mL) separately were loaded into a 25 mL three-neck flask and heated to 130 C maintaining for 30 min to obtain a brown OLA-S solution under nitrogen atmosphere. When the solution was cooled down to 65 C naturally, it was rapidly injected into the mixture. After the injection, the mixture turned to black and formed a colloidal solution. The colloidal solution was transferred into a 50 mL Teflon-lined stainless-steel autoclave. After being sealed, the autoclave was maintained at 200 C for 24 h in a heating furnace, and then the furnace was cooled down to 60 C naturally.Then the solution was added into a mixture of toluene and isopropanol(1:1) to precipitate the product. The black precipitate CZTS nanoparticles were centrifuged several times at 7000 rpm for 5 min to ensure removal all of the excess capping agent. After then,the CZTS nanocrystals were dispersed in toluene for the further study.

Reference： [1]Journal of Alloys and Compounds,2016,vol. 663,p. 617 - 623

41
[ 10544-50-0 ]
[ 1271-19-8 ]
[ 33120-66-0 ]
[Cp₂Ti(tBu-1,3-thiazoline-2-thione-4,5-dithiolate)] [ No CAS ]

Yield	Reaction Conditions	Operation in experiment
68%		Under inert atmosphere at 10 C, LDA was prepared by adding BuLi (2.7 mL, 4.3 mmol, 1.6 M in hexanes) to a solution of diisopropylamine (0.4 mL, 4.3 mmol) in 15 mL of anhydrous THF. The LDA solution was then added to a solution of 1,3-thiazoline-2-thione 1 (0.50 g, 2.8 mmol) of 1,3- thiazoline -2-thione 1 dissolved in 40 mLof anhydrous THF. After stirring for 30 min at 10 C, sulfur (S8,0.14 g, 4.3 mmol) was added and the solution was stirred for anadditional 30 min. A solution of 5.7 mmol of LDA was added to the reaction medium and after 3 h of stirring sulfur (0.19 g, 5.7 mmol)was added. After 30 min of stirring Cp2TiCl2 (1.1 g, 4.3 mmol) was added and the reaction mixture was stirred for 15 h. The solventwas evaporated and the residue was extracted with dichloromethane. The organic phase was washed with water and then driedover MgSO4. The resulting solid was purified by column chromatography using dichloromethane as eluent. Cp2Ti(tBu-thiazdt) 2 was isolated as a blue powder (m 0.78 g). in 68% yield,mp 148 C. Rf 0.72, (SiO2, CH2Cl2). 1H NMR (300 MHz) d 1.91 (s,9H, CH3), 5.57 (s, 5H, Cp), 6.09 (s, 5H, Cp); 13C NMR (75 MHz) d 30.5(CeCH3), 68.4 (CeCH3), 107.5 (Cp), 111.6 (Cp), 135.8 (C]C), 147.8(C]C), 193.5 (C]S); HRMS (ASAP) calcd for [MH] C17H20NS4Ti:413.99526 Found: 413.9953. Anal calcd for C17H19NS4Ti: C, 47.38; H,4.63; N, 3.39. Found: C, 47.17; H, 4.47; N, 3.55.

Reference： [1]Journal of Organometallic Chemistry,2016,vol. 819,p. 182 - 188

42
[ 10544-50-0 ]
[ 1271-19-8 ]
[ 33120-66-0 ]
[ 74-88-4 ]
[Cp₂Ti(2-MeS-1,3-thiazole-4,5-dithiolate)] [ No CAS ]

Yield	Reaction Conditions	Operation in experiment
56%		General procedure: Under inert atmosphere at 10 C, LDA was prepared by adding BuLi (2.7 mL, 4.3 mmol, 1.6 M in hexanes) to a solution of diisopropylamine (0.4 mL, 4.3 mmol) in 15 mL of anhydrous THF. The LDA solution was then added to a solution of 1,3-thiazoline-2-thione 1 (0.50 g, 2.8 mmol) of 1,3- thiazoline -2-thione 1 dissolved in 40 mLof anhydrous THF. After stirring for 30 min at 10 C, sulfur (S8,0.14 g, 4.3 mmol) was added and the solution was stirred for anadditional 30 min. A solution of 5.7 mmol of LDA was added to the reaction medium and after 3 h of stirring sulfur (0.19 g, 5.7 mmol)was added. After 30 min of stirring Cp2TiCl2 (1.1 g, 4.3 mmol) was added and the reaction mixture was stirred for 15 h. The solvent was evaporated and the residue was extracted with dichloromethane. The organic phase was washed with water and then dried over MgSO4. The resulting solid was purified by column chromatography using dichloromethane as eluent.

Reference： [1]Journal of Organometallic Chemistry,2016,vol. 819,p. 182 - 188

43
[ 75-15-0 ]
[ 86749-03-3 ]
[ 10544-50-0 ]
[ 2268-77-1 ]