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Chemical Structure| 111799-94-1 Chemical Structure| 111799-94-1

Structure of 111799-94-1

Chemical Structure| 111799-94-1

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Product Details of [ 111799-94-1 ]

CAS No. :111799-94-1
Formula : C21H18
M.W : 270.37
SMILES Code : CC1=CC=C2C(C3=CC=C(C)C=C3C4=CC=C(C)C=C24)=C1
MDL No. :MFCD04147264

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Application In Synthesis of [ 111799-94-1 ]

* All experimental methods are cited from the reference, please refer to the original source for details. We do not guarantee the accuracy of the content in the reference.

  • Downstream synthetic route of [ 111799-94-1 ]

[ 111799-94-1 ] Synthesis Path-Downstream   1~2

  • 1
  • [ 262373-15-9 ]
  • [ 966-54-1 ]
  • [ 111799-94-1 ]
YieldReaction ConditionsOperation in experiment
With (triphenylphosphine)gold(I) chloride; cesium fluoride; In acetonitrile; at 20℃; for 12h;Inert atmosphere;Catalytic behavior; General procedure: To a solution of Kobayashi's silylaryl triflate 1 (0.60 mmol) in anhydrous acetonitrile (3.0 mL), catalytic PPh3AuCl (32 mg, 0.060 mmol) and CsF (182 mg, 1.2 mmol) were added. The mixture was stirred at 60 C or room temperature for 6 h or 12 h. After removal of the solvent, the residue was then purified by flash column chromatography on silica gel (eluent = hexanes/ethyl acetate 40:1 v/v) to give the desired triphenylene 2.
  • 2
  • [ 57310-39-1 ]
  • [ 966-54-1 ]
  • [ 111799-94-1 ]
 

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