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Chemical Structure| 2307-10-0 Chemical Structure| 2307-10-0

Structure of 2307-10-0

Chemical Structure| 2307-10-0

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Product Details of [ 2307-10-0 ]

CAS No. :2307-10-0
Formula : C5H10OS
M.W : 118.20
SMILES Code : CC(SCCC)=O
English Name :S-Propyl ethanethioate
MDL No. :MFCD00039937
InChI Key :SBWFWBJCYMBZEY-UHFFFAOYSA-N
Pubchem ID :61295

Safety of [ 2307-10-0 ]

Application In Synthesis of [ 2307-10-0 ]

* All experimental methods are cited from the reference, please refer to the original source for details. We do not guarantee the accuracy of the content in the reference.

  • Downstream synthetic route of [ 2307-10-0 ]

[ 2307-10-0 ] Synthesis Path-Downstream   1~3

  • 1
  • [ 599-91-7 ]
  • [ 10387-40-3 ]
  • [ 2307-10-0 ]
  • 2
  • [ 506-96-7 ]
  • [ CAS Unavailable ]
  • [ 2307-10-0 ]
  • [ 928-47-2 ]
  • [ 2432-32-8 ]
YieldReaction ConditionsOperation in experiment
27% With aluminum tri-bromide In various solvent(s) at 20℃; for 2h; Yield given;
  • 3
  • [ 2307-10-0 ]
  • [ CAS Unavailable ]
  • [ 452-68-6 ]
  • [ 2747099-25-6 ]
YieldReaction ConditionsOperation in experiment
50% With [2,2]bipyridinyl; nickel dibromide; zinc In water; N,N-dimethyl-formamide at 110℃; for 15h; Schlenk technique; General procedures for the one-pot synthesis of thioesters 3 General procedure: A Schlenk flask equipped with a magnetic stir bar was charged with S-alkyl thioacetate 2 (1.5 mmol), aryl iodides1 (1.0 mmol), NiBr2 (21.8 mg, 0.1 mmol), bipyridine (31.2 mg, 0.2 mmol), and Zn powder (130 mg, 2.0 mmol). Next, the reaction flask was degassed and backfilled with CO three times, and then DMF/H2O (2:0.2 mL) were injected sequentially. The mixture was stirred at 110 °C for 15 h. When the reaction was complete, brine (30 mL)was added and the aqueous layer was extracted with EtOAc (2 × 20 mL). The combined organic layer was dried and evaporated and the residue was purified by flash chromatography on silica gel (eluent:petroleum ether/EtOAc = 100:1 to 50:1, v/v) to furnish the desired product 3.
 

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