[ CAS No. 16415-13-7 ] {[proInfo.proName]}

Name: 16415-13-7|Triethoxy(hexadecyl)silane|95%
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SKU: A190863
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Structure of 16415-13-7 * Storage: {[proInfo.prStorage]}

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Quality Control of [ 16415-13-7 ]

COA NMR CNMR HPLC LC-MS

Related Doc. of [ 16415-13-7 ]

SDS Specification

Alternatived Products of [ 16415-13-7 ]

Product Details of [ 16415-13-7 ]

CAS No. :	16415-13-7	MDL No. :	MFCD00054793
Formula :	C₂₂H₄₈O₃Si	Boiling Point :	-
Linear Structure Formula :	-	InChI Key :	OYGYKEULCAINCL-UHFFFAOYSA-N
M.W :	388.70	Pubchem ID :	85407
Synonyms :

Safety of [ 16415-13-7 ]

Signal Word:	Warning	Class:
Precautionary Statements:	P264-P280-P302+P352-P337+P313-P305+P351+P338-P362+P364-P332+P313	UN#:
Hazard Statements:	H315-H319	Packing Group:
GHS Pictogram:

Application In Synthesis of [ 16415-13-7 ]

* All experimental methods are cited from the reference, please refer to the original source for details. We do not guarantee the accuracy of the content in the reference.

Downstream synthetic route of [ 16415-13-7 ]

[ 16415-13-7 ] Synthesis Path-Downstream 1~11

1
[ 16415-13-7 ]
[ 408-21-9 ]

Yield	Reaction Conditions	Operation in experiment
	With hydrogen fluoride; water
	With HF In hydrogen fluoride aq. HF;

Reference： [1]Marans et al. [Journal of the American Chemical Society, 1951, vol. 73, p. 5127]
[2]Marans et al. [Journal of the American Chemical Society, 1951, vol. 73, p. 5127] [Gmelin Handbuch der Anorganischen Chemie, Gmelin Handbook: Si: MVol.C, 39, page 120 - 121]

2
[ 998-30-1 ]
[ 629-73-2 ]
[ 16415-13-7 ]

Yield	Reaction Conditions	Operation in experiment
	for 46h; Heating;
100 %Chromat.	With hydridochlorotris(triphenylphosphine)ruthenium(II); tris(dibutylamino)(dioctylamino)phosphonium hexafluorophosphate at 95℃; for 2h;
76 %Spectr.	With [Rh(OH)cod]₂ and diethylaminopropyltrimethoxysilane immobilized on SiO₂ In neat (no solvent) at 40℃; for 0.5h;

Reference： [1]Hosomi, Akira; Iijima, Susumu; Sakurai, Hideki [Chemistry Letters, 1981, p. 243 - 246]
[2]Location in patent: experimental part Wang, Diliang; Li, Jiayun; Peng, Jiajian; Bai, Ying; Lai, Guoqiao [Phosphorus, Sulfur and Silicon and the Related Elements, 2011, vol. 186, # 11, p. 2258 - 2266]
[3]Motokura, Ken; Maeda, Kyogo; Chun, Wang-Jae [ACS Catalysis, 2017, vol. 7, # 7, p. 4637 - 4641]

3
[ 16415-13-7 ]
[ 36653-82-4 ]

Yield	Reaction Conditions	Operation in experiment
	With disodium hydrogenphosphate; water; 3-chloro-benzenecarboperoxoic acid 1.) methanol, RT, 24 h; Yield given. Multistep reaction;

Reference： [1]Hosomi, Akira; Iijima, Susumu; Sakurai, Hideki [Chemistry Letters, 1981, p. 243 - 246]

Yield	Reaction Conditions	Operation in experiment
	Trichlorhexadecylsilan, Ethanol;
	Trichlor-hexadecyl-silan, EtOH;
		With particular preference, the alkoxysilanes set out below are prepared by the process of the invention: ... octyltriethoxysilane, cyclohexyltrimethoxysilane, cyclohexylmethyldimethoxysilane, hexadecyltrimethoxysilane, hexadecyltriethoxysilane.

5
[ 16415-13-7 ]
[ 171194-90-4 ]

Yield	Reaction Conditions	Operation in experiment
	With water
	With hydrogenchloride In ethanol for 7h;

Reference： [1]Shimojima, Atsushi; Kuroda, Kazuyuki [Angewandte Chemie - International Edition, 2003, vol. 42, # 34, p. 4057 - 4060]
[2]Shimojima, Atsushi; Liu, Zheng; Ohsuna, Tetsu; Terasaki, Osamu; Kuroda, Kazuyuki [Journal of the American Chemical Society, 2005, vol. 127, # 40, p. 14108 - 14116]

6
[ 64-17-5 ]
[ 5894-60-0 ]
[ 16415-13-7 ]

Reference： [1]Shimojima, Atsushi; Liu, Zheng; Ohsuna, Tetsu; Terasaki, Osamu; Kuroda, Kazuyuki [Journal of the American Chemical Society, 2005, vol. 127, # 40, p. 14108 - 14116]

7
[ 16415-13-7 ]
C₁₆H₃₃Cl₇O₂Si₃ [ No CAS ]

Yield	Reaction Conditions	Operation in experiment
	Multi-step reaction with 2 steps 1: H₂O 2: tetrachlorosilane / tetrahydrofuran; hexane / 20 °C

Reference： [1]Shimojima, Atsushi; Kuroda, Kazuyuki [Angewandte Chemie - International Edition, 2003, vol. 42, # 34, p. 4057 - 4060]

8
[ 16415-13-7 ]
C₁₆H₃₃Cl₉O₃Si₄ [ No CAS ]

Yield	Reaction Conditions	Operation in experiment
	Multi-step reaction with 2 steps 1: H₂O 2: tetrachlorosilane / tetrahydrofuran; hexane / 20 °C

Reference： [1]Shimojima, Atsushi; Kuroda, Kazuyuki [Angewandte Chemie - International Edition, 2003, vol. 42, # 34, p. 4057 - 4060]

9
POM-7 [ No CAS ]
[ 66-40-0 ]
[ 16415-13-7 ]
[tetraethylammonium]3[PW₁₁O₃₉(Si(CH₂)15CH₃)2] [ No CAS ]

Yield	Reaction Conditions	Operation in experiment
	With HCl In not given treatment of tungstate deriv. with silicate deriv. in presence of tetraethylammonium ions; elem. anal.;

Reference： [1]Landsmann, Steve; Lizandara-Pueyo, Carlos; Polarz, Sebastian [Journal of the American Chemical Society, 2010, vol. 132, # 14, p. 5315 - 5321]

10
POM-7 [ No CAS ]
[ 10549-76-5 ]
[ 16415-13-7 ]
[Bu₄N]3[PW₁₁O₃₉(Si(CH₂)15CH₃)2] [ No CAS ]

Yield	Reaction Conditions	Operation in experiment
	With HCl In not given treatment of tungstate deriv. with silicate deriv. in presence of tetrabutylammonium ions; elem. anal.;

Reference： [1]Landsmann, Steve; Lizandara-Pueyo, Carlos; Polarz, Sebastian [Journal of the American Chemical Society, 2010, vol. 132, # 14, p. 5315 - 5321]

11
[ 60-12-8 ]
[ 16415-13-7 ]
[ 1185275-68-6 ]
hexadecylsilicic acid bis(2-phenylethyl) ethyl ester [ No CAS ]
C₆₄H₁₀₂O₅Si₂ [ No CAS ]

Yield	Reaction Conditions	Operation in experiment
	With sodium methylate In methanol at 113 - 120℃; for 5h; Inert atmosphere;	3 Preparation Example 3 Preparation of a functional substance-releasing agent containing hexadecylsilicic acid tris (2-phenylethyl)ester[tris (2-phenylethyloxy)hexadecylsilane] In a 200 mL four-neck flask, under nitrogen flow, 50.56 g of hexadecyltriethoxysilane (0.13 mol), 44.43 g of 2-phenylethanol (0.36 mol), and 0.375 mL of 2.8% sodium methoxide in methanol were stirred for two hours at 113 to 120° C. with distilling off ethanol. After two hours, an inner pressure of the flask was gradually reduced to 8 kPa, and the mixture was stirred for additional three hours at 120° C. with distilling off ethanol. After three hours, the mixture was cooled and the reduced pressure was released. Then, the mixture was filtered to give 77.52 g of yellow oil containing hexadecylsilicic acid tris(2-phenylethyl)ester. The resultant oil was analyzed by GC. The result is shown in Table 3. From the result, contents of hexadecylsilicic acid tris(2-phenylethyl)ester of the compound (1) and hexadecylsilicic acid bis(2-phenylethyl)ethyl ester of the compound (2) were 69.9% and 19.9%, respectively.

Reference： [1]Current Patent Assignee: KAO CORPORATION - US8420845, 2013, B2 Location in patent: Page/Page column 8

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P265	Wash skin thouroughly after handling.
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P285	In case of inadequate ventilation wear respiratory protection.
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Response
Code	Phrase
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P304	IF INHALED:
P305	IF IN EYES:
P306	IF ON CLOTHING:
P307	IF exposed:
P308	IF exposed or concerned:
P309	IF exposed or if you feel unwell:
P310	Immediately call a POISON CENTER or doctor/physician.
P311	Call a POISON CENTER or doctor/physician.
P312	Call a POISON CENTER or doctor/physician if you feel unwell.
P313	Get medical advice/attention.
P314	Get medical advice/attention if you feel unwell.
P315	Get immediate medical advice/attention.
P320
P302 + P352	IF ON SKIN: wash with plenty of soap and water.
P321
P322
P330	Rinse mouth.
P331	Do NOT induce vomiting.
P332	IF SKIN irritation occurs:
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P337	If eye irritation persists:
P338	Remove contact lenses, if present and easy to do. Continue rinsing.
P340	Remove victim to fresh air and keep at rest in a position comfortable for breathing.
P341	If breathing is difficult, remove victim to fresh air and keep at rest in a position comfortable for breathing.
P342	If experiencing respiratory symptoms:
P350	Gently wash with plenty of soap and water.
P351	Rinse cautiously with water for several minutes.
P352	Wash with plenty of soap and water.
P353	Rinse skin with water/shower.
P360	Rinse immediately contaminated clothing and skin with plenty of water before removing clothes.
P361	Remove/Take off immediately all contaminated clothing.
P362	Take off contaminated clothing and wash before reuse.
P363	Wash contaminated clothing before reuse.
P370	In case of fire:
P371	In case of major fire and large quantities:
P372	Explosion risk in case of fire.
P373	DO NOT fight fire when fire reaches explosives.
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P376	Stop leak if safe to do so. Oxidising gases (section 2.4) 1
P377	Leaking gas fire: Do not extinguish, unless leak can be stopped safely.
P378
P380	Evacuate area.
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P390	Absorb spillage to prevent material damage.
P391	Collect spillage. Hazardous to the aquatic environment
P301 + P310	IF SWALLOWED: Immediately call a POISON CENTER or doctor/physician.
P301 + P312	IF SWALLOWED: call a POISON CENTER or doctor/physician IF you feel unwell.
P301 + P330 + P331	IF SWALLOWED: Rinse mouth. Do NOT induce vomiting.
P302 + P334	IF ON SKIN: Immerse in cool water/wrap in wet bandages.
P302 + P350	IF ON SKIN: Gently wash with plenty of soap and water.
P303 + P361 + P353	IF ON SKIN (or hair): Remove/Take off Immediately all contaminated clothing. Rinse SKIN with water/shower.
P304 + P312	IF INHALED: Call a POISON CENTER or doctor/physician if you feel unwell.
P304 + P340	IF INHALED: Remove victim to fresh air and Keep at rest in a position comfortable for breathing.
P304 + P341	IF INHALED: If breathing is difficult, remove victim to fresh air and keep at rest in a position comfortable for breathing.
P305 + P351 + P338	IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.
P306 + P360	IF ON CLOTHING: Rinse Immediately contaminated CLOTHING and SKIN with plenty of water before removing clothes.
P307 + P311	IF exposed: call a POISON CENTER or doctor/physician.
P308 + P313	IF exposed or concerned: Get medical advice/attention.
P309 + P311	IF exposed or if you feel unwell: call a POISON CENTER or doctor/physician.
P332 + P313	IF SKIN irritation occurs: Get medical advice/attention.
P333 + P313	IF SKIN irritation or rash occurs: Get medical advice/attention.
P335 + P334	Brush off loose particles from skin. Immerse in cool water/wrap in wet bandages.
P337 + P313	IF eye irritation persists: Get medical advice/attention.
P342 + P311	IF experiencing respiratory symptoms: call a POISON CENTER or doctor/physician.
P370 + P376	In case of fire: Stop leak if safe to Do so.
P370 + P378	In case of fire:
P370 + P380	In case of fire: Evacuate area.
P370 + P380 + P375	In case of fire: Evacuate area. Fight fire remotely due to the risk of explosion.
P371 + P380 + P375	In case of major fire and large quantities: Evacuate area. Fight fire remotely due to the risk of explosion.
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P401
P402	Store in a dry place.
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H200	Unstable explosive
H201	Explosive; mass explosion hazard
H202	Explosive; severe projection hazard
H203	Explosive; fire, blast or projection hazard
H204	Fire or projection hazard
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H221	Flammable gas
H222	Extremely flammable aerosol
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H229	Pressurized container: may burst if heated
H230	May react explosively even in the absence of air
H231	May react explosively even in the absence of air at elevated pressure and/or temperature
H240	Heating may cause an explosion
H241	Heating may cause a fire or explosion
H242	Heating may cause a fire
H250	Catches fire spontaneously if exposed to air
H251	Self-heating; may catch fire
H252	Self-heating in large quantities; may catch fire
H260	In contact with water releases flammable gases which may ignite spontaneously
H261	In contact with water releases flammable gas
H270	May cause or intensify fire; oxidizer
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H272	May intensify fire; oxidizer
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H281	Contains refrigerated gas; may cause cryogenic burns or injury
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Health hazards
Code	Phrase
H300	Fatal if swallowed
H301	Toxic if swallowed
H302	Harmful if swallowed
H303	May be harmful if swallowed
H304	May be fatal if swallowed and enters airways
H305	May be harmful if swallowed and enters airways
H310	Fatal in contact with skin
H311	Toxic in contact with skin
H312	Harmful in contact with skin
H313	May be harmful in contact with skin
H314	Causes severe skin burns and eye damage
H315	Causes skin irritation
H316	Causes mild skin irritation
H317	May cause an allergic skin reaction
H318	Causes serious eye damage
H319	Causes serious eye irritation
H320	Causes eye irritation
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H331	Toxic if inhaled
H332	Harmful if inhaled
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H371	May cause damage to organs
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Code	Phrase
H400	Very toxic to aquatic life
H401	Toxic to aquatic life
H402	Harmful to aquatic life
H410	Very toxic to aquatic life with long-lasting effects
H411	Toxic to aquatic life with long-lasting effects
H412	Harmful to aquatic life with long-lasting effects
H413	May cause long-lasting harmful effects to aquatic life
H420	Harms public health and the environment by destroying ozone in the upper atmosphere

[ CAS No. 16415-13-7 ] {[proInfo.proName]}

Quality Control of [ 16415-13-7 ]

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Product Details of [ 16415-13-7 ]

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Application In Synthesis of [ 16415-13-7 ]

[ 16415-13-7 ] Synthesis Path-Downstream 1~11

Precautionary Statements-General

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