Home Cart Sign in  
Chemical Structure| 2386-58-5 Chemical Structure| 2386-58-5

Structure of 2386-58-5

Chemical Structure| 2386-58-5

*Storage: {[sel_prStorage]}

*Shipping: {[sel_prShipping]}

,{[proInfo.pro_purity]}

4.5 *For Research Use Only !

{[proInfo.pro_purity]}
Cat. No.: {[proInfo.prAm]} Purity: {[proInfo.pro_purity]}

Change View

Size Price VIP Price

US Stock

Global Stock

In Stock
{[ item.pr_size ]} Inquiry {[ getRatePrice(item.pr_usd,item.pr_rate,item.mem_rate,item.pr_is_large_size_no_price, item.vip_usd) ]}

US Stock: ship in 0-1 business day
Global Stock: ship in 5-7 days

  • {[ item.pr_size ]}

In Stock

- +

Please Login or Create an Account to: See VIP prices and availability

US Stock: ship in 0-1 business day
Global Stock: ship in 2 weeks

  • 1-2 Day Shipping
  • High Quality
  • Technical Support
Product Citations

Alternative Products

Product Details of [ 2386-58-5 ]

CAS No. :2386-58-5
Formula : C2H5NO2S
M.W : 107.13
SMILES Code : C=CS(=O)(N)=O
MDL No. :MFCD00051751
InChI Key :JOXWSDNHLSQKCC-UHFFFAOYSA-N
Pubchem ID :520075

Safety of [ 2386-58-5 ]

GHS Pictogram:
Signal Word:Warning
Hazard Statements:H315-H319-H335
Precautionary Statements:P261-P305+P351+P338

Application In Synthesis of [ 2386-58-5 ]

* All experimental methods are cited from the reference, please refer to the original source for details. We do not guarantee the accuracy of the content in the reference.

  • Downstream synthetic route of [ 2386-58-5 ]

[ 2386-58-5 ] Synthesis Path-Downstream   1~1

  • 1
  • [ 6608-47-5 ]
  • [ 2386-58-5 ]
YieldReaction ConditionsOperation in experiment
With ammonia; In diethyl ether; for 0.166667h; A solution of TEA (7.67 mL, 55.0 mmol) in Et2O (50 ml) was added to a solution of 2-chloroethanesulfonyl chloride (5.22 mL, 50 mmol) in Et2O (100 ml) at -24 C. (CCl4-dry ice bath) and the mixture was stirred and allowed to warm to rt over 2 h. The reaction mixture was filtered to remove a white precipitate and the filtrate was concentrated (20 mL of volume). NH3 was bubbled into the solution of <strong>[6608-47-5]ethenesulfonyl chloride</strong> (1.266 g, 10.00 mmol) in Et2O (20 mL) for 10 min and the white precipitate was removed by filtration. The filtrate was concentrated to yield ethenesulfonamide (180 mg, 1.680 mmol, 16.80% yield) as a colorless gel which was used without further purification. 1H NMR (300 MHz, CD3OD) delta ppm 6.80 (dd, J=16.5, 9.9 Hz, 1H), 6.16 (d, J=16.5 Hz, 1H), 5.87 (dd, J=9.9 Hz, 1H). LC-MS retention time 0.17 min; m/z 108 (MH+). LC data was recorded on a Shimadzu LC-10AS liquid chromatograph equipped with a Phenomenex-Luna 10 u C18 4.6×50 mm column using a SPD-10AV UV-Vis detector at a detector wave length of 220 nM. The elution conditions employed a flow rate of 5 ml/min, a gradient of 100% solvent A/0% solvent B to 0% solvent A/100% solvent B, a gradient time of 2 min, a hold time of 1 min, and an analysis time of 5 min where solvent A was 10% MeOH/90% H2O/0.1% trifluoroacetic acid and solvent B was 10% H2O/90% MeOH/0.1% trifluoroacetic acid. MS data was determined using a Micromass Platform for LC in electrospray mode.
 

Historical Records