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Type | HazMat fee for 500 gram (Estimated) |
Excepted Quantity | USD 0.00 |
Limited Quantity | USD 15-60 |
Inaccessible (Haz class 6.1), Domestic | USD 80+ |
Inaccessible (Haz class 6.1), International | USD 150+ |
Accessible (Haz class 3, 4, 5 or 8), Domestic | USD 100+ |
Accessible (Haz class 3, 4, 5 or 8), International | USD 200+ |
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CAS No. : | 116-26-7 | MDL No. : | MFCD00209531 |
Formula : | C10H14O | Boiling Point : | - |
Linear Structure Formula : | - | InChI Key : | SGAWOGXMMPSZPB-UHFFFAOYSA-N |
M.W : | 150.22 | Pubchem ID : | 61041 |
Synonyms : |
|
Chemical Name : | 2,6,6-Trimethylcyclohexa-1,3-dienecarbaldehyde |
Signal Word: | Danger | Class: | 3 |
Precautionary Statements: | P261-P305+P351+P338 | UN#: | 1993 |
Hazard Statements: | H225-H315-H319-H335 | Packing Group: | Ⅲ |
GHS Pictogram: |
* All experimental methods are cited from the reference, please refer to the original source for details. We do not guarantee the accuracy of the content in the reference.
Yield | Reaction Conditions | Operation in experiment |
---|---|---|
91% | With lithium aluminium tetrahydride; In diethyl ether; at 0 - 20℃; for 2h; | 1-hydroxymethyl-2,6,6-trimethylcyclohexa-1,3-diene (safranol, 4). To a suspension of 320 mg (8.32 mmol, 2.5 equiv.) of lithium aluminium hydride in dry diethyl ether (30 mL) externally cooled 0C was slowly added a solution of <strong>[116-26-7]safranal</strong> 1 (500 mg, 3.33 mmol) in of diethyl ether (20 mL). After stirring for 1h at 0C and 1h at room temperature, the reaction was quenched carefully with water and filtrated, extracted with diethyl ether (3×20 mL) and dried (MgSO4). After filtration and evaporation, safranol (4) (460 mg, 91%) was obtained as colorless oil that was directly used for further reactions. |
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