Home Cart Sign in  
HazMat Fee +

There will be a HazMat fee per item when shipping a dangerous goods. The HazMat fee will be charged to your UPS/DHL/FedEx collect account or added to the invoice unless the package is shipped via Ground service. Ship by air in Excepted Quantity (each bottle), which is up to 1g/1mL for class 6.1 packing group I or II, and up to 25g/25ml for all other HazMat items.

Type HazMat fee for 500 gram (Estimated)
Excepted Quantity USD 0.00
Limited Quantity USD 15-60
Inaccessible (Haz class 6.1), Domestic USD 80+
Inaccessible (Haz class 6.1), International USD 150+
Accessible (Haz class 3, 4, 5 or 8), Domestic USD 100+
Accessible (Haz class 3, 4, 5 or 8), International USD 200+
Chemical Structure| 1099660-67-9 Chemical Structure| 1099660-67-9

Structure of 1099660-67-9

Chemical Structure| 1099660-67-9

*Storage: {[sel_prStorage]}

*Shipping: {[sel_prShipping]}

,{[proInfo.pro_purity]}

4.5 *For Research Use Only !

{[proInfo.pro_purity]}
Cat. No.: {[proInfo.prAm]} Purity: {[proInfo.pro_purity]}

Change View

Size Price VIP Price

US Stock

Global Stock

In Stock
{[ item.pr_size ]} Inquiry {[ getRatePrice(item.pr_usd,item.pr_rate,item.mem_rate,item.pr_is_large_size_no_price, item.vip_usd) ]}

US Stock: ship in 0-1 business day
Global Stock: ship in 5-7 days

  • {[ item.pr_size ]}

In Stock

- +

Please Login or Create an Account to: See VIP prices and availability

US Stock: ship in 0-1 business day
Global Stock: ship in 2 weeks

  • 1-2 Day Shipping
  • High Quality
  • Technical Support
Product Citations

Alternative Products

Product Details of [ 1099660-67-9 ]

CAS No. :1099660-67-9
Formula : C8H6ClFO4S
M.W : 252.65
SMILES Code : O=C(OC)C1=CC=C(F)C(S(=O)(Cl)=O)=C1
MDL No. :MFCD11650667

Safety of [ 1099660-67-9 ]

GHS Pictogram:
Signal Word:Danger
Hazard Statements:H314
Precautionary Statements:P260-P264-P280-P301+P330+P331-P303+P361+P353-P304+P340-P305+P351+P338-P310-P363-P405-P501
Class:8
UN#:3261
Packing Group:

Application In Synthesis of [ 1099660-67-9 ]

* All experimental methods are cited from the reference, please refer to the original source for details. We do not guarantee the accuracy of the content in the reference.

  • Downstream synthetic route of [ 1099660-67-9 ]

[ 1099660-67-9 ] Synthesis Path-Downstream   1~1

  • 1
  • [ 369-26-6 ]
  • [ 1099660-67-9 ]
YieldReaction ConditionsOperation in experiment
Into a 100-mL round-bottom flask, was placed <strong>[369-26-6]methyl 3-amino-4-fluorobenzoate</strong> (1 g, 5.91 mmol), HCl (6 M, 10 mL). This was followed by the addition of a solution of NaNO2 (630 mg, 9.13 mmol) in water (2 mL) dropwise with stirring at 0oC. The resulting solution was stirred for 20 min at 0oC. The above mixture was added to a saturated solution of SO2 in AcOH (20 mL) and CuCl2 (800 mg, 5.95 mmol) dropwise with stirring at 0oC. The resulting solution was stirred for 1 h at RT. The reaction was then quenched by the addition of 20 mL of water. The resulting solution was extracted with 3x20 mL of ethyl acetate and the organic layers combined and dried over anhydrous Na2SO4, then concentrated under vacuum. This resulted in 1.5 g (crude) of the title compound as a yellow oil. The crude product was used in the next step.
 

Historical Records

Technical Information

Categories