[ CAS No. 12079-65-1 ] {[proInfo.proName]}

Name: 12079-65-1|Cyclopentadienylmanganese(I) tricarbonyl|98%
Brand: Ambeed
SKU: A329851
Rating: 95 (40 reviews)

,{[proInfo.pro_purity]}

Cat. No.: {[proInfo.prAm]}

HazMat Fee +

There will be a HazMat fee per item when shipping a dangerous goods. The HazMat fee will be charged to your UPS/DHL/FedEx collect account or added to the invoice unless the package is shipped via Ground service. Ship by air in Excepted Quantity (each bottle), which is up to 1g/1mL for class 6.1 packing group I or II, and up to 25g/25ml for all other HazMat items.

Type	HazMat fee for 500 gram (Estimated)
Excepted Quantity	USD 0.00
Limited Quantity	USD 15-60
Inaccessible (Haz class 6.1), Domestic	USD 80+
Inaccessible (Haz class 6.1), International	USD 150+
Accessible (Haz class 3, 4, 5 or 8), Domestic	USD 100+
Accessible (Haz class 3, 4, 5 or 8), International	USD 200+

2D 3D

Structure of 12079-65-1 * Storage: {[proInfo.prStorage]}

Cart0 Add to My Favorites Add to My Favorites Bulk Inquiry Inquiry Add To Cart

Search after Editing

* Storage: {[proInfo.prStorage]}

For Research Only 110K+ Compounds Competitive Price 1-2 Day Shipping

Quality Control of [ 12079-65-1 ]

COA NMR CNMR HPLC LC-MS

Related Doc. of [ 12079-65-1 ]

SDS Specification

Alternatived Products of [ 12079-65-1 ]

Product Details of [ 12079-65-1 ]

CAS No. :	12079-65-1	MDL No. :	MFCD00001440
Formula :	C₈H₅MnO₃	Boiling Point :	-
Linear Structure Formula :	-	InChI Key :	-
M.W :	204.06	Pubchem ID :	-
Synonyms :

Safety of [ 12079-65-1 ]

Signal Word:	Danger	Class:	6.1
Precautionary Statements:	P264-P270-P301+P310+P330-P405-P501	UN#:	2811
Hazard Statements:	H300	Packing Group:	Ⅱ
GHS Pictogram:

Application In Synthesis of [ 12079-65-1 ]

* All experimental methods are cited from the reference, please refer to the original source for details. We do not guarantee the accuracy of the content in the reference.

Downstream synthetic route of [ 12079-65-1 ]

[ 12079-65-1 ] Synthesis Path-Downstream 1~88

1
[ 12079-65-1 ]
[ 74-85-1 ]
[ 12108-31-5 ]

Reference： [1]Journal of the American Chemical Society,1997,vol. 119,p. 10170 - 10177

2
[ 931-87-3 ]
[ 12079-65-1 ]
dicarbonyl(η(5)-cyclopentadienyl)manganese(η(2)-cis-cyclooctene) [ No CAS ]

Reference： [1]Journal of Organometallic Chemistry,1985,vol. 295,p. 63 - 72
[2]Journal of the American Chemical Society,1990,vol. 112,p. 1267 - 1268
[3]Inorganic Chemistry,2010,vol. 49,p. 7597 - 7604

3
[ 12079-65-1 ]
(η5-cyclopentadienyl)(triphenylphosphine)dicarbonylmanganese [ No CAS ]

Reference： [1]Journal of the Chemical Society, Dalton Transactions,
Journal of the Chemical Society, Dalton Transactions: Inorganic Chemistry (1972-1999),1977,p. 931 - 937
[2]Journal of the American Chemical Society,1990,vol. 112,p. 1267 - 1268
[3]Journal of the Chemical Society, Faraday Transactions 1: Physical Chemistry in Condensed Phases,1989,vol. 85,p. 3913 - 3926
[4]Organometallics,1983,vol. 2,p. 267 - 275
[5]Organometallics,1987,vol. 6,p. 2600 - 2605
[6]Organometallics,1987,vol. 6,p. 2600 - 2605

4
[ 12079-65-1 ]
C₅H₅Mn(CO)2CH₃C(O)CH₃ [ No CAS ]

Reference： [1]Journal of the American Chemical Society,1990,vol. 112,p. 1267 - 1268
[2]Journal of Organometallic Chemistry,1984,vol. 269,p. 155 - 170

5
[ 12079-65-1 ]
dicarbonyl(η(5)-cyclopentadienyl)manganese(THF) [ No CAS ]

Reference： [1]Chemische Berichte,1980,vol. 113,p. 2868 - 2875
[2]Journal of the American Chemical Society,1990,vol. 112,p. 1267 - 1268
[3]Journal of Organometallic Chemistry,1990,vol. 389,p. 103 - 128
[4]Bulletin of the Academy of Sciences of the USSR Division of Chemical Science,1986,vol. 35,p. 171 - 174
Bull. Acad. Sci. USSR, Div. Chem. Sci. (Engl. Transl.),1986,vol. 35,p. 188 - 191
[5]Journal of Organometallic Chemistry,1985,vol. 296,p. 377 - 382
[6]Journal of Organometallic Chemistry,1981,vol. 217,p. 61 - 78
[7]Journal of the American Chemical Society,1992,vol. 114,p. 6937 - 6938
[8]Journal of Organometallic Chemistry,1993,vol. 450,p. 151 - 155
[9]Chemische Berichte,1980,vol. 113,p. 2648 - 2654
[10]Journal of the Chemical Society. Chemical communications,1981,p. 311 - 313
[11]Bulletin of the Academy of Sciences of the USSR Division of Chemical Science,1988,vol. 37,p. 353 - 356
Bull. Acad. Sci. USSR, Div. Chem. Sci. (Engl. Transl.),1988,vol. 37,p. 434 - 437
[12]New Journal of Chemistry,1989,vol. 13,p. 399 - 402
[13]Journal of Organometallic Chemistry,1986,vol. 312,p. C53 - C56
[14]Journal of Organometallic Chemistry,1984,vol. 260,p. 281 - 292

6
[ 12079-65-1 ]
CpMn(CO)2-ClCH₂Cl [ No CAS ]

Reference： [1]Journal of the American Chemical Society,1992,vol. 114,p. 6937 - 6938

7
[ 12079-65-1 ]
C₅H₅Mn(CO)2(ClC₄H₉) [ No CAS ]

Reference： [1]Journal of the American Chemical Society,1992,vol. 114,p. 6937 - 6938

8
[ 12079-65-1 ]
C₅H₅Mn(CO)2(BrC₄H₉) [ No CAS ]

Reference： [1]Journal of the American Chemical Society,1992,vol. 114,p. 6937 - 6938

9
[ 12079-65-1 ]
[ 603-35-0 ]
(η5-cyclopentadienyl)(triphenylphosphine)dicarbonylmanganese [ No CAS ]

Yield	Reaction Conditions	Operation in experiment
61%	In tetrahydrofuran; for 23h;Irradiation; Inert atmosphere;	General procedure: A solution of [(C5H5)Mn(CO)3] (I) and a slight molar excessof the phosphane in tetrahydrofuran (THF, 120 ml) was irradiatedfor 7 h under argon. The colours of the solutionschanged from yellow to red with concomitant gas evolution.After further stirring for 16 h, the solvent was evacuated andthe residue dissolved in diethyl ether (Et2O) and filteredthrough a plug of silica gel. The solvent was evaporated againand the residue dissolved in the minimum amount of petroleumether. This solution was placed on top of a silica gelchromatography column (alumina in the case of 3a) and theproducts were eluted with a petroleum ether/Et2O (9:1 v/v)mixture. Evaporation of the eluate yielded the products asyellow powders. Recrystallization from petroleum ether (with some added Et2O) by slow evaporation in a refrigerator at5 C yielded crystals of all three compounds.

Reference： [1]Acta Crystallographica Section C: Structural Chemistry,2021,vol. 77,p. 633 - 640
[2]Chemistry - A European Journal,2014,vol. 20,p. 2175 - 2178
[3]Russian Chemical Bulletin,1999,vol. 48,p. 984 - 987
[4]Russian Chemical Bulletin,1999,vol. 48,p. 984 - 987
[5]Organometallics,1997,vol. 16,p. 120 - 123

10
[ 12079-65-1 ]
[ 1333-74-0 ]
(η5-C5H5)Mn(CO)2(η2-H2) [ No CAS ]

Reference： [1]Journal of the American Chemical Society,1997,vol. 119,p. 10170 - 10177
[2]Organometallics,2009,vol. 28,p. 3113 - 3122
[3]Organometallics,2009,vol. 28,p. 3113 - 3122
[4]Organometallics,2009,vol. 28,p. 3113 - 3122
[5]Chemical Communications,2014,vol. 50,p. 5874 - 5877

11
[ 10170-69-1 ]
[ 1755-01-7 ]
[ 12079-65-1 ]

Yield	Reaction Conditions	Operation in experiment
74%	In decalin; at 200℃; for 9h;Reflux; Inert atmosphere;	Under purified argon Mn2(CO)10 (980 mg, 2.51 mmol), dicyclopentadiene C10H12 (2.0 mL, 1960 mg, 14.9 mmol), and decaline (6 mL) were heated to reflux (oil bath temperature of ca. 200 C). A gas evolution started, which ceased after 6 h. After 9 h of heating, the reaction mixture was cooled to room temperature, filtered, and cooled to -20 C. Ayellow solid deposited, which was separated, washed with cold hexane, and dried in vacuo (yield: 600 mg, 59%). Cooling of the mother liquor to -78 C yielded an additional precipitate (yield: 350 mg, 34%). The crude product (950 mg, 93%) was sublimated in vacuo, which resulted in yellow crystals. Yield: 735 mg, 3.60 mmol, 72%. 1H NMR (CDCl3): δ = 4.76 (s,[40] Δν1/2 = 2Hz, 1JHC = 179 Hz) ppm. 13C NMR (CDCl3): δ = 224.8 (br., Δν1/2 = 50 Hz, CO), 82.7 (s, Δν1/2 = 5Hz, Cp) ppm. 55Mn NMR (CDCl3): δ = -2160 (br., Δν1/2 = 8.5 kHz) ppm. UV/Vis (hexane): λ (ε) = 216 (15000), 332 (1000) nm (Lmol-1cm-1).

Reference： [1]European Journal of Inorganic Chemistry,2012,p. 6018 - 6026
[2]Journal of the Chemical Society, Dalton Transactions,1981,p. 51 - 55

12
tetramethylphosponium-{dicarbonyl(η5-cyclopentadienyl)-{η1-2-(trimethylphosphoranylidene)acetyl}manganate(1-)} [ No CAS ]
[ 12079-65-1 ]

Reference： [1]Chemische Berichte,1983,vol. 116,p. 690 - 709

13
[ 12079-65-1 ]
[ 73183-34-3 ]
[ 737776-94-2 ]

Reference： [1]Chemical Communications,2004,p. 1508 - 1509

14
[ 109-99-9 ]
[ 12079-65-1 ]
dicarbonyl(η(5)-cyclopentadienyl)manganese(THF) [ No CAS ]

Yield	Reaction Conditions	Operation in experiment
	for 0.25h;UV-irradiation;	5.0mg <strong>[12079-65-1]CpMn(CO)3</strong> (0.024mmol) was dissolved in 2mL thf before it was subjected to 15min of UV laser photolysis (Brilliant B, 355nm, 20mJ/pulse, 10Hz) in an evacuated glass apparatus (25cm3 volume). The resultant CpMn(CO)2(thf) solution was then evacuated and frozen before 0.024mmol ligand L was added. The mixture was evacuated and left to mix at room temperature in the dark for 15min to afford orange CpMn(CO)2L. The CpMn(CO)2L solution was then studied using IR spectroscopy and ESI-MS spectrometry without further purification.
	at 20℃; for 1h;Inert atmosphere; Schlenk technique; Irradiation;	All complexes were synthesised according to a similar methodologyas reported by Lugan [4]. <strong>[12079-65-1]CpMn(CO)3</strong> (0.612 g, 3.0 mmol)was dissolved in 40ml of dry THF and irradiated for 60 min at roomtemperature. Imidazol-2-ylidene L1 (0.714 g, 3.0 mmol) was addedto the reaction mixture via cannula and the reaction allowed to stirfor 90 min. The reaction colour turned to deep brown and themixture was subsequently filtered through a small aluminium oxidecolumn. The solvent was evaporated, the product redissolvedand purified with column chromatography with hexane:ethereluent to recover 1 as an orange oil. Yield (0.267 g (31%) %).
	In neat (no solvent); at -40℃; for 1h;Inert atmosphere; UV-irradiation;	A yellow solution of <strong>[12079-65-1](η5-C5H5)Mn(CO)3</strong> (0.157 g, 0.770 mmol) in THF(30 mL) was UV-irradiated at -40 for 1 h.

	for 1h;UV-irradiation; Inert atmosphere; Schlenk technique; Glovebox;	A solution of [<strong>[12079-65-1]CpMn(CO)3</strong>] (56 mg, 0.27 mmol) is dissolved in 50 mL thf and irradiatedwith UV light for 1 h using a low-pressure mercury lamp (TQ 150). The pale-rose solutionis added to solid [Cp”2Zr(1:1-As4)] (1) (100 mg, 0.13 mmol). After stirring for 16 h atroom temperature, the solvent of the red-brown reaction mixture is removed in vacuo,extracted with 10 mL n-pentane and filtered via cannula. A red solution is obtained. Violetcrystals of 3 suitable for single crystal X-ray structure analysis were obtained by storing aconcentrated solution at 78 C. Crystalline yield: 15 mg (0.014 mmol, 11%).1H NMR (C6D6, 298 K): d [ppm] = 1.25 (s, 18 H, CCH3), 1.36 (s, 36 H, CCH3), 4.99 (t,2 H, C5H3tBu2), 5.26 (t, 2 H, C5H3tBu2), 5.42 (t, 2 H, C5H3tBu2); elemental analysis (%):calculated for [C40H52ZrAs4Mn2O4] (1097.62 gmol1): C, 43.77; H, 4.78; found: C, 42.68;H, 5.13; IR (toluene): [cm1] = 1928 (s), 1873 (s); LIFDI MS (toluene): m/z (%): 1095.9(M+, 42), 919.9 (M+-[CpMn(CO)2], 100); crystal data for C40H52As4Mn2O4Zr, triclinic, P 1P-1, a = 11.4684(3) Å, b = 12.1340(4) Å, c = 16.8248(4) Å, = 80.103(2), = 89.979(2), = 63.838(2), V = 2080.60(11) Å3.
	at -40℃; for 0.833333h;UV-irradiation; Inert atmosphere;	A red solution obtained by theUV irradiation of C5H5Mn(CO)3 (0.06 g, 0.24 mmol)in THF (15 mL) at -40 for 50 min

Reference： [1]Chemische Berichte,1983,vol. 116,p. 2574 - 2590
[2]Chemische Berichte,1981,vol. 114,p. 276 - 284
[3]Journal of the American Chemical Society,1998,vol. 120,p. 2202 - 2203
[4]Chemische Berichte,1995,vol. 128,p. 251 - 258
[5]Inorganic Chemistry,2010,vol. 49,p. 7597 - 7604
[6]Journal of Organometallic Chemistry,2013,vol. 729,p. 14 - 19
[7]Organometallics,2013,vol. 32,p. 4359 - 4365
[8]Journal of Organometallic Chemistry,2017,vol. 840,p. 11 - 22
[9]Chemistry - A European Journal,2017,vol. 23,p. 10319 - 10327
[10]Russian Journal of Coordination Chemistry,2019,vol. 45,p. 706 - 711
Koord. Khim.,2019,vol. 45,p. 611 - 616,6
[11]Molecules,2021,vol. 26
[12]Russian Journal of Coordination Chemistry,2021,vol. 47,p. 546 - 550
Koord. Khim.,2021,vol. 47,p. 484 - 488

15
[ 12079-65-1 ]
[ 536-74-3 ]
η(5)-cyclopentadienyl(phenylvinylidene)(dicarbonyl)manganese [ No CAS ]

Reference： [1]Inorganica Chimica Acta,1995,vol. 230,p. 97 - 104
Inorg. Chim. Acta,

16
[ 12079-65-1 ]
C5H5(PMe3)Co{μ-CO}{μ-CS}Mn(CO)C5H5 [ No CAS ]
C₅H₅Co(P(CH₃)3)(CO)(CS(Mn(CO)2(C₅H₅)))Mn(CO)C₅H₅ [ No CAS ]

Reference： [1]Journal of Organometallic Chemistry,1988,vol. 347,p. 137 - 150

17
[ 12079-65-1 ]
(η(5)-C5H4I)Mn(CO)3 [ No CAS ]

Reference： [1]Organometallics,1988,vol. 7,p. 2566 - 2567

18
[ 12079-65-1 ]
(acetylcyclopentadienyl)tricarbonylmanganese [ No CAS ]

Reference： [1]Journal of Organometallic Chemistry,1993,vol. 454,p. 183 - 198

19
[ 12079-65-1 ]
(η5-cyclopentadienyl)bis(triphenylphosphine)carbonylmanganese [ No CAS ]

Reference： [1]Journal of the Chemical Society, Dalton Transactions,
Journal of the Chemical Society, Dalton Transactions: Inorganic Chemistry (1972-1999),1977,p. 931 - 937
[2]Journal of the Chemical Society, Faraday Transactions 1: Physical Chemistry in Condensed Phases,1989,vol. 85,p. 3913 - 3926
[3]Organometallics,1983,vol. 2,p. 267 - 275

20
[ 12079-65-1 ]
[ 6104-47-8 ]
(n-η2-diphenylphosphinoethyne)bis((η5-cyclopentadienyl)dicarbonylmanganese) [ No CAS ]
(η5-cyclopentadienyl)(diphenylphosphinoethyne)dicarbonylmanganese [ No CAS ]

Yield	Reaction Conditions	Operation in experiment
1: 51.8% 2: 29.8%	With tetrahydrofuran In tetrahydrofuran Irradiation (UV/VIS); Ar atmosphere; irradiation of CpMn(CO)3 (1000 W quartz-mercury lamp, 5°C, 3 h), addn. of Ph2PCCH, stirring (15°C, 2 h); solvent removal, chromy. (SiO2, petroleum ether/CH2Cl2 9:1, 4:1); elem. anal.;

Reference： [1]Kolobova, N. E.; Derunov, V. V.; Shilova, O. S.; Isaeva, T. A.; Khandozhko, V. N. [Bulletin of the Academy of Sciences of the USSR Division of Chemical Science, 1988, vol. 37, p. 732 - 734][Bull. Acad. Sci. USSR, Div. Chem. Sci. (Engl. Transl.), 1988, vol. 37, p. 852 - 855]

21
[ 12079-65-1 ]
[ 1663-45-2 ]
carbonyl(η⁵cyclopentadienyl)[1,2bis(diphenylphosphanyl)ethane κ²P,P']manganese(I) [ No CAS ]

Yield	Reaction Conditions	Operation in experiment
27%	In tetrahydrofuran; for 23h;Irradiation; Inert atmosphere;	General procedure: A solution of [(C5H5)Mn(CO)3] (I) and a slight molar excessof the phosphane in tetrahydrofuran (THF, 120 ml) was irradiatedfor 7 h under argon. The colours of the solutionschanged from yellow to red with concomitant gas evolution.After further stirring for 16 h, the solvent was evacuated andthe residue dissolved in diethyl ether (Et2O) and filteredthrough a plug of silica gel. The solvent was evaporated againand the residue dissolved in the minimum amount of petroleumether. This solution was placed on top of a silica gelchromatography column (alumina in the case of 3a) and theproducts were eluted with a petroleum ether/Et2O (9:1 v/v)mixture. Evaporation of the eluate yielded the products asyellow powders. Recrystallization from petroleum ether (with some added Et2O) by slow evaporation in a refrigerator at5 C yielded crystals of all three compounds.

Reference： [1]Acta Crystallographica Section C: Structural Chemistry,2021,vol. 77,p. 633 - 640
[2]Journal of the Chemical Society, Faraday Transactions 1: Physical Chemistry in Condensed Phases,1989,vol. 85,p. 3913 - 3926

22
[ 12079-65-1 ]
[ 1079-66-9 ]
[ 62980-80-7 ]

Reference： [1]Journal of Organometallic Chemistry,1981,vol. 209,p. 233 - 244

23
[ 12079-65-1 ]
η,η(5)-fulvalenedimanganesehexacarbonyl [ No CAS ]

Reference： [1]Journal of the American Chemical Society,2000,vol. 122,p. 5477 - 5485
[2]Zeitschrift fur Naturforschung, B: Chemical Sciences,1993,vol. 48,p. 161 - 170

24
[ 12079-65-1 ]
[ 33513-42-7 ]
tricarbonyl(formylcyclopentadienyl)manganese [ No CAS ]

Yield	Reaction Conditions	Operation in experiment
94.5%		[0079] 5 g of cyclopentadienyl manganese tricarbonyl was weighed and dissolved in 60 mL anhydrous tetrahydrofuran. A solution of N-butyl lithium in hexane (19.1 mL, 1.6 mol/L) was dropwise added to the tetrahydrofuran solution under the protection of -78 C. argon. After the dropwise addition, 4.84 mL DMF was added to obtain a mixture which was stirred at room temperature for 2 h. After the reaction, 200 mL hydrochloric acid (3 N) was added to the resultant mixture, then 200 mL water was added, and the mixture obtained was extracted with hexane. The organic phase was washed with water and dried with anhydrous sodium sulfate, and after a process of reduced pressure distillation, 5.37 g brown solid (cyclopentadiene formaldehyde tricarbonyl manganese) was obtained with a yield of 94.5%.

Reference： [1]Patent: US2020/10496,2020,A1 .Location in patent: Paragraph 0079
[2]Bulletin of the Academy of Sciences of the USSR Division of Chemical Science,1980,vol. 29,p. 1701 - 1705
Bull. Acad. Sci. USSR, Div. Chem. Sci. (Engl. Transl.),1980,p. 2387 - 2391
[3]Journal of Organometallic Chemistry,2003,vol. 668,p. 17 - 24
[4]Organometallics,2012,vol. 31,p. 6880 - 6886
[5]Journal of Organometallic Chemistry,2016,vol. 817,p. 15 - 20
[6]Journal of Organometallic Chemistry,2018,vol. 867,p. 71 - 78

25
[ 12079-65-1 ]
[ 88686-45-7 ]
(OC(t-Bu)CH)2NP(η5-cyclopentadienyl)Mn(CO)2 [ No CAS ]

Reference： [1]Journal of the American Chemical Society,1991,vol. 113,p. 1799 - 1805

26
[ 12079-65-1 ]
(OC(t-Bu)CH)2NPSb [ No CAS ]
(OC(t-Bu)CH)2NSb{(η5-cyclopentadienyl)Mn(CO)2}2 [ No CAS ]

Reference： [1]Journal of the American Chemical Society,1991,vol. 113,p. 1799 - 1805

27
[ 12079-65-1 ]
[ 62-53-3 ]
CpMn(CO)<SUB>2</SUB>(PhNH<SUB>2</SUB>) [ No CAS ]

Reference： [1]Journal of Organometallic Chemistry,1985,vol. 281,p. 249 - 262
[2]RSC Advances,2015,vol. 5,p. 15159 - 15163

28
[ 12079-65-1 ]
hexacarbonyl(μ,η5:η5-fulvalene)dimanganese [ No CAS ]

Reference： [1]Journal of Organometallic Chemistry,1987,vol. 319,p. 183 - 196

29
[ 119-61-9 ]
[ 12079-65-1 ]
(1-(diphenylhydroxymethyl)cyclopentadienyl)manganese tricarbonyl [ No CAS ]

Reference： [1]Organometallics,2001,vol. 20,p. 227 - 230

30
[ 50-00-0 ]
[ 12079-65-1 ]
[ 12152-69-1 ]

Reference： [1]Organometallics,2016,vol. 35,p. 4090 - 4098
[2]Organometallics,2008,vol. 27,p. 289 - 296

31
[ 12079-65-1 ]
Cp₃UCHPMe₂Ph [ No CAS ]
[ 108-88-3 ]
[ 92472-04-3 ]

Reference： [1]Journal of the American Chemical Society,1984,vol. 106,p. 7245 - 7247

32
[ 12079-65-1 ]
(η5-C5H4COPh)Mn(CO)3 [ No CAS ]
(CO)3Mn(C₅H₄)C(C₆H₅)((CO)3Mn(C₅H₄))OH [ No CAS ]

Reference： [1]Journal of Organometallic Chemistry,1993,vol. 450,p. 27 - 31

33
[ 12079-65-1 ]
[ 98-88-4 ]
(CO)3Mn(C₅H₄)C(C₆H₅)((CO)3Mn(C₅H₄))OH [ No CAS ]

Reference： [1]Journal of Organometallic Chemistry,1995,vol. 503,p. 277 - 288

34
[ 12079-65-1 ]
[ 931-53-3 ]
C₅H₅Mn(CO)2(CNC₆H₁₁) [ No CAS ]

Reference： [1]Journal of Organometallic Chemistry,1983,vol. 255,p. 87 - 94

35
[ 12079-65-1 ]
[ 10340-91-7 ]
C₅H₅Mn(CO)2(CNCH₂C₆H₅) [ No CAS ]

Reference： [1]Journal of Organometallic Chemistry,1983,vol. 255,p. 87 - 94

36
[ 12079-65-1 ]
[ 12267-07-1 ]
(η5-cymantrenylphenylhydroxymethylcyclopentadienyl)tricarbonylrhenium [ No CAS ]

Reference： [1]Journal of Organometallic Chemistry,1993,vol. 450,p. 27 - 31

37
[ 12079-65-1 ]
Re(pentamethylcyclopentadiene)(ethyne)(NO)P(C₆H₅)3 [ No CAS ]
[ 420-37-1 ]
{(η5-C5Me5)Re(NO)(PPh3)(C3(OMe))Mn(CO)2(η5-C5H5)} [ No CAS ]

Reference： [1]Journal of the American Chemical Society,1998,vol. 120,p. 11071 - 11081

38
[ 12079-65-1 ]
{(η5-C5Me5)Re(NO)(PPh3)(C2Li)} [ No CAS ]
{(η5-C5Me5)Re(NO)(PPh3)(C3(OMe))Mn(CO)2(η5-C5H5)} [ No CAS ]

Reference： [1]Journal of the American Chemical Society,1993,vol. 115,p. 3824 - 3825

39
[ 12079-65-1 ]
[ 6141-55-5 ]
(C₅H₅)Mn(CO)2(C(C₆H₄CH₂)2) [ No CAS ]

Reference： [1]Journal of Organometallic Chemistry,1984,vol. 264,p. 327 - 352
[2]Zeitschrift fur Naturforschung, Teil B: Anorganische Chemie, Organische Chemie,1983,vol. 38,p. 1392 - 1398

40
[ 12079-65-1 ]
[ 6141-56-6 ]
(C₅H₅)Mn(CO)2(C(C₆H₄CH)2) [ No CAS ]

Reference： [1]Journal of Organometallic Chemistry,1984,vol. 264,p. 327 - 352

41
[ 12079-65-1 ]
[ 685498-28-6 ]
Mn(η-cyclopentadienyl)(CO)2(methyl isocyanide) [ No CAS ]

Reference： [1]Inorganica Chimica Acta,1977,vol. 22,p. 265 - 268
[2]Journal of Organometallic Chemistry,1983,vol. 255,p. 87 - 94

42
[ 12079-65-1 ]
[ 18344-70-2 ]
{μ-(1,4-bis(benzylidene)benzene)}bis{dicarbonyl(η5-cyclopentadienyl)manganese} [ No CAS ]

Reference： [1]Journal of Organometallic Chemistry,1984,vol. 264,p. 327 - 352
[2]Zeitschrift fur Naturforschung, Teil B: Anorganische Chemie, Organische Chemie,1983,vol. 38,p. 1392 - 1398

43
[ 12079-65-1 ]
[ 86660-77-7 ]
[ 93612-14-7 ]

Reference： [1]Inorganic Chemistry,1986,vol. 25,p. 2384 - 2389

44
η(5)-cyclopentadienyl(phenylvinylidene)(dicarbonyl)manganese [ No CAS ]
[ 12079-65-1 ]
2C₅H₅^(1-)*4CO*2Mn⁽²⁺⁾*C₆H₅CHC^(2-)=(C₅H₅)2(CO)4Mn₂(CCHC₆H₅) [ No CAS ]

Reference： [1]Inorganica Chimica Acta,1985,vol. 96,p. 1 - 8

45
[ 75-79-6 ]
[ 12079-65-1 ]
[ 114835-71-1 ]

Reference： [1]Journal of Organometallic Chemistry,1987,vol. 329,p. 43 - 50

46
[ 12079-65-1 ]
[ 1179-06-2 ]
μ-[1,4-Bis(diphenylphosphino)benzol]-bis[dicarbonyl-(η5-cyclopentadienyl)mangan] [ No CAS ]

Reference： [1]Chemische Berichte,1982,vol. 115,p. 3257 - 3270

47
[ 12079-65-1 ]
[ 85320-12-3 ]
[ 85320-14-5 ]
[ 85320-15-6 ]

Reference： [1]Journal of the American Chemical Society,1983,vol. 105,p. 3882 - 3886

48
[ 12079-65-1 ]
[ 85320-11-2 ]
[ 85320-13-4 ]

Reference： [1]Journal of the American Chemical Society,1983,vol. 105,p. 3882 - 3886

49
[ 12079-65-1 ]
[ 83334-39-8 ]
[ 85320-15-6 ]

Reference： [1]Journal of the American Chemical Society,1983,vol. 105,p. 3882 - 3886

50
[ 12079-65-1 ]
[ 13497-36-4 ]
[ 73752-23-5 ]

Reference： [1]Journal of Organometallic Chemistry,1980,vol. 187,p. 277 - 286

51
[ 12079-65-1 ]
[ 72553-94-7 ]
[ 73752-25-7 ]

Reference： [1]Journal of Organometallic Chemistry,1980,vol. 187,p. 277 - 286

52
[ 12079-65-1 ]
[ 201653-37-4 ]
(Salen)Ge=Mn(CO)2(η5-C5H5) [ No CAS ]

Reference： [1]Inorganic Chemistry,2000,vol. 39,p. 5492 - 5495
[2]Inorganic Chemistry,2000,vol. 39,p. 5492 - 5495

53
[ 16567-18-3 ]
[ 12079-65-1 ]
[ 342813-38-1 ]

Reference： [1]Journal of Organometallic Chemistry,2001,vol. 622,p. 66 - 73

54
[ 12079-65-1 ]
[ 7650-91-1 ]
[ 206365-32-4 ]

Reference： [1]Inorganica Chimica Acta,1998,vol. 272,p. 101 - 108

55
[ 75-21-8 ]
[ 12079-65-1 ]
[ 98-59-9 ]
[ 215460-58-5 ]

Reference： [1]Inorganica Chimica Acta,1998,vol. 280,p. 316 - 321

56
[ 188290-36-0 ]
[ 12079-65-1 ]
[ 368-39-8 ]
[ 214687-09-9 ]

Reference： [1]Journal of Organometallic Chemistry,1998,vol. 566,p. 133 - 142

57
[ 12079-65-1 ]
[ 252334-30-8 ]
[ 408499-80-9 ]

Reference： [1]Journal of Organometallic Chemistry,2002,vol. 641,p. 113 - 120

58
[ 29786-93-4 ]
[ 12079-65-1 ]
spiro[oxirane-2,17β'-estra-1,3,5(10)-trien-3-ol] [ No CAS ]
17α-[(cyclopentadienyltricarbonylmanganio)methyl]estra-1,3,5(10)-triene-3,17β-diol [ No CAS ]

Reference： [1]Journal of the American Chemical Society,1995,vol. 117,p. 8372 - 8380

59
[ 12079-65-1 ]
bis(cyclopentadienyl)(tert-butylimido)(tetrahydrofuran)zirconium(IV) [ No CAS ]
(C₅H₅)2Zr(O)(NC₄H₉)Zr(C₅H₅)2 [ No CAS ]
C₅H₅Mn(CO)2(CNC(CH₃)3) [ No CAS ]
(C₅H₅)2ZrNHC₄H₉C₅H₄Mn(CO)3 [ No CAS ]

Reference： [1]Journal of the American Chemical Society,1995,vol. 117,p. 5877 - 5878

60
[ 12079-65-1 ]
bis(cyclopentadienyl)(tert-butylimido)(tetrahydrofuran)zirconium(IV) [ No CAS ]
(C₅H₅)2ZrNHC₄H₉C₅H₄Mn(CO)3 [ No CAS ]

Reference： [1]Journal of the American Chemical Society,1995,vol. 117,p. 5877 - 5878

61
[ 12079-65-1 ]
[ 79-03-8 ]
[ 62010-78-0 ]

Reference： [1]Organometallics,2001,vol. 20,p. 4554 - 4561
[2]Journal of Organometallic Chemistry,2002,vol. 643-644,p. 350 - 356
[3]Molecules,2017,vol. 22

62
[ 12079-65-1 ]
[ 162404-88-8 ]
[ 525608-98-4 ]

Reference： [1]Zeitschrift fur Anorganische und Allgemeine Chemie,2002,vol. 628,p. 2919 - 2929

63
[ 12079-65-1 ]
[ 1159-86-0 ]
[ 172687-83-1 ]

Reference： [1]Journal of Organometallic Chemistry,1995,vol. 503,p. 277 - 288

64
[ 12079-65-1 ]
[ 171562-97-3 ]
[ 341-02-6 ]
[ 158840-67-6 ]

Reference： [1]Organometallics,1995,vol. 14,p. 5273 - 5280

65
[ 12079-65-1 ]
[ 17157-02-7 ]
[ 208120-14-3 ]

Reference： [1]Russian Chemical Bulletin,1998,vol. 47,p. 524 - 525

66
[ 12079-65-1 ]
[ 7704-34-9 ]
(C₅H₄SH)Mn(CO)3 [ No CAS ]

Reference： [1]Journal of Organometallic Chemistry,1993,vol. 443,p. 1 - 8

67
[ 12079-65-1 ]
[ 406486-54-2 ]
[ 470479-17-5 ]

Reference： [1]Angewandte Chemie - International Edition,2002,vol. 41,p. 2304 - 2306

68
[ 12079-65-1 ]
[ 10294-33-4 ]
[ 1010720-67-8 ]

Reference： [1]Organometallics,2008,vol. 27,p. 764 - 768

69
[ 59699-77-3 ]
[ 12079-65-1 ]

Reference： [1]Journal of the American Chemical Society,2008,vol. 130,p. 9859 - 9870

70
[ 941-55-9 ]
[ 12079-65-1 ]
[ 64-17-5 ]
CmNH₂ [ No CAS ]

Reference： [1]Journal of the American Chemical Society,2008,vol. 130,p. 9859 - 9870

71
[ 12079-65-1 ]
[ 484067-66-5 ]
[ 1180667-83-7 ]

Reference： [1]Russian Journal of General Chemistry,2008,vol. 78,p. 1573 - 1576
[2]Russian Journal of General Chemistry,2016,vol. 86,p. 338 - 343
Zh. Obshch. Khim.,2016,vol. 86,p. 338 - 343,6

72
[ 85-44-9 ]
[ 12079-65-1 ]
[ 1224100-76-8 ]

Yield	Reaction Conditions	Operation in experiment
51%		A mixture of phthalic anhydride (5.92 g, 40 mmol) and aluminiumchloride (10.67 g, 80 mmol) in dichloromethane (80 ml)was stirred for 30 min on an ice bath. Then the solution ofC5H5Mn(CO)3 (8.12 g, 40 mmol) in CH2Cl2 (80 ml) was added dropwisefor 30 min and refluxed for 4 h. The resulting mixture waspoured into ice mixed with concentrated HCl (5 ml). After all icemelted, the pale-yellow precipitate (insoluble in water and CH2Cl2)was separated with Buchner funnel and purified by recrystallizationfrom boiling isopropyl alcohol.Yield: yellow crystal, 6.78 g, 51%.

Reference： [1]Polyhedron,2019,vol. 169,p. 253 - 260
[2]Dalton Transactions,2010,vol. 39,p. 2536 - 2545

73
[ 12079-65-1 ]
[ 110-18-9 ]
zinc dibromide [ No CAS ]
BrZn(TMEDA)2CpMn(CO)3 [ No CAS ]

Reference： [1]Inorganica Chimica Acta,2011,vol. 369,p. 32 - 39

74
[ 109-04-6 ]
[ 12079-65-1 ]
[ 7646-85-7 ]
[ 1309383-88-7 ]

Reference： [1]Inorganica Chimica Acta,2011,vol. 370,p. 224 - 229

75
[ 12079-65-1 ]
[ 124-38-9 ]
tricarbonylcyclopentadienylmanganese carboxylic acid [ No CAS ]

Yield	Reaction Conditions	Operation in experiment
62.5%		[0073] 1 g of cyclopentadienyl manganese tricarbonyl was weighed and dissolved in 10 mL anhydrous tetrahydrofuran. A solution of N-butyl lithium in hexane (3.37 mL, 1.6 mol/L) was dropwise added to the tetrahydrofuran solution under the protection of -45 C. argon. After the dropwise addition, excess dry ice was added to obtain a mixture which was stirred at room temperature for 2 h. After the reaction, the solvent was evaporated under reduced pressure, and then water and ethyl acetate were added to the mixture obtained with being shaken greatly. Hydrochloric acid was added to

Reference： [1]Patent: US2020/10496,2020,A1 .Location in patent: Paragraph 0072-0073
[2]Journal of Molecular Structure,2013,vol. 1033,p. 187 - 199
[3]Polyhedron,2013,vol. 65,p. 110 - 121

76
[ 12079-65-1 ]
[ 6026-02-4 ]
[ 1421773-00-3 ]

Yield	Reaction Conditions	Operation in experiment
	With n-butyllithium; In tetrahydrofuran; hexane; at 20℃;Darkness;	Under purified argon nBuLi in hexane (2.5 m, 0.95 mL, 2.38 mmol) was diluted with hexane (4 mL) and added to a solution of <strong>[12079-65-1]CpMn(CO)3</strong> (408 mg,2.00 mmol) in THF (20 mL) cooled to -78 C with exclusion of light. After 1 h at -78 C, Et2NMe2SiCl (0.4 mL, 360 mg,2.17 mmol) in hexane (4.5 mL) was added slowly. After warming up to room temperature and stirring overnight, an orange-brown solution of Et2NMe2SiC5H4Mn(CO)3 was obtained

Reference： [1]European Journal of Inorganic Chemistry,2012,p. 6018 - 6026

77
[ 29786-93-4 ]
[ 12079-65-1 ]
tricarbonyl(lithiocyclopentadienyl)manganese [ No CAS ]

Yield	Reaction Conditions	Operation in experiment
	In tetrahydrofuran; hexane; at -78℃; for 1h;Darkness; Inert atmosphere;	Under purified argon nBuLi in hexane (2.5 m, 0.95 mL, 2.38 mmol) was diluted with hexane (4 mL) and added to a solution of <strong>[12079-65-1]CpMn(CO)3</strong> (408 mg,2.00 mmol) in THF (20 mL) cooled to -78 C with exclusion of light. After 1 h at -78 C, Et2NMe2SiCl (0.4 mL, 360 mg,2.17 mmol) in hexane (4.5 mL) was added slowly. After warming up to room temperature and stirring overnight, an orange-brown solution of Et2NMe2SiC5H4Mn(CO)3 was obtained

Reference： [1]European Journal of Inorganic Chemistry,2012,p. 6018 - 6026

78
[ 12079-65-1 ]
[ 106-95-6 ]
[ 12301-12-1 ]

Reference： [1]Russian Chemical Bulletin,2012,vol. 61,p. 2326 - 2337
Izv. Akad. Nauk, Ser. Khim.,2012,p. 2304 - 2315,12
[2]Advanced Synthesis and Catalysis,2015,vol. 357,p. 2255 - 2264

79
[ 12079-65-1 ]
1,3-dicyclohexyl-1H-imidazol-3-ium chloride [ No CAS ]
Cp(CO)2Mn(ICy) [ No CAS ]