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[ CAS No. 110199-18-3 ] {[proInfo.proName]}

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Product Details of [ 110199-18-3 ]

CAS No. :110199-18-3 MDL No. :MFCD06658215
Formula : C9H9NS2 Boiling Point : -
Linear Structure Formula :- InChI Key :IEXSISKCCADMLK-QMMMGPOBSA-N
M.W : 195.30 Pubchem ID :11521249
Synonyms :

Safety of [ 110199-18-3 ]

Signal Word:Warning Class:N/A
Precautionary Statements:P261-P305+P351+P338 UN#:N/A
Hazard Statements:H315-H319-H335 Packing Group:N/A
GHS Pictogram:

Application In Synthesis of [ 110199-18-3 ]

* All experimental methods are cited from the reference, please refer to the original source for details. We do not guarantee the accuracy of the content in the reference.

  • Downstream synthetic route of [ 110199-18-3 ]

[ 110199-18-3 ] Synthesis Path-Downstream   1~14

  • 2
  • [ 171877-37-5 ]
  • [ 110199-18-3 ]
  • 3
  • [ 110-57-6 ]
  • [ 110199-18-3 ]
  • (R)-2-(4'-chlorobut-2'-enylthio)-4-phenyl-Δ2-1,3-thiazolidine-2-thione [ No CAS ]
  • 4
  • [ 110199-18-3 ]
  • [ 63547-24-0 ]
  • [ 827603-88-3 ]
  • [ 827603-84-9 ]
  • 6
  • [ 30426-58-5 ]
  • [ 110199-18-3 ]
  • (R)-N-2-azidoacetyl-4-phenylthiazolidin-2-thione [ No CAS ]
  • 7
  • [ 75-36-5 ]
  • [ 110199-18-3 ]
  • (4R)-N-acetyl-4-phenyl-1,3-thiazolidine-2-thione [ No CAS ]
  • 8
  • [ 1908-90-3 ]
  • [ 1468-39-9 ]
  • [ 1402942-16-8 ]
  • [ 1435664-99-5 ]
  • [ 110199-18-3 ]
  • [ 185137-29-5 ]
  • 9
  • [ 123-62-6 ]
  • [ 110199-18-3 ]
  • [ 1039757-81-7 ]
  • 10
  • [ 123-62-6 ]
  • [ 110199-18-3 ]
  • [ 1217320-19-8 ]
  • 11
  • [ 1908-90-3 ]
  • [ 110199-18-3 ]
  • [ 185137-29-5 ]
  • 12
  • [ 56613-80-0 ]
  • [ 140-89-6 ]
  • [ 110199-18-3 ]
  • [ 171877-37-5 ]
YieldReaction ConditionsOperation in experiment
82%; 10% In ethanol; at 100℃; for 24h;Inert atmosphere; Sealed tube; General procedure: To the mixture of vicinal amino alcohol (1, 1.0 mmol, 1.0 equiv.) in absolute ethanol (2.0 mmol),potassium ethylxanthate (5.0 mmol, 5.0 equiv.) was added quickly. After flushed with N2 for 5 mins,the suspension was sealed and heated in an oil bath at 100 C for 24 hr. The it was cooled down toroom temperature, the mixture was transferred to a 50 mL-round bottom flask, and evaporated underreduced pressure to remove alcohol. Then water (10 mL) was added to the slurry and extracted withethyl acetate (30 mL*3). Combined organic phase was washed with brine (30 mL) and dried overanhydrous Na2SO4. After concentration, the crude product was obtained. Then it was applied onsilica gel for flash chromatography to afford corresponding 1,3-thiazolidine-2-thione (2). For somecases, 1,3-oxazolidine-2-thione (3) was obtained as side product.
  • 13
  • [ 140-89-6 ]
  • [ 171877-37-5 ]
  • [ 110199-18-3 ]
YieldReaction ConditionsOperation in experiment
85% With sodium monohydrogen sulfide x-hydrate; In ethanol; at 100℃; for 24h;Autoclave; Inert atmosphere; Sealed tube; Sodium hydrosulfide hydrate (68~72%, 160 mg, 2.0 mmol) and potassium ethylxanthate (321 mg,2.0 mmol) were added subsequently to the solution of (R)-4-phenyl-1,3-oxazolidine-2-thione (3a,179 mg, 1.0 mmol) in EtOH (abs. 2.0 mL) in a 20 mL-autoclave. It was flushed with N2 for 5 mins and sealed before it was placed in an oil bath at 100 C. After 24 hr, it was cooled down to r.t..EtOAc (50 mL) and H2O (10 mL) was added to the mixture before separation, then the organicphase was washed with H2O (10 mL * 2) and brine (10 mL) before it was dried over anhydrousNa2SO4. After concentration, the residue was purified via flash chromatography (EA/PE = 1:5) toafford (R)-4-phenyl-1,3-thiazolidine-2-thione as a white solid (2a, 166 mg, 0.85 mmol, 85% yield).
  • 14
  • [ 110199-18-3 ]
  • [ 501-52-0 ]
  • C18H17NOS2 [ No CAS ]
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