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[ CAS No. 15356-60-2 ]

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Chemical Structure| 15356-60-2
Chemical Structure| 15356-60-2
Structure of 15356-60-2 * Storage: {[proInfo.prStorage]}

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Product Details of [ 15356-60-2 ]

CAS No. :15356-60-2 MDL No. :MFCD00062983
Formula : C10H20O Boiling Point : 103-104°C at 9 mmHg
Linear Structure Formula :- InChI Key :N/A
M.W :156.27 g/mol Pubchem ID :165675
Synonyms :

1. D-Menthol

Safety of [ 15356-60-2 ]

Signal Word:Warning Class:N/A
Precautionary Statements:P273-P301+P312+P330-P302+P352-P305+P351+P338 UN#:N/A
Hazard Statements:H302-H315-H319-H335-H413 Packing Group:N/A
GHS Pictogram:

Application In Synthesis of [ 15356-60-2 ]

  • Upstream synthesis route of [ 15356-60-2 ]
  • Downstream synthetic route of [ 15356-60-2 ]

[ 15356-60-2 ] Synthesis Path-Upstream   1~1

  • 1
  • [ 108-30-5 ]
  • [ 15356-70-4 ]
  • [ 15356-60-2 ]
  • [ 2216-51-5 ]
  • [ 77341-67-4 ]
  • [ 204326-53-4 ]
YieldReaction ConditionsOperation in experiment
53 % ee With Candida cylindracea lipase In diethyl ether at 20℃; for 24 h; Schlenk technique; Resolution of racemate; Enzymatic reaction A dry Schlenk tube was charged with rac-alcohol (1 equivalent) and succinic anhydride (1 equiv.) dissolved in 2 mL of diethyl ether. The reaction was initiated by the addition of 100 mg of CCL. The reaction mixture was shaken at room temperature for 24 h. After removal of the lipase by filtration, the filtrate was shaken with 1 M Na2CO3 solution, and the remaining alcohol and the produced monoester succinate were separated by liquid–liquid extraction. The remaining enantiomer was obtained from the organic layer and the aqueous phase was washed with an organic solvent and treated by adding 1 M NaOH solution to obtain the other enantiomer. The enantiomeric excesses values were quantified by chiral GC analyses. Chiral GC: Chiralsil-DEX CB: (Tcolumn = 120 °C. flow: 1,2 mL/min); dl-(±)-menthyl acetate: td-(+) = 9.58 min; tl-(-) =10.85 min. dl-(±)-menthol: td-(+) = 13.25 min; tl-(-) = 13.69 min.
Reference: [1] Research on Chemical Intermediates, 2018, vol. 44, # 11, p. 6847 - 6860
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