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Chemical Structure| 18772-58-2 Chemical Structure| 18772-58-2

Structure of 18772-58-2

Chemical Structure| 18772-58-2

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Product Details of [ 18772-58-2 ]

CAS No. :18772-58-2
Formula : C21H30Si3
M.W : 366.72
SMILES Code : C[Si](C)(C)C#CC1=CC(C#C[Si](C)(C)C)=CC(C#C[Si](C)(C)C)=C1
MDL No. :N/A
InChI Key :VVTLQYQLVFNQBM-UHFFFAOYSA-N
Pubchem ID :10761444

Safety of [ 18772-58-2 ]

GHS Pictogram:
Signal Word:Warning
Hazard Statements:H315-H319
Precautionary Statements:P264-P280-P302+P352-P337+P313-P305+P351+P338-P362+P364-P332+P313

Application In Synthesis of [ 18772-58-2 ]

* All experimental methods are cited from the reference, please refer to the original source for details. We do not guarantee the accuracy of the content in the reference.

  • Downstream synthetic route of [ 18772-58-2 ]

[ 18772-58-2 ] Synthesis Path-Downstream   1~1

  • 1
  • [ 626-44-8 ]
  • [ 1066-54-2 ]
  • [ 18772-58-2 ]
YieldReaction ConditionsOperation in experiment
90% <strong>[626-44-8]1,3,5-triiodobenzene</strong> (33.0 g, 0.10 mol), Pd(dppf)Cl2.CH2Cl2 (700 mg, 0.86 mmol) under nitrogen atmosphereCuI (330 mg, 1.73 mmol) and isopropylamine (60 ml) were added to tetrahydrofuran (400 ml), and stirred at room temperature for 10 min.Trimethylsilylacetylene (32.3 g, 0.33 mol) was slowly added by syringe, and the mixture was warmed to 80 ° C and stirred for 12 hours.TLC showed the end of the reaction, and a silica gel column (PE/EA = 4/1 to 2/1) gave Compound 11 (33.0 g, yield 90percent).
 

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