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Chemical Structure| 1151548-69-4 Chemical Structure| 1151548-69-4

Structure of 1151548-69-4

Chemical Structure| 1151548-69-4

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Product Details of [ 1151548-69-4 ]

CAS No. :1151548-69-4
Formula : C19H16N2O4
M.W : 336.34
SMILES Code : O=C(O)C1=CC(OCC2=CC=NC=C2)=CC(OCC3=CC=NC=C3)=C1

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Application In Synthesis of [ 1151548-69-4 ]

* All experimental methods are cited from the reference, please refer to the original source for details. We do not guarantee the accuracy of the content in the reference.

  • Downstream synthetic route of [ 1151548-69-4 ]

[ 1151548-69-4 ] Synthesis Path-Downstream   1~2

  • 1
  • zinc(II) nitrate hexahydrate [ No CAS ]
  • [ 1151548-69-4 ]
  • [ 23351-91-9 ]
  • [ 7732-18-5 ]
  • [ 68-12-2 ]
  • [Zn2(5-bromoisophthalate)(3,5-bis(pyridin-4-yl-methoxy)benzoate)2(H2O)2]n*nDMF [ No CAS ]
YieldReaction ConditionsOperation in experiment
40% at 120℃; for 72h;High pressure; A mixture of Zn(NO3)2·6H2O (29.7mg, 0.1mmol), 5-Br-H2ip (12.1mg, 0.05mmol), Hbpmba (16.8mg, 0.05mmol), DMF (3mL) and H2O (6mL) was sealed in a 15mL Teflon-lined reactor and heated at 120C for 72h. Upon cooling to room temperature at a rate of 10Ch-1, colorless crystals were obtained in 40% yield based on 5-Br-H2ip. Anal. calcd for C49H44BrN5O15Zn2: C, 51.02; H, 3.84; N, 6.07. Found: C, 51.00; H, 3.92; N, 6.27%. IR (KBr, cm-1): 3439(w), 3062(w,nu FontWeight="Bold" FontSize="10" -H), 2931(w), 2840(w), 2783(w), 1680(s,nuC=O), 1612(s), 1552(s,nuas,OCO), 1439(m), 1377(s,nus,OCO), 1218(m), 1073(m), 812(m), 776(m, gamma FontWeight="Bold" FontSize="10" -H), 726(s, gamma FontWeight="Bold" FontSize="10" -H), 629(m).
  • 2
  • zinc(II) nitrate hexahydrate [ No CAS ]
  • [ 1151548-69-4 ]
  • [ 23351-91-9 ]
  • [ 7732-18-5 ]
  • [Zn2(5-bromoisophthalate)(3,5-bis(pyridin-4-yl-methoxy)benzoate)2]n*2nH2O [ No CAS ]
YieldReaction ConditionsOperation in experiment
37% In N,N-dimethyl-formamide; at 85℃; for 72h;High pressure; A mixture of Zn(NO3)2·6H2O (29.7mg, 0.1mmol), 5-Br-H2ip (12.1mg, 0.05mmol), Hbpmba (16.8mg, 0.05mmol), DMF (3mL) and H2O (6mL) was sealed in a 15mL Teflon-lined reactor and heated at 120C for 72h. Upon cooling to room temperature at a rate of 10Ch-1, colorless crystals were obtained in 40% yield based on 5-Br-H2ip. Anal. calcd for C49H44BrN5O15Zn2: C, 51.02; H, 3.84; N, 6.07. Found: C, 51.00; H, 3.92; N, 6.27%. IR (KBr, cm-1): 3439(w), 3062(w,nu FontWeight="Bold" FontSize="10" -H), 2931(w), 2840(w), 2783(w), 1680(s,nuC=O), 1612(s), 1552(s,nuas,OCO), 1439(m), 1377(s,nus,OCO), 1218(m), 1073(m), 812(m), 776(m, gamma FontWeight="Bold" FontSize="10" -H), 726(s, gamma FontWeight="Bold" FontSize="10" -H), 629(m).
 

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