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Chemical Structure| 14032-66-7 Chemical Structure| 14032-66-7

Structure of 14032-66-7

Chemical Structure| 14032-66-7

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Tobias Esser ; André Wassenberg ; Jan-Christian Raabe ; Dorothea Voß ; Jakob Albert ;

Abstract: The main objective of this study was to gain a deeper understanding of oxidative valorization of humins using polyoxometalate (POM) catalysts. Based on experiments using individual monofuran derivatives as a substrate, evident reaction pathways for the conversion to were postulated. By analogous routes, difuran derivatives or branched rings could also be converted to and formic acid, respectively. Hereby, the monovanadium-substituted catalyst was found to be superior compared to other structures in terms of activity and selectivity due to its unique electrochemical properties. In detail, H4[PVMo11O40] showed the lowest peak potential in Square-Wave-Voltammetry measurements, achieving the highest activity and selectivity. Hereby, a deeper understanding of the selective oxidation of humin model substrates like derivatives of varying complexity could be achieved. Therefore, helpful conclusions can be drawn for the transformation of humins representing a decisive step toward efficient processes for their valorization.

Keywords: biomass ; polyoxometalate catalysts ; humin ; selective oxidation ; maleic acid

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Product Details of [ 14032-66-7 ]

CAS No. :14032-66-7
Formula : C4H4O3
M.W : 100.07
SMILES Code : O=C1OC(O)C=C1
MDL No. :MFCD00015554
InChI Key :DUAZKLYNTLDKQK-UHFFFAOYSA-N
Pubchem ID :21076

Safety of [ 14032-66-7 ]

GHS Pictogram:
Signal Word:Warning
Hazard Statements:H302-H315-H319-H335
Precautionary Statements:P261-P264-P270-P271-P280-P301+P312-P302+P352-P304+P340-P305+P351+P338-P330-P332+P313-P337+P313-P362-P403+P233-P405-P501

Application In Synthesis of [ 14032-66-7 ]

* All experimental methods are cited from the reference, please refer to the original source for details. We do not guarantee the accuracy of the content in the reference.

  • Downstream synthetic route of [ 14032-66-7 ]

[ 14032-66-7 ] Synthesis Path-Downstream   1~2

  • 1
  • [ 98-01-1 ]
  • [ 64-17-5 ]
  • [ 14032-66-7 ]
  • [ 13529-27-6 ]
  • [ 109-94-4 ]
  • 2
  • [ 13529-27-6 ]
  • [ 64-17-5 ]
  • [ 14032-66-7 ]
  • [ 122-51-0 ]
 

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