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Chemical Structure| 1215692-34-4 Chemical Structure| 1215692-34-4

Structure of 1215692-34-4

Chemical Structure| 1215692-34-4

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Product Details of [ 1215692-34-4 ]

CAS No. :1215692-34-4
Formula : C40H30IrN3
M.W : 744.90
SMILES Code : C=1C=CC(=CC1)C=2C=[N]3C(=CC2C)C=4C=CC=C[C-]4[Ir+3]563([C-]=7C=CC=CC7C=8C=CC=C[N]85)[C-]=9C=CC=CC9C=%10C=CC=C[N]%106
MDL No. :N/A

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Application In Synthesis of [ 1215692-34-4 ]

* All experimental methods are cited from the reference, please refer to the original source for details. We do not guarantee the accuracy of the content in the reference.

  • Downstream synthetic route of [ 1215692-34-4 ]

[ 1215692-34-4 ] Synthesis Path-Downstream   1~1

  • 1
  • [ 1008-89-5 ]
  • 4-methyl-2,5-diphenylpyridine [ No CAS ]
  • iridium nitrate [ No CAS ]
  • [ 94928-86-6 ]
  • [ 1215692-67-3 ]
  • [ 1215692-34-4 ]
  • Ir(4-methyl-2,5-diphenylpyridine)<SUB>3</SUB> [ No CAS ]
YieldReaction ConditionsOperation in experiment
17.9%Chromat.; 31.8%Chromat.; 40.6%Chromat.; 9.7%Chromat. In water; ethylene glycol; at 180℃; for 17h;Inert atmosphere; 807.6 mg of an iridium nitrate aqueous solution (iridium content: 9.52 wt percent), 124 mg of compound (A), 98 mg of compound (I) and 5 ml of ethylene glycol were reacted by heating in an argon atmosphere at 180° C. for 17 hours. The reaction mixture was cooled to room temperature, and then extracted with dichloromethane added thereto. The organic extract was concentrated under reduced pressure, and from the precipitated solid, origin impurities were removed by silica gel chromatography (eluant: dichloromethane). The yield of the solid obtained after purification was 196 mg. Analysis was performed by HPLC (Prominence manufactured by Shimadzu Corporation, column: normal phase silica gel, mobile phase: mixed solvent of THF (40percent) and hexane (60percent), detection wavelength: 300 nm), and the result showed that the production ratios of compounds (1), (37), (38) and (39) were 17.9percent, 40.6percent, 31.8percent and 9.7percent (peak area ratio), respectively.
 

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