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Chemical Structure| 655-86-7 Chemical Structure| 655-86-7
Chemical Structure| 655-86-7

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Synonyms: 2,3-Phenazinediamine

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Product Details of 2,3-Diaminophenazine

CAS No. :655-86-7
Formula : C12H10N4
M.W : 210.23
SMILES Code : NC1=CC2=NC3=CC=CC=C3N=C2C=C1N
Synonyms :
2,3-Phenazinediamine
MDL No. :MFCD00160693
InChI Key :VZPGINJWPPHRLS-UHFFFAOYSA-N
Pubchem ID :410099

Safety of 2,3-Diaminophenazine

GHS Pictogram:
Signal Word:Warning
Hazard Statements:H302-H315-H319-H335
Precautionary Statements:P261-P305+P351+P338

Application In Synthesis of 2,3-Diaminophenazine

* All experimental methods are cited from the reference, please refer to the original source for details. We do not guarantee the accuracy of the content in the reference.

  • Downstream synthetic route of [ 655-86-7 ]

[ 655-86-7 ] Synthesis Path-Downstream   1~1

  • 1
  • [ 652-12-0 ]
  • [ 655-86-7 ]
  • [ 1431328-08-3 ]
YieldReaction ConditionsOperation in experiment
19% With zinc diacetate; at 220℃; for 12h;Inert atmosphere; 2,3-Phenazinediamine(1.06g, 5.05 mmol) , zinc acetate(1.85g, 10.08mmol) and 3,4,5,6-Tetrafluorophthalic anhydride (1.21g 5.49 mmol) were well mixed by a mortar, then heated at 220 ℃ in a glass tube protected under argon atmosphere for 12 hours. After that the mixture was cooled down and washed by tetrahydrofuran (THF). The eluted solution was condensed and purified through column chromatography with ethyl acetate and hexane (1:1) to afford compound 1 as orange colour powder, (341mg, yield 19%. 1H NMR (300 MHz, DMSO-d6, 298 K): δ= 7.882 (m, 2H), 8.205 (m, 3H), 8.450 (s, 2H), 13.224 (s, 1H). FTIR (KBr), 3469, 3059, 3038, 2337, 1542, 1525, 1510, 1489, 1474, 1419, 1369, 1350, 1308, 1273, 1219, 1206, 1184, 1171, 1136, 1085, 1036, 964, 899, 890, 833, 762cm-1. MALDI-TOF MS: Calc. for C19H8F4N4: [M] 368.0685, Found: [M] 368.5. HR-MS calcd for C19H8F4N4 [M+1], 369.1685; found, 369.0754.
 

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