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[ CAS No. 18084-64-5 ] {[proInfo.proName]}

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Chemical Structure| 18084-64-5
Chemical Structure| 18084-64-5
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Product Details of [ 18084-64-5 ]

CAS No. :18084-64-5 MDL No. :MFCD05864401
Formula : C36H44N4 Boiling Point : -
Linear Structure Formula :- InChI Key :-
M.W : 532.76 Pubchem ID :-
Synonyms :

Safety of [ 18084-64-5 ]

Signal Word:Warning Class:N/A
Precautionary Statements:P264-P280-P302+P352+P332+P313+P362+P364-P305+P351+P338+P337+P313 UN#:N/A
Hazard Statements:H315-H319 Packing Group:N/A
GHS Pictogram:

Application In Synthesis of [ 18084-64-5 ]

* All experimental methods are cited from the reference, please refer to the original source for details. We do not guarantee the accuracy of the content in the reference.

  • Downstream synthetic route of [ 18084-64-5 ]

[ 18084-64-5 ] Synthesis Path-Downstream   1~24

  • 2
  • [ 1074-42-6 ]
  • [ 18084-64-5 ]
  • [ 1034-11-3 ]
  • [ 267231-82-3 ]
YieldReaction ConditionsOperation in experiment
With iodine In chloroform-d1
  • 3
  • [ 1074-42-6 ]
  • [ 18084-64-5 ]
  • [ 1034-11-3 ]
  • [ CAS Unavailable ]
YieldReaction ConditionsOperation in experiment
With K5<CoW12O40>; water; potassium acetate In acetonitrile
YieldReaction ConditionsOperation in experiment
Triisobutylamin,/BRN= 107828/;
N-Benzylaziridin, p-Toluolsulfonsaeure;
(yield)96 percent;
  • 5
  • [ 18084-64-5 ]
  • [ CAS Unavailable ]
  • [ 498534-63-7 ]
YieldReaction ConditionsOperation in experiment
92% In ethanol Cu(NO3)2*6H2O was dissolved in EtOH at 60°C with stirring, ligandwas added, stirred overnight; filtered, washed with EtOH-Et2O, dried over CaCl2; elem. anal.;
  • 6
  • [ 18084-64-5 ]
  • [ CAS Unavailable ]
  • [ 60326-14-9 ]
YieldReaction ConditionsOperation in experiment
61% In ethanol Co(NO3)2*6H2O was added to suspn. of ligand in EtOH at 50°C, stirred overnight; filtered, washed with CH2Cl2 and EtOH, dried over P2O5 in vacuo; elem. anal.;
  • 8
  • [ 100-44-7 ]
  • [ 294-90-6 ]
  • [ 18084-64-5 ]
YieldReaction ConditionsOperation in experiment
75% With potassium carbonate In acetonitrile for 10.5h; Heating;
  • 9
  • [ 100-52-7 ]
  • [ 294-90-6 ]
  • [ 18084-64-5 ]
YieldReaction ConditionsOperation in experiment
75% With sodium tris(acetoxy)borohydride In 1,2-dichloro-ethane at 20℃; for 72h; Inert atmosphere;
  • 10
  • [ 18084-64-5 ]
  • [ CAS Unavailable ]
  • [ 1396237-79-8 ]
YieldReaction ConditionsOperation in experiment
In acetonitrile
  • 11
  • [ 100-39-0 ]
  • [ 294-90-6 ]
  • [ 18084-64-5 ]
YieldReaction ConditionsOperation in experiment
89% With sodium hydroxide In water; acetonitrile for 6h; General synthetic procedure A: N-tetraalkylation of macrocycles General procedure: Macrocycle (1.0 equiv) and alkyl halide (4.1 equiv) were dissolved in a 1:1 mixture of aqueous 1 MNaOH and CH3CN (5-20 mL). The reaction mixture was shaken for 6 h. The resulting precipitate was collected by filtration, washed with hexane, and dried in vacuo to give the desired N-tetraalkyl derivative.
  • 12
  • [ 1583306-65-3 ]
  • [ 18084-64-5 ]
YieldReaction ConditionsOperation in experiment
75% With borane-THF In tetrahydrofuran at 90℃; for 24h;
  • 13
  • [ 18084-64-5 ]
  • [ 79060-88-1 ]
  • [ 2377168-66-4 ]
YieldReaction ConditionsOperation in experiment
In chloroform-d1 Sonication;
  • 14
  • [ 1583306-61-9 ]
  • [ 18084-64-5 ]
YieldReaction ConditionsOperation in experiment
Multi-step reaction with 2 steps 1: N-ethyl-N,N-diisopropylamine; HATU / N,N-dimethyl-formamide / 21 h / 20 °C 2: borane-THF / tetrahydrofuran / 24 h / 90 °C
  • 15
  • [ CAS Unavailable ]
  • [ 18084-64-5 ]
YieldReaction ConditionsOperation in experiment
Multi-step reaction with 3 steps 1.1: N-ethyl-N,N-diisopropylamine / dichloromethane / 1 h / 20 °C 1.2: 40 h / 20 °C 2.1: N-ethyl-N,N-diisopropylamine; HATU / N,N-dimethyl-formamide / 21 h / 20 °C 3.1: borane-THF / tetrahydrofuran / 24 h / 90 °C
  • 16
  • [ 18084-64-5 ]
  • [ CAS Unavailable ]
  • [ 2412834-36-5 ]
YieldReaction ConditionsOperation in experiment
In diethyl ether; acetonitrile Sonication; 2.2. Synthesis of [Pb(TB-cyclen)](ClO4)2 (1) 1 equivalent of TB-cyclen (0.05 mmol, 26.64 mg) was dissolved in10 mL of acetonitrile in a sample vial. Then 1 equivalent of Pb(ClO4)2·3H2O (0.05 mmol, 24.08 mg) was added directly to the TBCsolution. The solution was sonicated until all solids had dissolved, andthe sample vial was placed upright in a larger vial containing about5 mL of diethyl ether which was then closed. Diffusion of ether into theacetonitrile solution led to deposition of colorless crystals after 3 weeks,which were isolated and air dried. Elemental anal. calc. forC36H44PbCl2N4O8, C, 46.05; H, 4.72; N, 5.97%. Found C, 46.10; H,4.42, N, 5.96%.
  • 17
  • [ 18084-64-5 ]
  • [ CAS Unavailable ]
  • [ 75-05-8 ]
  • [ 2412834-38-7 ]
YieldReaction ConditionsOperation in experiment
In diethyl ether Sonication; 2.3. Synthesis of [Cd(TB-cyclen)CH3CN](ClO4)2 (2) 1 equivalent of TB-cyclen (0.06 mmol, 31.97 mg) was dissolved in10 mL of acetonitrile in a sample vial. Then 1 equivalent of Cd(ClO4)2·6H2O (0.06 mmol, 25.2 mg) was added directly to the TBCsolution. Use of the ether-diffusion method described for 1 above led todeposition of colorless crystals after 3 weeks, which were isolated andair dried. Elemental anal. calc. for C38H47CdCl2N5O8, 51.56; H, 5.35; N, 7.91%. Found C, 51.40; H, 5.02, N, 7.94%.
  • 18
  • [ 18084-64-5 ]
  • [ CAS Unavailable ]
  • [ 75-05-8 ]
  • [ 2412834-40-1 ]
YieldReaction ConditionsOperation in experiment
In diethyl ether Sonication; 2.4. Synthesis of [Hg(TB-cyclen)CH3CN](ClO4)2 (3) 1 equivalent of TBC (0.06 mmol, 31.88 mg) was dissolved in 10 mLof acetonitrile in a sample vial. Then 1 equivalent of Hg(ClO4)2·3H2O(0.06 mmol, 30.46 mg) was added directly to the TBC solution. Use ofthe ether-diffusion method described for 1 above led to deposition ofcolorless crystals after 3 weeks, which were isolated and air dried.Elemental anal. calc. for C38H47HgCl2N2O8, C, 46.89; H, 4.87; N, 7.20.Found C, 46.50; H, 4.92; N, 7.02.
  • 19
  • [ 18084-64-5 ]
  • [ 2412834-41-2 ]
YieldReaction ConditionsOperation in experiment
With zinc perchlorate In chloroform; water 2.5. Synthesis of [(TB-cyclen)H]ClO4 (4) These were obtained as the product of an attempted synthesis of theZnII complex of TB-cyclen by means of layering a solution of Zn(ClO4)2·6H2O (0.06 mmol, 22.35 mg) in 3 mL of water on a solution ofTB-cyclen (0.06 mmol, 31.97 g) in 3 mL of CHCl3. The colorless crystalsof 4 were deposited, presumably before the ZnII complex could form,which would be slowed down by the need for phase transfer for complexformation to occur. After collection and analysis these crystalswere considered to be of crystallographic interest. Calcd. forC36H45ClN4O4, C, 56.87; H, 5.97; N, 7.37. Found C, 56.83; H, 5.91; N,7.30.
  • 20
  • [ 18084-64-5 ]
  • [ 615-94-1 ]
  • [ CAS Unavailable ]
  • [ 2419921-51-8 ]
YieldReaction ConditionsOperation in experiment
57.3% Stage #1: N,N’,N’’,N’’’-tetrabenzyl-1,4,7,10-tetraazacyclododecane; cobalt(II) perchlorate hexahydrate In dichloromethane; acetonitrile for 12h; Inert atmosphere; Schlenk technique; Reflux; Stage #2: 2,5-dihydroxy-1,4-benzoquinone With triethylamine In dichloromethane; acetonitrile for 2h; Inert atmosphere; Schlenk technique; Reflux;
  • 21
  • [ 18084-64-5 ]
  • [ 87-88-7 ]
  • [ CAS Unavailable ]
  • [ CAS Unavailable ]
YieldReaction ConditionsOperation in experiment
47.9% Stage #1: N,N’,N’’,N’’’-tetrabenzyl-1,4,7,10-tetraazacyclododecane; cobalt(II) perchlorate hexahydrate In dichloromethane; acetonitrile for 12h; Inert atmosphere; Schlenk technique; Reflux; Stage #2: 3,6-dichloro-2,5-dihydroxy-1,4-benzoquinone With triethylamine In dichloromethane; acetonitrile for 2h; Inert atmosphere; Schlenk technique; Reflux;
  • 22
  • [ 18084-64-5 ]
  • [ CAS Unavailable ]
  • [ CAS Unavailable ]
  • [ 2419921-57-4 ]
YieldReaction ConditionsOperation in experiment
62% Stage #1: N,N’,N’’,N’’’-tetrabenzyl-1,4,7,10-tetraazacyclododecane; cobalt(II) perchlorate hexahydrate In dichloromethane; acetonitrile for 12h; Inert atmosphere; Schlenk technique; Reflux; Stage #2: 3,6-dihydroxy-2,5-dimethoxy-p-benzoquinone dilithium salt In dichloromethane; acetonitrile for 2h; Inert atmosphere; Schlenk technique; Reflux;
  • 23
  • [ 18084-64-5 ]
  • [ 4370-59-6 ]
  • [ CAS Unavailable ]
  • [ 2419921-55-2 ]
YieldReaction ConditionsOperation in experiment
64.9% Stage #1: N,N’,N’’,N’’’-tetrabenzyl-1,4,7,10-tetraazacyclododecane; cobalt(II) perchlorate hexahydrate In dichloromethane; acetonitrile for 12h; Inert atmosphere; Schlenk technique; Reflux; Stage #2: bromanilic acid With triethylamine In dichloromethane; acetonitrile for 2h; Inert atmosphere; Schlenk technique; Reflux;
  • 24
  • [ 18084-64-5 ]
  • [ CAS Unavailable ]
  • [ 2715024-54-5 ]
YieldReaction ConditionsOperation in experiment
80% In acetonitrile at 20℃; for 12h; Glovebox; Inert atmosphere;
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