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[ CAS No. 1206-85-5 ] {[proInfo.proName]}

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Cat. No.: {[proInfo.prAm]}
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Chemical Structure| 1206-85-5
Chemical Structure| 1206-85-5
Structure of 1206-85-5 * Storage: {[proInfo.prStorage]}
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Product Details of [ 1206-85-5 ]

CAS No. :1206-85-5 MDL No. :N/A
Formula : C12H9N3 Boiling Point : -
Linear Structure Formula :- InChI Key :WURVTDKUHZJPJX-UHFFFAOYSA-N
M.W : 195.22 Pubchem ID :121055
Synonyms :

Safety of [ 1206-85-5 ]

Signal Word:Danger Class:6.1
Precautionary Statements:P501-P261-P270-P271-P264-P280-P337+P313-P305+P351+P338-P361+P364-P332+P313-P301+P310+P330-P302+P352+P312-P304+P340+P311-P403+P233-P405 UN#:3439
Hazard Statements:H301+H311+H331-H315-H319 Packing Group:
GHS Pictogram:

Application In Synthesis of [ 1206-85-5 ]

* All experimental methods are cited from the reference, please refer to the original source for details. We do not guarantee the accuracy of the content in the reference.

  • Downstream synthetic route of [ 1206-85-5 ]

[ 1206-85-5 ] Synthesis Path-Downstream   1~23

  • 1
  • [ 608-72-0 ]
  • [ 544-92-3 ]
  • [ 1206-85-5 ]
  • 4
  • [ 608-72-0 ]
  • compound from pyridine and CuCN [ No CAS ]
  • [ 1206-85-5 ]
  • 5
  • dinitrile of/the/ eso-amino-mesitylen-eso-dicarboxylic acid [ No CAS ]
  • [ 1206-85-5 ]
  • 6
  • [ 5211-86-9 ]
  • [ 1206-85-5 ]
  • 1,3,5-tricyano-2,4,6-tris(2-piperidin-1-ylvinyl)benzene [ No CAS ]
  • 7
  • [ 10338-57-5 ]
  • [ 1206-85-5 ]
  • 1,3,5-tricyano-2,4,6-tris(p-piperidinylstyryl)benzene [ No CAS ]
  • 8
  • [ 4432-76-2 ]
  • [ 1206-85-5 ]
  • 2,4,6-Tris-((E)-2-diethylamino-vinyl)-benzene-1,3,5-tricarbonitrile [ No CAS ]
  • 9
  • [ 1206-85-5 ]
  • [ 119198-88-8 ]
  • 10
  • [ 1206-85-5 ]
  • 3,5-diformyl-2,4,6-trimethyl-benzonitrile [ No CAS ]
  • 3,5-dicyano-2,4,6-trimethylbenzaldehyde [ No CAS ]
  • 12
  • [ 1206-85-5 ]
  • [ 123-11-5 ]
  • 1,3,5-tricyano-2,4,6-tris(p-methoxystyryl)benzene [ No CAS ]
  • 13
  • [ 1206-85-5 ]
  • [ 4637-24-5 ]
  • 1,3,5-tricyano-2,4,6-tris(2-dimethylaminovinyl)benzene [ No CAS ]
  • 14
  • [ 1206-85-5 ]
  • [ 120-21-8 ]
  • 1,3,5-tricyano-2,4,6-tris(p-diethylaminostyryl)benzene [ No CAS ]
  • 15
  • [ 1206-85-5 ]
  • 7-hydroxy-3,5-dimethyl-bicyclo[4.2.0]octa-1(6),2,4-triene-2,4-dicarbaldehyde [ No CAS ]
  • 16
  • [ 1206-85-5 ]
  • 4-formyl-7-hydroxy-3,5-dimethyl-bicyclo[4.2.0]octa-1(6),2,4-triene-2-carbonitrile [ No CAS ]
  • 17
  • [ 1206-85-5 ]
  • 5-formyl-8-hydroxy-2,4-dimethyl-bicyclo[4.2.0]octa-1(6),2,4-triene-3-carbonitrile [ No CAS ]
  • 18
  • [ 1206-85-5 ]
  • 7-hydroxy-3,5-dimethyl-bicyclo[4.2.0]octa-1(6),2,4-triene-2,4-dicarbonitrile [ No CAS ]
  • 19
  • [ 608-72-0 ]
  • [ 1206-85-5 ]
YieldReaction ConditionsOperation in experiment
6g (40.59%) With pyridine;CuCN; 2) Synthesis of 2,4,6-tricyano-1,3,5-trimethylbenzene (TCM) CuCN (220g, 243 mmol) and pyridine (146.7g, 1.85 mol) were added to a high pressure reaction vessel, and well mixed, and then <strong>[608-72-0]2,4,6-tribromo-1,3,5-trimethylbenzene</strong>(25g, 75.8mmol) was added thereto. The reaction mixture was reacted at 205 0 for 2 hours. Cu therein was excluded with excessive methylene diamine, and then filtered by MC. Water in the reaction mixture was eliminated over MgSO4, and then solvent therein was evaporated in vacuum. The residue was absorbed to silica gel column and separated with a tube chromatography (Hx: MC = 3:1) to obtain white solid [yield: 6g (40.59%)].
  • 20
  • [ 608-72-0 ]
  • copper(l) cyanide [ No CAS ]
  • [ 1206-85-5 ]
YieldReaction ConditionsOperation in experiment
46% In N,N-dimethyl-formamide; at 150 - 160℃; for 8h;Reflux; To a solution of CuCN (5.0 g, 56.0 mmol) in 40.0 mL of DMF was added 2,4,6-dibromomesitylene (4.0 g, 30.0 mmol) and the resultant mixture was heated at reflux (150-160 C) for 8 h. Subsequently, the reaction mixture was cooled to room temperature and a solution of FeCl3 (24.0 g in 32.0 mL of 2.4 N HCl) was added. The mixture was heated at 78-80 C for 20 min and then cooled. The organic matter was extracted with chloroform, washed with water, dried over anhydrous Na2SO4 and the solvent removed in vacuo. The residue was subjected to column chromatography (10% ethyl acetate/hexane) to obtain 1.0 g (46%) of 2,4,6-Tricyanomesitylene as colourless crystalline material, mp 178-179 C (lit 180 C), 1H NMR (CDCl3, 400 MHz) 2.82 (s, 9H) ppm; 13C NMR (CDCl3, 100 MHz) delta 150.0, 114.4, 114.3, 20.8 ppm.
  • 21
  • [ 1206-85-5 ]
  • [ 1422036-95-0 ]
YieldReaction ConditionsOperation in experiment
45% With aluminum oxide; copper(II) bis(trifluoromethanesulfonate); In N,N-dimethyl acetamide; at 100℃; for 6.0h;Sealed tube; Inert atmosphere; In a sealed tube 2.0 g of basic Al2O3-Cu(OTf)2 catalyst was added to a solution of tricyanomesitylene (100 mg,0.51 mmol) in a 7.0 mL of dimethyl acetamide (DMA) under inert atmosphere and the resultant mixture was heated at 100 C) for 6 h. The reaction mixture was cooled to room temp and filtered. The solvent (filtrate) was evaporated under reduced pressure. The residue was subjected to column chromatography (30% ethyl acetate in hexane) to obtain 22 mg (yield 45% at 49% conversion) IQ as yellowish-brown amorphous powder; mp > 300 C; 1H NMR (CDCl3, 400 MHz) δ 7.24 (s, 1H, aromatic), 5.71 (s, 2H, amine), 3.26 (s, 3H, p-methyl of aryl group), 2.91 (s, 3H, 6-methyl of isoquinoline), 2.81 (s, 3H, 8- methyl of isoquinoline), 2.36 (s, 6H, o-methyl of aryl group) ppm; 13C NMR (CDCl3, 100 MHz) δ 157.8, 154.3, 147.8, 146.8, 146.0, 144.6, 141.0, 139.1, 115.9, 115.8 (×2), 115.1, 115.0, 114.1, 113.6 (×2), 109.9 (×2), 109.3, 23.1, 21.0, 20.3, 19.8 (×2) ppm; IR (KBr) ν 3404, 3294, 3142, 2932, 2225, 1593, 1474 cm-1; ESI-MS m/z calculated for (C24H18N6 + H+): 391.1671, found 390.8277; Anal. Calcd. for C24H18N6: C, 73.83; H, 4.65; N, 21.52. Found C, 73.66; H, 4.68; N, 21.46.
  • 22
  • [ 108-67-8 ]
  • [ 1206-85-5 ]
  • 23
  • [ 1206-85-5 ]
  • [ 780722-26-1 ]
  • 1,3,5-tris(2,4-diamino-1,3,5-triazin-6-yl)-2,4,6-trimethylbenzene [ No CAS ]
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