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[ CAS No. 1151548-69-4 ] {[proInfo.proName]}

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Chemical Structure| 1151548-69-4
Chemical Structure| 1151548-69-4
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Product Details of [ 1151548-69-4 ]

CAS No. :1151548-69-4 MDL No. :
Formula : C19H16N2O4 Boiling Point : -
Linear Structure Formula :- InChI Key :-
M.W : 336.34 Pubchem ID :-
Synonyms :

Safety of [ 1151548-69-4 ]

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Precautionary Statements: UN#:
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Application In Synthesis of [ 1151548-69-4 ]

* All experimental methods are cited from the reference, please refer to the original source for details. We do not guarantee the accuracy of the content in the reference.

  • Downstream synthetic route of [ 1151548-69-4 ]

[ 1151548-69-4 ] Synthesis Path-Downstream   1~15

  • 1
  • [ 1151548-69-4 ]
  • [ 482-05-3 ]
  • [ 7732-18-5 ]
  • [ CAS Unavailable ]
  • [ CAS Unavailable ]
YieldReaction ConditionsOperation in experiment
65% With NaOH In water High Pressure; mixt. of Cd(CH3COO)2*2H2O, pmb and bpdc ligands, NaOH, and H2O placed into Teflon-lined reactor and heated at 150°C for 3 d; react. mixt.slowly cooled to room temp.; elem. anal.;
  • 2
  • [ 1151548-69-4 ]
  • [ 100-21-0 ]
  • [ CAS Unavailable ]
  • [ CAS Unavailable ]
YieldReaction ConditionsOperation in experiment
64% With NaOH In water High Pressure; hydrothermal synthesis; Cd(OAc)2, NaOH, 3,5-bis(4-pyridylmethyloxy)benzoic acid, and 1,4-benzenedicarboxylic acid in distd. H2O heated in sealedTeflon-lined stainless steel autoclave at 150°C for 3 d; cooled with 10°C/min to room temp.; elem. anal.;
  • 3
  • [ CAS Unavailable ]
  • [ 1151548-69-4 ]
  • [ 100-21-0 ]
  • [ CAS Unavailable ]
YieldReaction ConditionsOperation in experiment
52% With NaOH In water High Pressure; hydrothermal synthesis; Co(OAc)2, NaOH, 3,5-bis(4-pyridylmethyloxy)benzoic acid, and 1,4-benzenedicarboxylic acid in distd. H2O heated in sealedTeflon-lined stainless steel autoclave at 150°C for 3 d; cooled with 10°C/min to room temp.; elem. anal.;
  • 4
  • [ CAS Unavailable ]
  • [ 1151548-69-4 ]
  • [ 100-21-0 ]
  • [ CAS Unavailable ]
YieldReaction ConditionsOperation in experiment
42.5% With NaOH In water High Pressure; Zn nitrate, two acids (1:1:1) and NaOH in H2O, sealed in stainless-steelcontainer, heated at 150°C for 3 d, cooled down to room temp. at rate 5°C/h; collected, washed with water, dried in air; elem. anal.;
  • 5
  • [ 1151548-69-4 ]
  • [ CAS Unavailable ]
  • [ 1233862-91-3 ]
YieldReaction ConditionsOperation in experiment
36.5% With NaOH In water High Pressure; hydrothermal synthesis; 3,5-bis(pyridin-4-ylmethoxy)benzoic acid, Zn(OAc)2, NaOH, H2O heated in a sealed Teflon-lined stainless steel autoclave at 150°C for 72 h; cooled to room temp. with 5°C/h; washed with distd. H2O; dried in air; elem. anal.;
  • 6
  • [ 1151548-69-4 ]
  • [ CAS Unavailable ]
  • [ CAS Unavailable ]
YieldReaction ConditionsOperation in experiment
42.5% With NaOH In water High Pressure; hydrothermal synthesis; 3,5-bis(pyridin-4-ylmethoxy)benzoic acid, Cd(OAc)2, NaOH, H2O heated in a sealed Teflon-lined stainless steel autoclave at 150°C for 72 h; cooled to room temp. with 5°C/h; washed with distd. H2O; dried in air; elem. anal.;
  • 7
  • [ CAS Unavailable ]
  • [ 1151548-69-4 ]
  • [ 7732-18-5 ]
  • [ CAS Unavailable ]
YieldReaction ConditionsOperation in experiment
38.2% With NaOH In water High Pressure; mixt. heated at 150 °C for 72 h in Teflon-lined stainless steel container; cooled to room temp. (10 °C/h), washed (water), dried in air, elem. anal.;
  • 8
  • [ CAS Unavailable ]
  • [ 1151548-69-4 ]
  • [ 787-70-2 ]
  • [ CAS Unavailable ]
YieldReaction ConditionsOperation in experiment
40.6% With NaOH In water High Pressure; mixt. heated at 150 °C for 72 h in Teflon-lined stainless steel container; cooled to room temp. (10 °C/h), washed (water), dried in air, elem. anal.;
  • 9
  • cobalt(II) sulphate heptahydrate [ No CAS ]
  • [ 1151548-69-4 ]
  • [ 39269-10-8 ]
  • 2Co(2+)*H2O*C12H14O4(2-)*2C19H15N2O4(1-) [ No CAS ]
YieldReaction ConditionsOperation in experiment
30.5% With sodium hydroxide; In water; N,N-dimethyl-formamide; at 140℃; for 72h;Autoclave; A mixture of CoSO4.7H2O (0.20mmol,0.056g), HL (0.10mmol,0.034g), H2adbc (0.15mmol,0.034g) and NaOH(0.30mmol,0.012g), in H2O (14ml) and DMF (2 drops) was sealed in a 25 ml Teflon-lined stainless steel container, which was heated to 140 1C for 72h and then cooled down to room temperature at a rate of 5 C h. Purple crystals of 2 were collected and washed with distilled water and dried in air to give the product: 30.5%yield(based onHL).Anal.Calc.forC50H44Co2N4O13 (%): C,58.48;H,4.29;N, 5.46.FoundC,58.47;H,4.31;N,5.45.IR(KBrpellet,cm1): 34293056,1710,1619,1581,1467,1373,1166,1062,788,and719.
  • 10
  • [ CAS Unavailable ]
  • [ 1151548-69-4 ]
  • [ 100-21-0 ]
  • [ CAS Unavailable ]
YieldReaction ConditionsOperation in experiment
31.6% With sodium hydroxide In water; N,N-dimethyl-formamide at 160℃; for 72h; Autoclave; 2.4. Synthesisof[Co2L2(tpa)]n (3) A mixture of CoSO4 7H2O (0.20mmol,0.056g),HL(0.10mmol,0.034g),H2tpa (0.20mmol,0.033g)and NaOH (0.50mmol,0.02g)in H2O (14ml) and DMF(2drops)was sealed in a 25ml Teflon-lined stainless steelcontainer,which was heated to160 1C for 72h and then cooled down to room temperature at a rate of 5C h. Purple crystals of 3 were collected and washed with distilled water and dried in air to give the product :31.6% yield (based on HL ).Anal.Calc. for C23H17CoN2O6 (%): C,57.98;H,3.57;N,5.88.Found C,57.99;H,3.58;N,5.86. IR (KBr pellet ,cm1): 3433,2989,1618,1595,1556,1466,1371,1167,1090,1061,900,808,786,and713.
  • 11
  • cobalt(II) sulphate heptahydrate [ No CAS ]
  • [ 4282-31-9 ]
  • [ 1151548-69-4 ]
  • 2Co(2+)*2C19H15N2O4(1-)*C6H2O4S(2-) [ No CAS ]
YieldReaction ConditionsOperation in experiment
29.8% With sodium hydroxide; In water; N,N-dimethyl-formamide; at 160℃; for 72h;Autoclave; A mixtureof CoSO4 7H2O (0.20mmol,0.056g),HL(0.10mmol,0.034g), H2tdc (0.20mmol,0.021g) and NaOH (0.50mmol,0.02g) in H2O (14ml) and DMF ( 2 drops )was sealed in a 25ml Teflon-lined stainlesssteel container,which was heated to 160 1C for 72h and then cooled down to room temperature at a rate of 5 C h. Purple crystals of 4 were collected and washed with distilled water and dried in air to give the product: 29.8% yield (based on HL). Anal.Calc.for C44H32Co2N4O12S (%):C,55.11;H,3.34;N,5.85. Found C,55.12;H,3.36;N,5.81.IR (KBr pellet,cm1): 3432,2976,1630,1595,1556,1466,1371,1167,1090,1061,900,808,786,and719.
  • 12
  • [ CAS Unavailable ]
  • [ 1151548-69-4 ]
  • [ 20084-29-1 ]
  • [ CAS Unavailable ]
YieldReaction ConditionsOperation in experiment
29.4% With sodium hydroxide In water; N,N-dimethyl-formamide at 160℃; for 72h; Autoclave; Synthesis of [Co2L2(bdtc)(H2O)]n (5) A mixture of CoCl2.6H2O (0.20 mmol, 0.048g), HL (0.10mmol, 0.034 g), H2bdtc (0.10mmol,0.026g) and NaOH (0.30mmol, 0.012 g) in H2O (14ml) and DMF (2 drops) was sealed in a 25 ml Teflon-lined stainless steel container,which was heated to 160 C for 72h and then cooled down to room temperature at a rate of 5C h. Purple crystals of 5 were collected and washed with distilled water and dried in air to give the product : 29.4%yield (based on HL). Anal.Calc.for C48H40Co2N4O13S2 (%): C,54.24;H,3.77;N,5.27.FoundC,54.23;H,3.78;N,5.30.IR (KBr pellet,cm1):3431,3039,2098,1610,1593,1550,1475,1410,1373,1160,1067,1061,897,783,and511.
  • 13
  • [ CAS Unavailable ]
  • [ 1151548-69-4 ]
  • [ CAS Unavailable ]
YieldReaction ConditionsOperation in experiment
40.6% With sodium hydroxide In water; N,N-dimethyl-formamide at 160℃; for 72h; Autoclave; 2.2. Synthesisof[CoL2(H2O)2]n 2nH2O (1) mixture of CoCl2 6H2O (0.20mmol,0.048g),HL(0.10mmol,0.034 g) and NaOH(0.10mmol,0.004g) in H2O (14ml) and DMF(2 drops) was sealed in a 25ml Teflon-lined stainless steel container,which was heated at 160 1C for 72 h and then cooled down to room temperature at a rate of 5 1C h. Purple crystals of 1 were collected and washed with distilled water and dried in air to give the product; 40.6% yield (basedonHL) .Anal.Calc.forC38H38CoN4O12 (%): C,56.93;H,4.74;N,6.99.FoundC,56.91;H,4.73;N,6.70.IR(KBrpellet,cm1): 3431,2996,1627,1586,1458,1369,1243,1165,1106,1068,897,785,and 720.
  • 14
  • zinc(II) nitrate hexahydrate [ No CAS ]
  • [ 1151548-69-4 ]
  • [ 23351-91-9 ]
  • [ 7732-18-5 ]
  • [ 68-12-2 ]
  • [Zn2(5-bromoisophthalate)(3,5-bis(pyridin-4-yl-methoxy)benzoate)2(H2O)2]n*nDMF [ No CAS ]
YieldReaction ConditionsOperation in experiment
40% at 120℃; for 72h;High pressure; A mixture of Zn(NO3)2·6H2O (29.7mg, 0.1mmol), 5-Br-H2ip (12.1mg, 0.05mmol), Hbpmba (16.8mg, 0.05mmol), DMF (3mL) and H2O (6mL) was sealed in a 15mL Teflon-lined reactor and heated at 120C for 72h. Upon cooling to room temperature at a rate of 10Ch-1, colorless crystals were obtained in 40% yield based on 5-Br-H2ip. Anal. calcd for C49H44BrN5O15Zn2: C, 51.02; H, 3.84; N, 6.07. Found: C, 51.00; H, 3.92; N, 6.27%. IR (KBr, cm-1): 3439(w), 3062(w,nu FontWeight="Bold" FontSize="10" -H), 2931(w), 2840(w), 2783(w), 1680(s,nuC=O), 1612(s), 1552(s,nuas,OCO), 1439(m), 1377(s,nus,OCO), 1218(m), 1073(m), 812(m), 776(m, gamma FontWeight="Bold" FontSize="10" -H), 726(s, gamma FontWeight="Bold" FontSize="10" -H), 629(m).
  • 15
  • zinc(II) nitrate hexahydrate [ No CAS ]
  • [ 1151548-69-4 ]
  • [ 23351-91-9 ]
  • [ 7732-18-5 ]
  • [Zn2(5-bromoisophthalate)(3,5-bis(pyridin-4-yl-methoxy)benzoate)2]n*2nH2O [ No CAS ]
YieldReaction ConditionsOperation in experiment
37% In N,N-dimethyl-formamide; at 85℃; for 72h;High pressure; A mixture of Zn(NO3)2·6H2O (29.7mg, 0.1mmol), 5-Br-H2ip (12.1mg, 0.05mmol), Hbpmba (16.8mg, 0.05mmol), DMF (3mL) and H2O (6mL) was sealed in a 15mL Teflon-lined reactor and heated at 120C for 72h. Upon cooling to room temperature at a rate of 10Ch-1, colorless crystals were obtained in 40% yield based on 5-Br-H2ip. Anal. calcd for C49H44BrN5O15Zn2: C, 51.02; H, 3.84; N, 6.07. Found: C, 51.00; H, 3.92; N, 6.27%. IR (KBr, cm-1): 3439(w), 3062(w,nu FontWeight="Bold" FontSize="10" -H), 2931(w), 2840(w), 2783(w), 1680(s,nuC=O), 1612(s), 1552(s,nuas,OCO), 1439(m), 1377(s,nus,OCO), 1218(m), 1073(m), 812(m), 776(m, gamma FontWeight="Bold" FontSize="10" -H), 726(s, gamma FontWeight="Bold" FontSize="10" -H), 629(m).
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