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Chemical Structure| 2052-14-4 Chemical Structure| 2052-14-4

Structure of 2052-14-4

Chemical Structure| 2052-14-4

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Product Details of [ 2052-14-4 ]

CAS No. :2052-14-4
Formula : C11H14O3
M.W : 194.23
SMILES Code : O=C(OCCCC)C1=CC=CC=C1O
MDL No. :MFCD00020038
Boiling Point : No data available
InChI Key :YFDUWSBGVPBWKF-UHFFFAOYSA-N
Pubchem ID :16330

Safety of [ 2052-14-4 ]

GHS Pictogram:
Signal Word:Warning
Hazard Statements:H302-H315-H319
Precautionary Statements:P501-P270-P264-P280-P337+P313-P301+P312+P330

Application In Synthesis of [ 2052-14-4 ]

* All experimental methods are cited from the reference, please refer to the original source for details. We do not guarantee the accuracy of the content in the reference.

  • Downstream synthetic route of [ 2052-14-4 ]

[ 2052-14-4 ] Synthesis Path-Downstream   1~1

  • 1
  • [ 56-23-5 ]
  • [ 71-36-3 ]
  • [ 108-95-2 ]
  • [ 94-26-8 ]
  • [ 2052-14-4 ]
YieldReaction ConditionsOperation in experiment
62%; 38% With diiron nonacarbonyl; at 130℃; for 6h;Inert atmosphere; Sealed tube; General procedure: The reactions were carried out in 10-mL glass ampules which were placed in a 17-mL stainless-steel high pressure micro reactor with controlled heating. An ampule was charged under argon with 1-10 mmol of the catalyst [FeCl3, FeBr3, FeCl2, FeBr2, FeCl3·6H2O, FeCl3·4H2O, Fe(acac), or Fe2(CO)9], 100 mmol of phenol, anisole, phenetole, or o-, m-, or p-cresol, 100-1000 mmol of CCl4, and 100-1000 mmol of methanol, ethanol, propan-1-ol, or butan-1-ol. The ampule was sealed and placed into the reactor which was hermetically closed and heated for 4-8 h at 130C with continuous stirring. The reactor was cooled to 20C, the ampule was opened, and the mixture was neutralized with Na2CO3, treated with boiling petroleum ether for 10-15 min, and filtered through a filter paper. The solvent was distilled off, and the residue was distilled under reduced pressure or subjected to chromatography in a column (h = 21, d = 1.2 cm) charged with silica gel using petroleum ether as eluent. Analytical samples were obtained by recrystallization from ethanol.
 

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