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Chemical Structure| 1315544-67-2 Chemical Structure| 1315544-67-2

Structure of 1315544-67-2

Chemical Structure| 1315544-67-2

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Product Details of [ 1315544-67-2 ]

CAS No. :1315544-67-2
Formula : C10H12ClNO3
M.W : 229.66
SMILES Code : O=C(C1=C(CCl)[N+]([O-])=CC(C)=C1)OCC

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Application In Synthesis of [ 1315544-67-2 ]

* All experimental methods are cited from the reference, please refer to the original source for details. We do not guarantee the accuracy of the content in the reference.

  • Downstream synthetic route of [ 1315544-67-2 ]

[ 1315544-67-2 ] Synthesis Path-Downstream   1~1

  • 1
  • [ 124796-97-0 ]
  • [ 1315544-67-2 ]
YieldReaction ConditionsOperation in experiment
63% With 3-chloro-benzenecarboperoxoic acid; In dichloromethane; at 20 - 25℃; for 18h; As shown in step 11 -iii of Scheme 11 , Compound 2036 (465 mg, 2.18 mmol) was placed in a 40 ml vial, diluted with DCM (4.35 mL), and 3-chlorobenzenecarboperoxoic acid (m-CPBA, 551 mg, 2.39 mmol) was added at room temperature with stirring. After 18 hours, the mixture was diluted with 30 mL of DCM, washed with saturated sodium carbonate (3 x 5 mL), and washed with brine. The organics were passed through a phase separator and concentrated to dryness under reduced pressure to give ethyl 2-(chloromethyl)-3- (ethoxycarbonyl)-5-methylpyridine 1-oxide (Compound 2037, 318 mg, 1.38 mmol, 63% yield): ESMS (M+l) 230.14. This material was used as is in subsequent reactions
 

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