Alternatived Products of [ 1092491-37-6 ]
Product Details of [ 1092491-37-6 ]
CAS No. : | 1092491-37-6 |
MDL No. : | N/A |
Formula : |
C29H22F12NOP
|
Boiling Point : |
- |
Linear Structure Formula : | - |
InChI Key : | BWFJKDQRRFAXAO-HSZRJFAPSA-N |
M.W : |
659.45
|
Pubchem ID : | 154728631 |
Synonyms : |
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Safety of [ 1092491-37-6 ]
Application In Synthesis of [ 1092491-37-6 ]
* All experimental methods are cited from the reference, please refer to the original source for details. We do not guarantee the accuracy of the content in the reference.
- Downstream synthetic route of [ 1092491-37-6 ]
- 1
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[ 154701-60-7 ]
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[ 142421-57-6 ]
-
[ 1092491-37-6 ]
Yield | Reaction Conditions | Operation in experiment |
75.5% |
Stage #1: 2-(2-bromophenyl)-4-(1,1-dimethylethyl)-4,5-dihydro-(4S)-oxazole With tert.-butyl lithium In diethyl ether; pentane at -78℃; for 1h; Inert atmosphere;
Stage #2: bis(3,5-di(trifluoromethyl)phenyl)chlorophosphine In diethyl ether; pentane at -78 - 20℃; for 1h; Inert atmosphere; |
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|
Stage #1: 2-(2-bromophenyl)-4-(1,1-dimethylethyl)-4,5-dihydro-(4S)-oxazole With tert.-butyl lithium In diethyl ether at -78℃; for 1h; Inert atmosphere;
Stage #2: bis(3,5-di(trifluoromethyl)phenyl)chlorophosphine In diethyl ether at -78 - 20℃; Inert atmosphere; |
|
Reference:
[1]Adamson, Nathan J.; Hull, Ethan; Malcolmson, Steven J.
[Journal of the American Chemical Society, 2017, vol. 139, # 21, p. 7180 - 7183]
[2]Garcia-Fortanet, Jorge; Buchwald, Stephen L.
[Angewandte Chemie - International Edition, 2008, vol. 47, # 42, p. 8108 - 8111]