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[ CAS No. 14092-11-6 ] {[proInfo.proName]}

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Cat. No.: {[proInfo.prAm]}
Chemical Structure| 14092-11-6
Chemical Structure| 14092-11-6
Structure of 14092-11-6 * Storage: {[proInfo.prStorage]}
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Product Details of [ 14092-11-6 ]

CAS No. :14092-11-6 MDL No. :
Formula : C11H19N Boiling Point : -
Linear Structure Formula :- InChI Key :-
M.W : 165.28 Pubchem ID :-
Synonyms :

Safety of [ 14092-11-6 ]

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Application In Synthesis of [ 14092-11-6 ]

* All experimental methods are cited from the reference, please refer to the original source for details. We do not guarantee the accuracy of the content in the reference.

  • Downstream synthetic route of [ 14092-11-6 ]

[ 14092-11-6 ] Synthesis Path-Downstream   1~9

  • 1
  • [ 290-87-9 ]
  • [ 14092-11-6 ]
  • [ 4436-63-9 ]
  • 2
  • [ 14092-11-6 ]
  • [ 873-41-6 ]
  • [ 135962-53-7 ]
YieldReaction ConditionsOperation in experiment
38% In diethyl ether at 0℃; for 0.5h;
  • 3
  • [ 14092-11-6 ]
  • [ 64-17-5 ]
  • [ 3289-28-9 ]
YieldReaction ConditionsOperation in experiment
72% With lead(IV) acetate; boron trifluoride diethyl etherate In benzene for 30h; Ambient temperature;
  • 4
  • [ 14092-11-6 ]
  • [ 898-22-6 ]
  • [ 117682-25-4 ]
  • 5
  • [ 14092-11-6 ]
  • [ 3775-29-9 ]
  • 8-methylenebicyclo[4.3.1]decan-10-one [ No CAS ]
YieldReaction ConditionsOperation in experiment
60% With palladium diacetate; triphenylphosphine In acetonitrile at 45℃; for 1h;
  • 6
  • [ 14092-11-6 ]
  • [ 94446-97-6 ]
  • [ 874947-71-4 ]
  • 7
  • [ 14092-11-6 ]
  • [ 2003-10-3 ]
  • [ 62368-85-8 ]
YieldReaction ConditionsOperation in experiment
In <i>N</i>-methyl-acetamide; water 45.a EXAMPLE 45 a. A solution of 106.8 g (0.4 mole) of m-trifluoromethylphenacyl bromide in dry dimethylformamide is added dropwise to a cooled solution of 74.4 g (0.45 mole) of 1-pyrrolidino-1-cycloheptene in dry dimethylformamide. After stirring at ambient temperature for 5 hours, water is added and the mixture is stirred overnight. The reaction mixture is poured into 1500 ml. of water and extracted with chloroform. The chloroform solution is washed with water, dried, and concentrated to a red oil, which is stirred at 60° C. for 1 hour in a high vacuum. Upon cooling, the oil solidifies to an orange solid of 2-(m-trifluoromethylphenacyl)cycloheptanone, m.p. 55°-60° C. The above structure is consistent with infra red and nuclear magnetic resonance spectra.
  • 8
  • [ 14092-11-6 ]
  • [ 114078-88-5 ]
  • [ 51490-23-4 ]
YieldReaction ConditionsOperation in experiment
67% In chloroform; at 0 - 45℃; for 0.75h;Molecular sieve; Compound (M-21) (2.00 g, 12.5 mmol) was dissolved in chloroform (25.0 mL), 4A molecular sieve (400 mg,powder) was added, compound (M-22) (3.10 g, 18.8 mmol) was added at 0C, and the mixture was stirred at 0C for 5min. After stirring at 45C for 40 min, the mixture was allowed to cool to room temperature. The solvent was evaporatedunder reduced pressure, and the residue was purified by silica gel column chromatography (n-hexane:ethyl acetate) togive compound (M-23) (yield 1.90 g, 67%)
  • 9
  • [ 14092-11-6 ]
  • [ 114078-88-5 ]
  • C10H12BrN [ No CAS ]
YieldReaction ConditionsOperation in experiment
67% In chloroform; at 0 - 45℃; for 0.75h;Molecular sieve; Compound (M-21) (2.00 g, 12.5 mmol)Was dissolved in chloroform (25.0 mL)4 A molecular sieve (400 mg, powder)And the compound (M-22) (3.10 g, 18.8 mmol) was added at 0 C.,And the mixture was stirred at 0 C. for 5 minutes.After stirring at 45 C. for 40 minutes, it was allowed to cool to room temperature.The solvent was distilled off under reduced pressure,The residue was purified by silica gel column chromatography (n-hexane: ethyl acetate)Compound (M-23)(Yield 1.90 g, yield 67%).
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