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Chemical Structure| 1182844-62-7 Chemical Structure| 1182844-62-7

Structure of 1182844-62-7

Chemical Structure| 1182844-62-7

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Product Details of [ 1182844-62-7 ]

CAS No. :1182844-62-7
Formula : C11H5BrN2O
M.W : 261.07
SMILES Code : O=C1C2=CC(Br)=CN=C2C3=NC=CC=C31
MDL No. :MFCD31729260

Safety of [ 1182844-62-7 ]

GHS Pictogram:
Signal Word:Warning
Hazard Statements:H315-H319-H335
Precautionary Statements:P261-P264-P271-P280-P302+P352-P304+P340-P305+P351+P338-P312-P362-P403+P233-P501

Application In Synthesis of [ 1182844-62-7 ]

* All experimental methods are cited from the reference, please refer to the original source for details. We do not guarantee the accuracy of the content in the reference.

  • Downstream synthetic route of [ 1182844-62-7 ]

[ 1182844-62-7 ] Synthesis Path-Downstream   1~1

  • 1
  • [ 66127-01-3 ]
  • [ 1182844-62-7 ]
YieldReaction ConditionsOperation in experiment
50% Add 0.1mol of <strong>[66127-01-3]<strong>[66127-01-3]3-bromo-1,10-phenanthrolin</strong>e</strong> and 0.35mol of KOH to 1.3L of water. the temperature was raised to reflux with stirring. After about 1 h, a hot solution of 0.3 mol of KMNO4 in water (1L) was added dropwise. the mixture was refluxed for an additional 2 h, then filter while hot. The filtrate was cooled and extracted three times with chloroform. after drying over anhydrous sodium sulfate and filtering, the filtrate was spin-dried under reduced pressure. Intermediate 1-2-28-2 was obtained by column chromatography (yield 50%).
 

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