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Chemical Structure| 1493805-13-2 Chemical Structure| 1493805-13-2

Structure of 1493805-13-2

Chemical Structure| 1493805-13-2

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Product Details of [ 1493805-13-2 ]

CAS No. :1493805-13-2
Formula : C10H8N6
M.W : 212.21
SMILES Code : C1(N2C=NN=C2)=CC=CC(N3C=NN=C3)=C1
MDL No. :N/A
InChI Key :HVMMGTLUNJNHFE-UHFFFAOYSA-N
Pubchem ID :102583435

Safety of [ 1493805-13-2 ]

GHS Pictogram:
Signal Word:Warning
Hazard Statements:H315-H319
Precautionary Statements:P264-P280-P302+P352-P337+P313-P305+P351+P338-P362+P364-P332+P313

Application In Synthesis of [ 1493805-13-2 ]

* All experimental methods are cited from the reference, please refer to the original source for details. We do not guarantee the accuracy of the content in the reference.

  • Downstream synthetic route of [ 1493805-13-2 ]

[ 1493805-13-2 ] Synthesis Path-Downstream   1~1

  • 1
  • [ 628-36-4 ]
  • [ 108-45-2 ]
  • [ 1493805-13-2 ]
YieldReaction ConditionsOperation in experiment
86% at 100℃; for 12h; In the presence of a magnet,A reflux condenser and a thermometer, m-phenylenediamine (1 mmol) was added to the 50 mL three-necked round bottom flask,(2 mmol) of bisformylhydrazide was added and the mixture was stirred at 100 ° C for 12 hours.After completion of the reaction, the reaction solution was cooled to room temperature,A large amount of precipitate was precipitated, and the precipitate was recrystallized from water and ethanol in a yield of 86percent.Elemental analysis for C10H8N6 Calculated:C, 56.60; H, 3.80; N, 39.60. Found: C, 56.56; H, 3.75; N, 39.56. M-phenylenediamine and bis-formylhydrazine was 1: 2.
86% at 100℃; for 12h; Into a 50 mL three-necked round bottom flask equipped with a magnetic stirrer, a reflux condenser and a thermometer, m-phenylenediamine (1Mmol), bisformylhydrazide (2 mmol) and stirred at 100 ° C for 12 hours. After the completion of the reaction, the reaction solution was cooled to room temperature, a large amount of precipitate was precipitated, and the precipitate was recrystallized from water and ethanol in a yield of 86percent. Analysis for Theory: C, 56.60; 11.3.80; 139.60. The molar ratio of m-phenylenediamine and bis-formylhydrazine was 1: 2.
86% at 100℃; for 12h; A 50 mL three-necked round-bottomed flask equipped with a magnetic stirrer, reflux condenser and thermometer was charged with m-phenylenediamine (1Mmol), bisformylhydrazide (2 mmol), and the mixture was stirred at 100 ° C for 12 hours. After the completion of the reaction, the reaction solution was cooled to room temperature, and a large amount of precipitate was precipitated. The precipitate was recrystallized from water and ethanol to give a yield of 86percent.
86% at 100℃; for 12h; Equipped with a magnetic child within, a reflux condenser, a thermometer and three 50 mL round bottom flask were added m-phenylenediamine (1 mmol), formic hydrazide bis (2 mmol), stirring was started at 100 deg.] C, for 12 hours.After completion of the reaction, the reaction solution was cooled to room temperature, the precipitated heavy precipitate, the precipitate was washed with water and recrystallized from ethanol, yield 86percent
86% at 160℃; for 12h; In a 50 mL three-necked round bottom flask equipped with a magnet, a reflux condenser and a thermometer, m-phenylenediamine (1 mmol)Dibenzohydrazide(2 mmol), and the mixture was stirred at 160 ° C for 12 hours.After completion of the reaction, the reaction solution was lowered to room temperature, and a large amount of precipitate was precipitated, and the precipitate was recrystallized from water and ethanol to yield 86percent. Elemental analysis for C1QH8N6 Theory: C, 56.60; H, 3.80; N, 39.60. Found: C, 56.56; H, 3.75; N, 39.56.The molar ratio of m-phenylenediamine and dicarboxylic acid hydrazide was 1: 2.
86% at 100℃; for 12h; Methylene phenylenediamine (1 mmol) and dicarboxylic acid hydrazide (2 mmol) were added to a 50 mL three-necked round bottom flask equipped with a magnet, a reflux condenser and a thermometer, and the mixture was stirred at 100 ° C for 12 hours.After completion of the reaction, the reaction solution was lowered to room temperature, and a large amount of precipitate was precipitated, and the precipitate was recrystallized from water and ethanol to yield 86percent.Elemental analysis C1QH8N6 Theory: C, 56.60; 11,3.80; 139.60. The molar ratio of m-phenylenediamine and dicarboxylic acid hydrazide was 1: 2.
86% at 100℃; for 12h; m-Phenylenediamine (1 mmol) and 1,2-Diformylhydrazine (2 mmol) were added to a 50 mL three-necked round bottom flask equipped with a magnet, a reflux condenser and a thermometer and the mixture was stirred at 100 ° C for 12 hours. After completion of the reaction, the reaction solution was lowered to room temperature, and a large amount of precipitate was precipitated, and the precipitate was recrystallized from water and ethanol , yield 86percent.Elemental analysis C10H8N6 Theory: C, 56.60; 11,3.80; 139.60. The molar ratio of m-phenylenediamine and 1,2-Diformylhydrazine was 1: 2.
86% at 100℃; for 12h; In the sub equipped with a magnetic, reflux condenser, and thermometer wereadded 50mL round bottom flask was three-phenylenediamine (1 mmol), bis formyl hydrazine(2mmol), stirring was started at 100 deg.] C, for 12 hours. After completion of thereaction, the reaction solution cooled to room temperature, the precipitated heavyprecipitate, the precipitate was washed with water and recrystallized from ethanol,yield 86percent. Elemental analysis for C 10H 8N 6Theory: C, 56.60; H, 3.80; N, 39.60. Found:C, 56.56; H, 3.75; N, 39.56. M-phenylenediamine, the molar ratio of bis hydrazide is 1:2.
86% at 160℃; for 12h; In a 50 mL three-necked round bottom flask equipped with a magnetron reflux condenser and a thermometer M-phenylenediamine (1 mmol), Diformylhydrazine(2 mmol), and the mixture was stirred at 160 ° C for 12 hours. After completion of the reaction, the reaction solution was lowered to room temperature, and a large amount of precipitate was precipitated, and the precipitate was recrystallized from water and ethanol to yield 86percent. Elemental analysis for C10H8N6 Theory: C, 56.60; H, 3.80; N, 39.60. Found: C, 56.56; H, 3.75; N, 39.56. The molar ratio of m-phenylenediamine and dicarboxylic acid hydrazide was 1: 2.
86% at 100℃; for 12h; Preparation of ligands In the presence of magnetic,Reflux condenser and thermometer50 mL three-necked round bottom flaskM-phenylenediamine (1 mmol), dicarboxylic acid hydrazide (2 mmol),Start stirring at 100 ° C,The reaction was carried out for 12 hours.After completion of the reaction, the reaction solution was lowered to room temperature, and a large amount of precipitate was precipitated, and the precipitate was recrystallized from water and ethanol to yield 86percent.Elemental analysis for C10H8N6 Theory: C, 56.60; H, 3.80; N, 39.60. Found: C, 56.56; H, 3.75; N, 39.56. The molar ratio of m-phenylenediamine and dicarboxylic acid hydrazide was 1: 2.
86% at 100℃; for 12h; In a 50 mL three-necked round bottom flask equipped with a magnet, a reflux condenser and a thermometer, m-phenylenediamine (1Mmol), formic acid hydrazide (2 mmol), and the mixture was stirred at 100 ° C for 12 hours. After completion of the reaction, the reaction solution was lowered to the chamberTemperature, precipitation of a large number of precipitation, the precipitation of water and ethanol to recrystallize, the yield of 86percent. Elemental analysis C1QH8N6 Theory: C, 56.60;11,380; 139.60. The molar ratio of m-phenylenediamine and dicarboxylic acid hydrazide was 1: 2.
86% at 100℃; for 12h; A 50 mL three-necked round bottom flask equipped with a magnet, a reflux condenser and a thermometer was charged with m-phenylenediamine (1mmol), dicarboxylic acid hydrazine(2 mmol), and the mixture was stirred at 100 ° C for 12 hours. After the reaction,The reaction solution was allowed to stand at room temperature, and a large amount of precipitate was precipitated. The precipitate was recrystallized from water and ethanol to yield 86percent.
86% at 160℃; for 12h; In the provided with a magneton, reflux condenser and a thermometer of the 50 ml round bottom flask in three separately adding m-phenylene diamine (1 mmol), double-carbohydrazide (2 mmol), stir in 160 °C, reaction 12 hours. After the reaction, the reaction liquid to room temperature, precipitated a large amount of precipitation, the precipitated water and ethanol to recrystallize, yield 86percent.
86% at 100℃; for 12h; In a 50 mL round bottom flask equipped with a magnetic, reflux condenser and thermometer were added m-phenylenediamine (1 mmol of), bis formohydrazide (2 mmol), stirring was started at 100 deg.] C, for 12 hours. After completion of the reaction, the reaction solution was cooled to room temperature, precipitation of large amount of precipitate, the precipitate was washed with water and recrystallized from ethanol, yield 86percent.
86% at 100℃; for 12h; 4-(3-(4H-1,2,4-triazol-4-yl)phenyl)-4H-1,2,4-triazole (L)Preparation of Ligands In a 50 mL three-necked round-bottomed flask equipped with a magnet, a reflux condenser and a thermometer, m-phenylenediamine (1 mmol) and bisformylhydrazine (2 mmol) were respectively added and stirring was started at 100°C. Reaction 12 hour. After the reaction was completed, the reaction solution was cooled to room temperature, a large amount of precipitate was precipitated, and the precipitate was recrystallized from water and ethanol in a yield of 86percent.
86% at 160℃; for 12h; In a 50 mL three-necked round bottom flask equipped with a magnet, a reflux condenser, and a thermometer, m-phenylenediamine (1 mmol) and <strong>[628-36-4]diformylhydrazine</strong> (2 mmol) were respectively added, and the mixture was stirred at 160°C for 12 hours. After the reaction was completed, the reaction solution was cooled to room temperature, a large amount of precipitate was precipitated, and the precipitate was recrystallized from water and ethanol in a yield of 86percent. Elemental Analysis for C10H8N6 requires: C, 56.60; H, 3.80; N, 39.60. Found: C, 56.56; H, 3.75; N, 39.56. Mphenylenediamine, the mole of bisacyl hydrazide The ratio is 1:2
at 160℃; for 12h; 50 mL in a magnet, reflow condenser and thermometerThe three-necked round bottom flask was added with m-phenylenediamine(1 mmol), dicarboxylic acid hydrazide (2 mmol),Start stirring at 160 ° C and react for 12 hours.After completion of the reaction, the reaction solution was lowered to room temperature, and a large amount of precipitate was precipitated, and the precipitate was recrystallized from water and ethanol to yield 86percent. Elemental analysis C1QH8N6 Theory: C, 56.60; 11,3.80; 139.60. The molar ratio of m-phenylenediamine to bishydrazide was 1: 2

 

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