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Chemical Structure| 218909-60-5 Chemical Structure| 218909-60-5

Structure of 218909-60-5

Chemical Structure| 218909-60-5

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Product Details of [ 218909-60-5 ]

CAS No. :218909-60-5
Formula : C18H13I2N
M.W : 497.11
SMILES Code : IC1=CC=C(N(C2=CC=CC=C2)C3=CC=C(I)C=C3)C=C1

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Application In Synthesis of [ 218909-60-5 ]

* All experimental methods are cited from the reference, please refer to the original source for details. We do not guarantee the accuracy of the content in the reference.

  • Downstream synthetic route of [ 218909-60-5 ]

[ 218909-60-5 ] Synthesis Path-Downstream   1~1

  • 1
  • [ 603-34-9 ]
  • [ 218909-60-5 ]
  • [ 4181-20-8 ]
YieldReaction ConditionsOperation in experiment
In a 250 mL two-neck round bottom flask equipped with magnetic stirrer, condenser and nitrogen inlet-outlet were introduced triphenylamine (8 g, 3.2 mmol), KI (7.19 g, 4.3 mmol), and glacial acetic acid (120 mL). The mixture was stirred in nitrogen atmosphere at 85 °C for 5 h and KIO3 (4.60 g, 2.15 mmol) was introduced over 5 h. The mixture was precipitated in water and a dirty white compound was obtained and purified by column chromatography using ethyl acetate/hexane (1:5) as eluent. Yield: 66percent,Mp 69-70 C. 1H NMR (CDCl3, ppm): 7.50 (4H, d, J 8.8 Hz), 7.24(2H, d, J 8.0 Hz), 7.06-7.04 (3H, d t), 6.82-6.80 (4H, d,J 8.8 Hz).
 

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