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[ CAS No. 1170736-59-0 ] {[proInfo.proName]}

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Chemical Structure| 1170736-59-0
Chemical Structure| 1170736-59-0
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Product Details of [ 1170736-59-0 ]

CAS No. :1170736-59-0 MDL No. :MFCD27952571
Formula : C36H29O4P Boiling Point : -
Linear Structure Formula :- InChI Key :RHMYOMFPZOCLLW-UHFFFAOYSA-N
M.W : 556.59 Pubchem ID :44206861
Synonyms :

Safety of [ 1170736-59-0 ]

Signal Word:Warning Class:N/A
Precautionary Statements:P264-P280-P302+P352-P332+P313-P362+P364 UN#:N/A
Hazard Statements:H315 Packing Group:N/A
GHS Pictogram:

Application In Synthesis of [ 1170736-59-0 ]

* All experimental methods are cited from the reference, please refer to the original source for details. We do not guarantee the accuracy of the content in the reference.

  • Downstream synthetic route of [ 1170736-59-0 ]

[ 1170736-59-0 ] Synthesis Path-Downstream   1~9

  • 1
  • [ CAS Unavailable ]
  • [ 1170736-59-0 ]
YieldReaction ConditionsOperation in experiment
With water at 95℃; for 6h; Inert atmosphere;
  • 2
  • [ 18531-94-7 ]
  • [ 1170736-59-0 ]
YieldReaction ConditionsOperation in experiment
Multi-step reaction with 3 steps 1.1: N,N,N,N,-tetramethylethylenediamine; n-butyllithium / diethyl ether 1.2: 2 h / -78 °C 2.1: tripotassium phosphate tribasic; palladium 10% on activated carbon / lithium hydroxide monohydrate; 1,4-dioxane / 0.5 h / 80 °C / Microwave irradiation 3.1: trichlorophosphate; pyridine / 3 h / 0 - 20 °C / Inert atmosphere 3.2: 1 h / 0 - 20 °C
Multi-step reaction with 5 steps 1.1: sodium hydroxide / 8.5 h / 20 - 100 °C 2.1: N,N,N,N,-tetramethylethylenediamine; n-butyllithium / diethyl ether / 8.5 h / 20 - 100 °C 2.2: 2 h / -78 °C 2.3: 3 h / 5 °C 3.1: tripotassium phosphate tribasic; [1,1'-bis(diphenylphosphino)ferrocene]dichloropalladium(II) / tetrahydrofuran; lithium hydroxide monohydrate / 100 °C / Microwave irradiation 4.1: pyridine hydrochloride / toluene / 100 °C / Microwave irradiation 5.1: trichlorophosphate; pyridine / 3 h / 0 - 20 °C / Inert atmosphere 5.2: 1 h / 0 - 20 °C
  • 3
  • [ 1170736-60-3 ]
  • [ 1170736-59-0 ]
YieldReaction ConditionsOperation in experiment
Multi-step reaction with 2 steps 1.1: pyridine hydrochloride / toluene / 100 °C / Microwave irradiation 2.1: trichlorophosphate; pyridine / 3 h / 0 - 20 °C / Inert atmosphere 2.2: 1 h / 0 - 20 °C
  • 4
  • [ 435327-17-6 ]
  • [ 1170736-59-0 ]
YieldReaction ConditionsOperation in experiment
86% Stage #1: (R)-(+)-3,3'-bis(3,5-dimethylphenyl)-[-1,1'-binaphthalene]-2,2'-diol With pyridine; trichlorophosphate at 0 - 20℃; for 3h; Inert atmosphere; Stage #2: With lithium hydroxide monohydrate at 0 - 20℃; for 1h; Synthesis of 8a-8k General procedure: To a solution of a compound 6a-6k (1 equiv.) in pyridine (8 vol) was added POCl3 (2 equiv.) dropwise under the nitrogen atmosphere at 0 °C. The reaction mixture was warmed up to room temperature and stirred for 3 h (monitored by TLC). Then the mixture was cooled down to ca 5 °C and H2O (10 equiv.) was added to it and stirred at RT for 1 h (TLC). Pyridine was removed under vacuum, and the residue was refluxed in 6N HCl (20 vol.) overnight. The solid was filtered off and washed with water until the last drop showed pH 5-6. The solid was further recrystallized to afford the corresponding pure product.
  • 5
  • [ 287111-93-7 ]
  • [ 1170736-59-0 ]
YieldReaction ConditionsOperation in experiment
Multi-step reaction with 2 steps 1.1: tripotassium phosphate tribasic; palladium 10% on activated carbon / lithium hydroxide monohydrate; 1,4-dioxane / 0.5 h / 80 °C / Microwave irradiation 2.1: trichlorophosphate; pyridine / 3 h / 0 - 20 °C / Inert atmosphere 2.2: 1 h / 0 - 20 °C
  • 6
  • [ 2960-93-2 ]
  • [ 1170736-59-0 ]
YieldReaction ConditionsOperation in experiment
Multi-step reaction with 4 steps 1.1: N,N,N,N,-tetramethylethylenediamine; n-butyllithium / diethyl ether / 8.5 h / 20 - 100 °C 1.2: 2 h / -78 °C 1.3: 3 h / 5 °C 2.1: tripotassium phosphate tribasic; [1,1'-bis(diphenylphosphino)ferrocene]dichloropalladium(II) / tetrahydrofuran; lithium hydroxide monohydrate / 100 °C / Microwave irradiation 3.1: pyridine hydrochloride / toluene / 100 °C / Microwave irradiation 4.1: trichlorophosphate; pyridine / 3 h / 0 - 20 °C / Inert atmosphere 4.2: 1 h / 0 - 20 °C
  • 7
  • [ 215433-49-1 ]
  • [ 1170736-59-0 ]
YieldReaction ConditionsOperation in experiment
Multi-step reaction with 3 steps 1.1: tripotassium phosphate tribasic; [1,1'-bis(diphenylphosphino)ferrocene]dichloropalladium(II) / tetrahydrofuran; lithium hydroxide monohydrate / 100 °C / Microwave irradiation 2.1: pyridine hydrochloride / toluene / 100 °C / Microwave irradiation 3.1: trichlorophosphate; pyridine / 3 h / 0 - 20 °C / Inert atmosphere 3.2: 1 h / 0 - 20 °C
  • 8
  • [ 861909-33-3 ]
  • [ 172975-69-8 ]
  • [ 1170736-59-0 ]
YieldReaction ConditionsOperation in experiment
88 % With potassium dihydrogenphosphate; 4,7-dimethoxy-1,10-phenanthroline; (TMEDA)Ni(o-tolyl)Cl; potassium <i>tert</i>-butylate In butan-1-ol at 60℃; Inert atmosphere; 3.3 In a 5L multi-mouth bottle, weigh 50g of brominated binaphthol phosphate, 32.3g of 3,5-dimethylphenylboronic acid, 42g of potassium phosphate, 17.6g of potassium tert-butoxide, and 2.6g of 4 , 7-diphenyl-1,10-phenanthroline and 1.18g of (TMEDA)Ni(o-tolyl)Cl were added to the bottle, pumped argon three times, and then added 2L of sec-butyl alcohol.After reacting at 60°C for 16 hours, it was cooled to room temperature, diluted with 500 mL of dichloromethane, passed through diatomaceous earth, and the filtrate was spin-dried.After separation and purification by neutral alumina, 48 g of white solid was obtained, namely the chiral phosphoric acid compound of this example, with a yield of 88%.The NMR characterization of the chiral phosphoric acid compound in this example is as follows
  • 9
  • [ 39648-67-4 ]
  • [ 1170736-59-0 ]
YieldReaction ConditionsOperation in experiment
Multi-step reaction with 2 steps 1.1: sec.-butyllithium / tetrahydrofuran; hexane / 2 h / -78 °C / Inert atmosphere 1.2: Ca. 150 min / 20 °C / Inert atmosphere 2.1: potassium <i>tert</i>-butylate; potassium dihydrogenphosphate; 4,7-dimethoxy-1,10-phenanthroline; (TMEDA)Ni(o-tolyl)Cl / butan-1-ol / 16 h / 60 °C / Inert atmosphere
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