Home Cart Sign in  
Chemical Structure| 122200-58-2 Chemical Structure| 122200-58-2

Structure of 122200-58-2

Chemical Structure| 122200-58-2

*Storage: {[sel_prStorage]}

*Shipping: {[sel_prShipping]}

,{[proInfo.pro_purity]}

4.5 *For Research Use Only !

{[proInfo.pro_purity]}
Cat. No.: {[proInfo.prAm]} Purity: {[proInfo.pro_purity]}

Change View

Size Price VIP Price

US Stock

Global Stock

In Stock
{[ item.pr_size ]} Inquiry {[ getRatePrice(item.pr_usd,item.pr_rate,item.mem_rate,item.pr_is_large_size_no_price, item.vip_usd) ]}

US Stock: ship in 0-1 business day
Global Stock: ship in 5-7 days

  • {[ item.pr_size ]}

In Stock

- +

Please Login or Create an Account to: See VIP prices and availability

US Stock: ship in 0-1 business day
Global Stock: ship in 2 weeks

  • 1-2 Day Shipping
  • High Quality
  • Technical Support
Product Citations

Alternative Products

Product Details of [ 122200-58-2 ]

CAS No. :122200-58-2
Formula : C10H9IO2
M.W : 288.08
SMILES Code : COC(C12C3C4C1C5C2C3C45I)=O
MDL No. :MFCD24524097
InChI Key :YAHYLPAQBZZHKI-UHFFFAOYSA-N
Pubchem ID :369180

Safety of [ 122200-58-2 ]

GHS Pictogram:
Signal Word:Warning
Hazard Statements:H315-H319
Precautionary Statements:P264-P280-P302+P352-P337+P313-P305+P351+P338-P362+P364-P332+P313

Application In Synthesis of [ 122200-58-2 ]

* All experimental methods are cited from the reference, please refer to the original source for details. We do not guarantee the accuracy of the content in the reference.

  • Downstream synthetic route of [ 122200-58-2 ]

[ 122200-58-2 ] Synthesis Path-Downstream   1~1

  • 1
  • [ 32846-66-5 ]
  • [ 122200-58-2 ]
YieldReaction ConditionsOperation in experiment
With [bis(acetoxy)iodo]benzene; iodine; In toluene; at 80℃; for 8h;Inert atmosphere; A suspension of 28 (3.46 g, 16.8 mmol) in PhMe (265 mL) was treated with PhI(OAc)2 (16.2 g, 50.4 mmol, 3.0 equiv.) and I2 (12.7 g, 50.4 mmol, 3 equiv.) and stirred at 80 C for 8 h. After cooling to rt, n-pentane (135 mL) was added to the reaction mixture. The solution was washed with sat. aq. Na2SO3 (2 × 45 mL), H2O (45 mL), and brine (45 mL), dried (MgSO4), and the solvent reduced in vacuo. The remaining liquid was dissolved in THF (90 mL), and treated with a solution of NaOH (679 mg, 17.0 mmol, 1.01 equiv.) in MeOH (65 mL) and H2O (20 mL). After stirring at rt for 14 h, the solution was evaporated to near-dryness, dissolved in H2O (45 mL), and acidified to pH 1 with 32% aq. HCl. The precipitated solid was filtered, washed with H2O (5 mL), and dried under vacuum to constant weight furnishing 29 (3.42 g, 74%) as an off-white solid with spectroscopic properties matching those reported:4 m.p. 209 C (dec.); (lit. m.p.4 215 C, dec.); 1H NMR (200.1 MHz, CD3OD); delta 4.38-4.32 (3H, m), 4.28-4.21 (3H, m).
 

Historical Records