Name: 2449-35-6|4,4'-Sulfonyldibenzoic acid|98%
Brand: Ambeed
SKU: A600849
Price: 7.0 USD
Availability: InStock
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1
[ 64-17-5 ]
[ 2449-35-6 ]
[ 47424-13-5 ]

Yield	Reaction Conditions	Operation in experiment
65%	With sulfuric acid for 5h; Heating;
62%	With sulfuric acid for 6h; Reflux;
	With sulfuric acid

Reference： [1]Patel; Patolia; Baxi [Journal of the Indian Chemical Society, 1990, vol. 67, # 7, p. 599 - 601]
[2]Gu, Pei-Yang; Zhang, You-Hao; Liu, Gao-Yan; Ge, Jian-Feng; Xu, Qing-Feng; Zhang, Qichun; Lu, Jian-Mei [Chemistry - An Asian Journal, 2013, vol. 8, # 9, p. 2161 - 2166]
[3]Buehler; Masters [Journal of Organic Chemistry, 1939, vol. 4, p. 262,264] Murahashi; Anzai [Kobunshi Kagaku, 1946, vol. 3, p. 33,39][Chem.Abstr., 1950, p. 11106]

2
[ 599-66-6 ]
[ 2449-35-6 ]

Reference： [1]Patent: US2614120,1950,
[2]Acta Chemica Scandinavica (1947),1953,vol. 7,p. 774,778
[3]Kobunshi Kagaku,1946,vol. 3,p. 33,39
Chem.Abstr.,1950,p. 11106
[4]Chemische Berichte,1878,vol. 11,p. 121
[5]Bulletin de la Societe Chimique de France,1893,vol. <3> 9,p. 707

3
[ 2449-35-6 ]
[ 4462-61-7 ]

Yield	Reaction Conditions	Operation in experiment
93%	With thionyl chloride; N,N-dimethyl-formamide for 24h; Reflux;
78%	With thionyl chloride In N,N-dimethyl-formamide at 90℃; for 3h;
	With phosphorus pentachloride at 130 - 140℃;

Reference： [1]Location in patent: experimental part Gibson, Harry W.; Brumfield, Kimberly K.; Grisle, Roger A.; Hermann, Christine K. F. [Journal of Polymer Science, Part A: Polymer Chemistry, 2010, vol. 48, # 17, p. 3856 - 3867]
[2]Tundidor-Camba; Terraza; Tagle; Coll; Ojeda; Pino [RSC Advances, 2015, vol. 5, # 29, p. 23057 - 23066]
[3]Iwanowa et al. [Zhurnal Organicheskoi Khimii, 1967, vol. 3, p. 146,150, 151][Journal of Organic Chemistry USSR (English Translation), 1967, vol. 3, p. 141,144, 145]

4
[ 599-66-6 ]
[ 64-19-7 ]
CrO₃ [ No CAS ]
[ 2449-35-6 ]

Reference： [1]Journal of Organic Chemistry,1939,vol. 4,p. 262,264

5
[ 599-66-6 ]
[ 64-19-7 ]
potassium permanganate [ No CAS ]
[ 2449-35-6 ]

Reference： [1]Chemische Berichte,1878,vol. 11,p. 121

6
[ 852152-46-6 ]
[ 2449-35-6 ]
polyamide, polycondensation; monomer(s): 2,2'-di(naphthalen-1-yl)biphenyl-4,4'-diamine; 4,4'-sulfonyldibenzoic acid [ No CAS ]

Yield	Reaction Conditions	Operation in experiment
	With pyridine; triphenyl phosphite; calcium chloride In 1-methyl-pyrrolidin-2-one at 100℃;

Reference： [1]Liaw, Der-Jang; Chang, Feng-Chyuan; Leung, Man-Kit; Chou, Meng-Yen; Muellen, Klaus [Macromolecules, 2005, vol. 38, # 9, p. 4024 - 4029]

7
[ 37968-97-1 ]
[ 2449-35-6 ]
[ 6018-89-9 ]
[[Ni(4,4'-sulfonyldibenzoate)(4,4'-dipyridyl-sulfide)(H₂O)0.5](H₂O)1.2]n [ No CAS ]

Yield	Reaction Conditions	Operation in experiment
58%	With NaOH In water High Pressure; mixt. of Ni(CH3CO2)2*4H2O, ligands and NaOH in H2O placed in autoclave, heated to 160°C for 5 d; elem. anal.;

Reference： [1]Li, Dong-Sheng; Fu, Feng; Zhao, Jun; Wu, Ya-Pan; Du, Miao; Zou, Kun; Dong, Wen-Wen; Wang, Yao-Yu [Dalton Transactions, 2010, vol. 39, # 48, p. 11522 - 11525]

8
[ 3965-53-5 ]
[ 2449-35-6 ]

Yield	Reaction Conditions	Operation in experiment
96%	With potassium hydroxide In ethanol Reflux;

Reference： [1]Location in patent: experimental part Gibson, Harry W.; Brumfield, Kimberly K.; Grisle, Roger A.; Hermann, Christine K. F. [Journal of Polymer Science, Part A: Polymer Chemistry, 2010, vol. 48, # 17, p. 3856 - 3867]

9
[ 177325-13-2 ]
[ 2449-35-6 ]
[ 7732-18-5 ]
[ CAS Unavailable ]
[ CAS Unavailable ]

Yield	Reaction Conditions	Operation in experiment
43%	With 1,2-diaminoethane In water High Pressure; mixt. of Zn(OAc)2*2H2O, levofloxacin hydrochloride, acid and water; adjusted to pH 8.5 with 1,2-diaminoethane, sealed in autoclave, heated at 130°C for 4 d, cooled to room temp.; elem. anal.;

Reference： [1]He, Jiang-Hong; Sun, Dian-Zhen; Xiao, Dong-Rong; Yan, Shi-Wei; Chen, Hai-Yan; Wang, Xin; Yang, Juan; Wang, En-Bo [Polyhedron, 2012, vol. 42, # 1, p. 24 - 29]

10
[ 855766-92-6 ]
[ 2449-35-6 ]
Co⁽²⁺⁾*6H₂O*3NO₃^(1-) [ No CAS ]
[ 1434133-67-1 ]

Reference： [1]CrystEngComm,2013,vol. 15,p. 1377 - 1388

11
magnesium(II) nitrate hexahydrate [ No CAS ]
[ 64-17-5 ]
[ 2449-35-6 ]
[ 7732-18-5 ]
[Mg₃(OH)₂(4,4′-sulfonyldibenzoate)₂(EtOH)(H₂O)₃]*3.5H₂O [ No CAS ]

Yield	Reaction Conditions	Operation in experiment
41.2%	at 150℃; for 48h; High pressure;	Compound 1 can be synthesized by hydrothermal method or microwave syntheses method. In both of the two methods, a reactor comprises a Teflon inner cup and iron outer cup is utilized to synthesizing Compound 1. The difference between hydrothermal method and microwave syntheses method is that the reactor is put into a high temperature furnace for synthesizing in the hydrothermal method but the reactor is put into a microwave reactor for synthesizing in the microwave syntheses method. The hydrothermal method for synthesizing compound 1 is detailed as the following: First, 0.205 g (0.8 mmol) Mg(NO3)2.6H2O, 0.0612 g (0.2 mmol) 4,4′-sulfonyldibenzoic acid (H2SBA), 5.0 mL ethanol (EtOH), and 1.0 mL water (H2O) are put into the Teflon inner cup in order. And then, the Teflon inner cup is put into the iron outer cup and the reactor is put into the high temperature furnace. In the high temperature furnace, the reactor (or the Mg(NO3)2.6H2O, 4,4′-sulfonyldibenzoic acid (H2SBA), ethanol (EtOH), and water (H2O) in the reactor) is heated to 150° C. with 60° Ch-1 and it is maintained at 150° C. for reacting for about 2 days. After, the reactor is cooled to room temperature with 6° Ch-1. And then, compound 1 is gotten through suction filtration, washing with ethanol and water, and drying. The compound 1 is a transparent acicular crystal. The weight of the gotten compound 1 is 0.072 g, and the yield of the compound 1 is 41.2% by calculating with defining the 4,41-sulfonyldibenzoic acid (H2SBA) as a limiting reagent. The weight of the Mg(NO3)2.6H2O, 4,4′-sulfonyldibenzoic acid (H2SBA), ethanol (EtOH), and water (H2O) mentioned above are just taken as an example, and not limited to this. The weight of the Mg(NO3)2.6H2O, 4,4′-sulfonyldibenzoic acid (H2SBA), ethanol (EtOH), and water (H2O) could be increased or decreased with the same ratio of weight mentioned above.
41.21%	at 150℃; for 0.333333h; Autoclave; Microwave irradiation;

Reference： [1]Current Patent Assignee: CHUNG YUAN CHRISTIAN UNIVERSITY - US2013/66093, 2013, A1 Location in patent: Paragraph 0041
[2]Wu, Cheng-You; Raja, Duraisamy Senthil; Yang, Chun-Chuen; Yeh, Chun-Ting; Chen, Yu-Ru; Li, Chen-Yu; Ko, Bao-Tsan; Lin, Chia-Her [CrystEngComm, 2014, vol. 16, # 39, p. 9308 - 9319]

12
zinc(II) nitrate hexahydrate [ No CAS ]
[ 64-17-5 ]
[ 2449-35-6 ]
[ 7732-18-5 ]
Zn₃(4,4′-sulfonyldibenzoate)₂(OH)₂*EtOH [ No CAS ]

Yield	Reaction Conditions	Operation in experiment
88.4%	at 150℃; for 48h; High pressure;	Compound 5 also can be synthesized by hydrothermal method or microwave syntheses method. The hydrothermal method for synthesizing compound 5 is detailed as following: First, 0.118 g (0.4 mmol) Zn(NO3)2.6H2O, 0.0612 g (0.2 mmol) 4,4′-sulfonyldibenzoic acid (H2SBA), 5.0 mL ethanol (EtOH), and 1.0 mL water (H2O) are put into the Teflon inner cup in order. And then, the Teflon inner cup is put into the iron outer cup and the reactor is put into the high temperature furnace. In the high temperature furnace, the reactor (or the Zn(NO3)2.6H2O, 4,4′-sulfonyldibenzoic acid (H2SBA), ethanol (EtOH), and water (H2O) in the reactor) is heated to 150° C. with 60° Ch-1 and it is maintained at 150° C. for reacting for about 2 days. After, the reactor is cooled to room temperature with 6° Ch-1. And then, compound 5 is gotten through suction filtration, washing with ethanol and water, and drying. The compound 5 is a transparent acicular crystal. The weight of the gotten compound 5 is 0.0782 g, and the yield of the compound 5 is 88.4% by calculating with defining the 4,4′-sulfonyldibenzoic acid (H2SBA) as a limiting reagent. The weight of the Zn(NO3)2.6H2O, 4,4′-sulfonyldibenzoic acid (H2SBA), ethanol (EtOH), and water (H2O) mentioned above are just taken as an example, and not limited to this. The weight of the Zn(NO3)2.6H2O, 4,4′-sulfonyldibenzoic acid (H2SBA), ethanol (EtOH), and water (H2O) could be increased or decreased with the same ratio of weight mentioned above.
88.41%	at 180℃; for 0.666667h; Autoclave; Microwave irradiation;

Reference： [1]Current Patent Assignee: CHUNG YUAN CHRISTIAN UNIVERSITY - US2013/66093, 2013, A1 Location in patent: Paragraph 0070
[2]Wu, Cheng-You; Raja, Duraisamy Senthil; Yang, Chun-Chuen; Yeh, Chun-Ting; Chen, Yu-Ru; Li, Chen-Yu; Ko, Bao-Tsan; Lin, Chia-Her [CrystEngComm, 2014, vol. 16, # 39, p. 9308 - 9319]

13
calcium(II) nitrate tetrahydrate [ No CAS ]
[ 2449-35-6 ]
[ 7732-18-5 ]
Ca(4,4′-sulfonyldibenzoate)*H₂O [ No CAS ]

Yield	Reaction Conditions	Operation in experiment
44.5%	In ethanol at 120℃; for 48h; High pressure;	Compound 2 can be synthesized by hydrothermal method or microwave syntheses method. The hydrothermal method for synthesizing compound 2 is detailed as following: First, 0.0945 g (0.4 mmol) Ca(NO3)2.4H2O, 0.0612 g (0.2 mmol) 4,4′-sulfonyldibenzoic acid (H2SBA), 9.0 mL ethanol (EtOH), and 1.0 mL water (H2O) are put into the Teflon inner cup in order. And then, the Teflon inner cup is put into the iron outer cup and the reactor is put into the high temperature furnace. In the high temperature furnace, the reactor (or the Ca(NO3)2.4H2O, 4,4′-sulfonyldibenzoic acid (H2SBA), ethanol (EtOH), and water (H2O) in the reactor) is heated to 120° C. with 60°Ch-1 and it is maintained at 120° C. for reacting for about 2 days. After, the reactor is cooled to room temperature with 6° Ch-1. And then, compound 2 is gotten through suction filtration, washing with ethanol and water, and drying. The compound 2 is a transparent tabular crystal. The weight of the gotten compound 2 is 0.0323 g, and the yield of the compound 2 is 44.5% by calculating with defining the 4,4′-sulfonyldibenzoic acid (H2SBA) as a limiting reagent. The microwave syntheses method for synthesizing compound 2 is detailed as following: First, Ca(NO3)2.4H2O, 4,4′-sulfonyldibenzoic acid (H2SBA), ethanol (EtOH), and water (H2O) with the same weight (or weight ratio) as above mentioned are put into the Teflon inner cup in order. And then, the Teflon inner cup is put into the iron outer cup and the reactor is put into the microwave reactor. In the microwave reactor, the output power of the microwave reactor is set to 400 W, and the reactor (or the Ca(NO3)2.4H2O, 4,4′-sulfonyldibenzoic acid (H2SBA), ethanol (EtOH), and water (H2O) in the reactor) is heated to 150° C. with 60° Ch-1. It is maintained at 150° C. for reacting or synthesizing for 20 minutes. After, the reactor is cooled to room temperature with 6° Ch-1. And then, compound 2 is gotten through suction filtration, washing with ethanol and water, and drying. A compound is produced by heating compound 2 to 200° C. to remove water of crystallization from compound 2. According to powder X-ray diffraction analysis for this compound, it is found that the structures of this compound and compound 2 are almost the same and this compound has a formula [Ca(SBA)]. The weight of the Ca(NO3)2.4H2O, 4,4′-sulfonyldibenzoic acid (H2SBA), ethanol (EtOH), and water (H2O) mentioned above are just taken as an example, and not limited to this. The weight of the Ca(NO3)2.4H2O, 4,4′-sulfonyldibenzoic acid (H2SBA), ethanol (EtOH), and water (H2O) could be increased or decreased with the same ratio of weight mentioned above.

Reference： [1]Current Patent Assignee: CHUNG YUAN CHRISTIAN UNIVERSITY - US2013/66093, 2013, A1 Location in patent: Paragraph 0054

14
strontium nitrate [ No CAS ]
[ 2449-35-6 ]
[ 7732-18-5 ]
Sr(4,4′-sulfonyldibenzoate)*0.5H₂O [ No CAS ]

Yield	Reaction Conditions	Operation in experiment
75.3%	In ethanol at 150℃; for 48h; High pressure;	Compound 3 also can be synthesized by hydrothermal method or microwave syntheses method. The hydrothermal method for synthesizing compound 3 is detailed as following: First, 0.1692 g (0.8 mmol) Sr(NO3)2, 0.0612 g (0.2 mmol) 4,4′-sulfonyldibenzoic acid (H2SBA), 7.0 mL ethanol (EtOH), and 3.0 mL water (H2O) are put into the Teflon inner cup in order. And then, the Teflon inner cup is put into the iron outer cup and the reactor is put into the high temperature furnace. In the high temperature furnace, the reactor (or the Sr(NO3)2, 4,4′-sulfonyldibenzoic acid (H2SBA), ethanol (EtOH), and water (H2O) in the reactor) is heated to 150° C. with 60° Ch-1 and it is maintained at 150° C. for reacting for about 2 days. After, the reactor is cooled to room temperature with 6° Ch-1. And then, compound 3 is gotten through suction filtration, washing with ethanol and water, and drying. The compound 3 is a transparent fringe crystal (or columnar crystal). The weight of the gotten compound 3 is 0.0616 g, and the yield of the compound 3 is 75.3% by calculating with defining the 4,4′-sulfonyldibenzoic acid (H2SBA) as a limiting reagent. The microwave syntheses method for synthesizing compound 3 is detailed as following: First, Sr(NO3)2, 4,4′-sulfonyldibenzoic acid (H2SBA), ethanol (EtOH), and water (H2O) with the same weight (or weight ratio) as above mentioned are put into the Teflon inner cup in order. And then, the Teflon inner cup is put into the iron outer cup and the reactor is put into the microwave reactor. In the microwave reactor, the output power of the microwave reactor is set to 400 W, and the reactor (or the Sr(NO3)2, 4,4′-sulfonyldibenzoic acid (H2SBA), ethanol (EtOH), and water (H2O) in the reactor) is heated to 180° C. with 60° Ch-1. It is maintained at 180° C. for reacting or synthesizing for 20 minutes. After, the reactor is cooled to room temperature with 6° Ch-1. And then, compound 3 is gotten through suction filtration, washing with ethanol and water, and drying. A compound is produced by heating compound 3 to 200° C. to remove water of crystallization from compound 3. According to powder X-ray diffraction analysis for this compound, it is found that the structures of this compound and compound 3 are almost the same and this compound has a formula [Sr(SBA)]. The weight of the Sr(NO3)2, 4,4′-sulfonyldibenzoic acid (H2SBA), ethanol (EtOH), and water (H2O) mentioned above are just taken as an example, and not limited to this. The weight of the Sr(NO3)2, 4,4′-sulfonyldibenzoic acid (H2SBA), ethanol (EtOH), and water (H2O) could be increased or decreased with the same ratio of weight mentioned above.

Reference： [1]Current Patent Assignee: CHUNG YUAN CHRISTIAN UNIVERSITY - US2013/66093, 2013, A1 Location in patent: Paragraph 0055

15
manganese (II) nitrate tetrahydrate [ No CAS ]
[ 64-17-5 ]
[ 2449-35-6 ]
[ 1426678-30-9 ]

Yield	Reaction Conditions	Operation in experiment
87.2%	In water at 150℃; for 48h; High pressure;	Compound 4 also can be synthesized by hydrothermal method or microwave syntheses method. The hydrothermal method for synthesizing compound 4 is detailed as following: First, 0.100 g (0.4 mmol) Mn(NO3)2.4H2O, 0.1224g (0.4 mmol) 4,4′-sulfonyldibenzoic acid (H2SBA), 5.0 mL ethanol (EtOH), and 1.0 mL water (H2O) are put into the Teflon inner cup in order. And then, the Teflon inner cup is put into the iron outer cup and the reactor is put into the high temperature furnace. In the high temperature furnace, the reactor (or the Mn(NO3)2.4H2O, 4,4′-sulfonyldibenzoic acid (H2SBA), ethanol (EtOH), and water (H2O) in the reactor) is heated to 150° C. with 60° Ch-1 and it is maintained at 150° C. for reacting for about 2 days. After, the reactor is cooled to room temperature with 6° Ch-1. And then, compound 4 is gotten through suction filtration, washing with ethanol and water, and drying. The compound 4 is a transparent acicular crystal. The weight of the gotten compound 4 is 0.0705 g, and the yield of the compound 4 is 87.2% by calculating with defining the 4,4′-sulfonyldibenzoic acid (H2SBA) as a limiting reagent. The weight of the Mn(NO3)2.4H2O, 4,4′-sulfonyldibenzoic acid (H2SBA), ethanol (EtOH), and water (H2O) mentioned above are just taken as an example, and not limited to this. The weight of the Mn(NO3)2.4H2O, 4,4′-sulfonyldibenzoic acid (H2SBA), ethanol (EtOH), and water (H2O) could be increased or decreased with the same ratio of weight mentioned above.
	In water at 180℃; for 0.333333h; Autoclave; Microwave irradiation;

Reference： [1]Current Patent Assignee: CHUNG YUAN CHRISTIAN UNIVERSITY - US2013/66093, 2013, A1 Location in patent: Paragraph 0062
[2]Wu, Cheng-You; Raja, Duraisamy Senthil; Yang, Chun-Chuen; Yeh, Chun-Ting; Chen, Yu-Ru; Li, Chen-Yu; Ko, Bao-Tsan; Lin, Chia-Her [CrystEngComm, 2014, vol. 16, # 39, p. 9308 - 9319]

16
[ 280-57-9 ]
zinc(II) nitrate hexahydrate [ No CAS ]
[ 2449-35-6 ]
[Zn₂(4,4'-sulfonyldibenzoate)₂(1,4-diazabicyclo[2.2.2]octane)] [ No CAS ]

Yield	Reaction Conditions	Operation in experiment
56%	In N,N-dimethyl-formamide at 100℃; for 48h; Sealed tube;

Reference： [1]Hijikata, Yuh; Horike, Satoshi; Sugimoto, Masayuki; Inukai, Munehiro; Fukushima, Tomohiro; Kitagawa, Susumu [Inorganic Chemistry, 2013, vol. 52, # 7, p. 3634 - 3642]

17
zinc(II) nitrate hexahydrate [ No CAS ]
[ 2449-35-6 ]
[ 113682-56-7 ]
[ 68-12-2 ]
[Zn₂(4,4'-sulfonyldibenzoate)₂(1,4-bis(4-pyridyl)benzene)]_*2(N,N-dimethylformamide) [ No CAS ]

Reference： [1]Inorganic Chemistry,2013,vol. 52,p. 3634 - 3642

18
zinc(II) nitrate hexahydrate [ No CAS ]
[ 57654-36-1 ]
[ 2449-35-6 ]
[ 33513-42-7 ]
[Zn₂(4,4'-sulfonyldibenzoate)₂(3,6-bis(4-pyridyl)-1,2,4,5-tetrazine)]_*2(N,N-dimethylformamide) [ No CAS ]

Yield	Reaction Conditions	Operation in experiment
68%	at 100℃; for 48h; Sealed tube;

Reference： [1]Hijikata, Yuh; Horike, Satoshi; Sugimoto, Masayuki; Inukai, Munehiro; Fukushima, Tomohiro; Kitagawa, Susumu [Inorganic Chemistry, 2013, vol. 52, # 7, p. 3634 - 3642]

19
[ 553-26-4 ]
zinc(II) nitrate hexahydrate [ No CAS ]
[ 2449-35-6 ]
[Zn₂(4,4'-sulfonyldibenzoate)₂(4,4'-bipyridyl)] [ No CAS ]

Yield	Reaction Conditions	Operation in experiment
75%	In N,N-dimethyl-formamide at 100℃; for 48h; Sealed tube;

Reference： [1]Hijikata, Yuh; Horike, Satoshi; Sugimoto, Masayuki; Inukai, Munehiro; Fukushima, Tomohiro; Kitagawa, Susumu [Inorganic Chemistry, 2013, vol. 52, # 7, p. 3634 - 3642]

20
nickel(II) nitrate hexahydrate [ No CAS ]
[ 2449-35-6 ]
[ 39642-94-9 ]
2Ni⁽²⁺⁾*6H₂O*2C₁₄H₈O₆S^(2-)*C₁₈H₂₂N₄O₂ [ No CAS ]

Yield	Reaction Conditions	Operation in experiment
66%	With sodium hydroxide In methanol; water at 120℃; for 48h; Autoclave;

Reference： [1]Liao, Yu-Hung; Hsu, Wayne; Yang, Chun-Chuen; Wu, Can-Yu; Chen, Jhy-Der; Wang, Ju-Chun [CrystEngComm, 2013, vol. 15, # 19, p. 3974 - 3983]

21
nickel(II) nitrate hexahydrate [ No CAS ]
[ 2449-35-6 ]
[ 14180-69-9 ]
C₁₆H₁₈N₄O₂*Ni⁽²⁺⁾*2H₂O*C₁₄H₈O₆S^(2-) [ No CAS ]

Yield	Reaction Conditions	Operation in experiment
64%	With sodium hydroxide In methanol; water at 120℃; for 48h; Autoclave;

Reference： [1]Liao, Yu-Hung; Hsu, Wayne; Yang, Chun-Chuen; Wu, Can-Yu; Chen, Jhy-Der; Wang, Ju-Chun [CrystEngComm, 2013, vol. 15, # 19, p. 3974 - 3983]

22
manganese(II) chloride tetrahydrate [ No CAS ]
[ 2449-35-6 ]
4,4′-bis(imidazolyl)biphenyl [ No CAS ]
[ 7732-18-5 ]
[ 33513-42-7 ]
[Mn₃(4,4'-bisimidazolylbiphenyl)₂(sdb)₂(NO₂^-)₂(H₂O)₂]_n·2DMF [ No CAS ]

Yield	Reaction Conditions	Operation in experiment
58%	at 95℃; for 72h; High pressure;	A mixture of MnCl2·4H2O (19.8mg, 0.1mmol), sdb (30.4mg, 0.1mmol), and BIBP (28.8mg, 0.1mmol) was dissolved in 2mL of distilled water and 6mL of DMF. The final mixture was sealed in a 15mL Parr Teflon-lined stainless-steel vessel and heated at 95°C for 3days, and then the reaction system was cooled to room temperature. Colorless diamond bulk crystals of 1 were obtained, washed with water, and dried under ambient conditions (yields: 58% for 1 based on BIBP). Elemental analysis (%) calcd for (C70H62Mn3N12O20S2): C, 51.89; H, 3.86; N, 10.37. Found: C, 51.84; H, 3.82; N, 10.33. IR (KBr, cm-1): 1656(w),1634(w), 1597(vs), 1511(s), 1395(vs), 1324(m), 1161(m), 1100(m), 838(m), 738(s), 617(m).

Reference： [1]Zhang, Chun-Li; Qin, Ling; Zheng, He-Gen [Inorganic Chemistry Communications, 2013, vol. 34, p. 34 - 36]

23
[ 100-48-1 ]
sodium azide [ No CAS ]
zinc(II) nitrate hexahydrate [ No CAS ]
[ 2449-35-6 ]
Zn<SUB>2</SUB>(OH)(SDBA)(5-(4-pyridyl)tetrazolate) [ No CAS ]

Yield	Reaction Conditions	Operation in experiment
52%	In water at 180℃; for 72h; High pressure;	Synthesis of the complex Zn2(OH)(SDBA)(PTZ) (1) The single crystals of complex 1 were prepared by in situ hydrothermal reaction. A mixture containing Zn(NO3)2*6H2O (59.2 mg, 0.2 mmol), 4-cyanopyridine (10.4 mg, 0.1 mmol), H2SDBA (30.6 mg, 0.1 mmol) and NaN3 (13.2 mg, 0.2 mmol) in 15 mL deionized water was sealed in a 25 mL Teflonlined stainless steel container and heated at 180 °C for 72 h under the autogenous pressure. After the mixture was slowly cooled to room temperature, colorless block crystals suitable for X-ray analysis were obtained directly, which were washed with deionized water and ethanol several times, and dried in air, 31.1 mg, yield 52% based on 4-cyanopyridine.

Reference： [1]Huang, Rong-Yi; Xue, Chen; Wang, Zhu-Qinq; Xu, Heng; Wu, Gen-Hua; Ye, Shi-Yong [Inorganica Chimica Acta, 2013, vol. 405, p. 302 - 308]

24
cadmium(II) nitrate tetrhydrate [ No CAS ]
[ 2449-35-6 ]
[ 1338812-80-8 ]
[Cd(4,4'-sdba)(,4-bis(1,2,4-triazol-1-ylmethyl)-2,3,5,6-tetramethylbenzene)]n [ No CAS ]

Yield	Reaction Conditions	Operation in experiment
58%	In water at 160℃; for 72h; High pressure;	2.2.3. Synthesis of [Cd(p-phda)(btmx)(H₂O)]H₂O}_n (3) General procedure: A mixture of Cd(NO3)2*4H2O (30.8 mg, 0.1 mmol), btmx (29.8 mg, 0.1 mmol), and p-H2phda (19.4 mg, 0.1 mmol) in 10 mL distilled H2O was sealed in a 25 mL Teflon-lined stainless steel container and heated at 160 °C for 3 days. After the mixture was cooled to room temperature at a rate of 5 °C/h, colorless crystals of 3 were obtained, yield 63% based on Cd.

Reference： [1]Wu, Dongqing; Meng, Wei; Zhang, Lin; Liu, Lu; Hou, Hongwei; Fan, Yaoting [Inorganica Chimica Acta, 2013, vol. 405, p. 318 - 325]

25
[ 109-99-9 ]
zinc(II) nitrate hexahydrate [ No CAS ]
[ 2449-35-6 ]
[ 348596-90-7 ]
[Zn₂(4,4'-sulfonyldibenzoate)₂(1,3-bis(imidazol-1-ylmethyl)-2,4,6-trimethylbenzene)](tetrahydrofuran)₂ [ No CAS ]

Yield	Reaction Conditions	Operation in experiment
42%	In methanol; water at 124.84℃; for 50h; Autoclave;	Synthesis of [Zn₂ (SDB)₂ (BITMB)]·(THF)₂}_n (CP3) H2SDB (75 mg, 0.36 mmol), BITMB (70 mg, 0.25 mmol) and Zn(NO3)2·6H2O (100 mg, 0.33 mmol) were dispersed in 12 mL mixed solvent (5 mL water, 5 mL THF and 2 mL methanol) and then sealed in a 23 mL Teflon-lined autoclave, which was heated at 398 K for 50 h. Yield=42%. Elemental analysis (%), Cal.: C, 54.69; H, 4.50; N, 4.81; S, 5.51; found: C, 54.32; H, 4.65; N, 4.68; IR cm-1 (KBr): 3435 (br), 3142 (w), 2924 (w), 2366 (w), 1657 (s), 1562 (w), 1406 (s), 1293 (w), 1223 (w), 1163 (m), 1098 (m), 1014 (w), 870 (w), 740 (s), 619 (w).

Reference： [1]Bisht, Kamal Kumar; Rachuri, Yadagiri; Parmar, Bhavesh; Suresh, Eringathodi [Journal of Solid State Chemistry, 2014, vol. 213, p. 43 - 51]

26
[ 123-91-1 ]
cobalt(II) nitrate hexahydrate [ No CAS ]
[ 2449-35-6 ]
[ 348596-90-7 ]
[Co₂(4,4'-sulfonyldibenzoate)₂(1,3-bis(imidazol-1-ylmethyl)-2,4,6-trimethylbenzene)](dioxane)₃ [ No CAS ]

Yield	Reaction Conditions	Operation in experiment
36%	In water at 124.84℃; for 60h; Autoclave;	Synthesis of [Co₂(SDB)₂(BITMB)]·(dioxane)₃}_n (CP4) H2SDB (75 mg, 0.36 mmol), BITMB (90 mg, 0.32 mmol) and Co(NO3)2·6H2O (154 mg, 0.52 mmol) were dispersed in a mixture of 3 mL water and 3 mL 1,4-dioxane and then sealed in a 14 mL Teflon-lined autoclave, which was heated at 398 K for 60 h. Yield=36%. Elemental analysis (%), Cal.: C, 53.86; H, 4.76; N, 4.41; S, 5.05; found: C, 53.68; H, 5.02; N, 4.32; IR cm-1 (KBr): 3425 (br), 3105 (w), 2956 (w), 2850 (w), 2375 (w), 1640 (s), 1562 (w), 1406 (s), 1293 (m), 1163 (m), 1112 (s), 1014 (w), 870 (m), 735 (s), 620 (w).

Reference： [1]Bisht, Kamal Kumar; Rachuri, Yadagiri; Parmar, Bhavesh; Suresh, Eringathodi [Journal of Solid State Chemistry, 2014, vol. 213, p. 43 - 51]

27
nickel(II) nitrate hexahydrate [ No CAS ]
[ 2449-35-6 ]
[ 348596-90-7 ]
[Ni(4,4'-sulfonyldibenzoate)(1,3-bis(imidazol-1-ylmethyl)-2,4,6-trimethylbenzene)(water)](water) [ No CAS ]

Yield	Reaction Conditions	Operation in experiment
45%	In 1,4-dioxane; methanol; water at 124.84℃; for 50h; Autoclave;	Synthesis of [Ni(SDB)(BITMB)(H₂O)]·H₂O}_n (CP1) H2SDB (70 mg, 0.33 mmol), BITMB (75 mg, 0.26 mmol) and Ni(NO3)2·6H2O (100 mg, 0.34 mmol) were dispersed in 10 mL mixed solvent (3 mL water, 3 mL methanol and 4 mL 1,4-dioxane) and then sealed in a 23 mL Teflon-lined autoclave, which was heated at 398 K for 50 h. Yield=45%. Elemental analysis (%), Cal.: C, 54.81; H, 4.75; N, 8.25; S, 4.72; found: C, 54.27; H, 4.87; N, 8.12. IR cm-1 (KBr): 3435 (br), 2924 (w), 2362 (w), 1616 (s), 1563 (m), 1394 (s), 1298 (m), 1228 (w), 1164 (m), 1103 (m), 1020 (m), 829 (w), 740 (s), 689 (w), 620 (m).

Reference： [1]Bisht, Kamal Kumar; Rachuri, Yadagiri; Parmar, Bhavesh; Suresh, Eringathodi [Journal of Solid State Chemistry, 2014, vol. 213, p. 43 - 51]

28
[ 109-99-9 ]
cadmium(II) nitrate tetrhydrate [ No CAS ]
[ 2449-35-6 ]
[ 348596-90-7 ]
[Cd(4,4'-sulfonyldibenzoate)(1,3-bis(imidazol-1-ylmethyl)-2,4,6-trimethylbenzene)(water)](tetrahydrofuran)(water) [ No CAS ]

Yield	Reaction Conditions	Operation in experiment
67%	In water at 124.84℃; for 98h; Autoclave;	Synthesis of [{Cd(SDB)(BITMB)(H₂O)}·(THF)·H₂O]_n (CP2) H2SDB (60 mg, 0.29 mmol), BITMB (100 mg, 0.35 mmol) and Cd(NO3)2·4H2O (300 mg, 0.97 mmol) were dispersed in 10 mL water/tetrahydrofuran (1:1) and then sealed in a 23 mL Teflon-lined autoclave, which was heated at 398 K for 98 h. Yield=67%. Elemental analysis (%) Cal.: C, 52.21; H, 5.01; N, 6.96; S, 3.98; found: C, 52.48; H, 5.35; N, 6.74; IR cm-1 (KBr): 3412 (br), 3123 (w), 2961 (w), 2367 (w), 1595 (m), 1553 (s), 1398 (s), 1293 (m), 1223 (w), 1158 (w), 1089 (w), 1019 (w), 856 (w), 745 (s), 619 (m).

Reference： [1]Bisht, Kamal Kumar; Rachuri, Yadagiri; Parmar, Bhavesh; Suresh, Eringathodi [Journal of Solid State Chemistry, 2014, vol. 213, p. 43 - 51]

29
[ 2449-35-6 ]
[ 887917-77-3 ]
[ 7732-18-5 ]
[ 7646-85-7 ]
[Zn₂(4'-(3-pyridyl)-4,2':6',4″-terpyridine)₂(4,4'-sulfonyldibenzoic acid(-2H))₂]_n.1.5_n(H₂O) [ No CAS ]

Yield	Reaction Conditions	Operation in experiment
51.1%	With sodium hydroxide at 180℃; for 72h; High pressure;	2.3.4. Synthesisof[Zn2(344-pytpy)2(sfdb)2]n .1.5n(H2O) (4) This compoundwaspreparedinasimilarprocedureas 2, byusing H2sfdb (0.0300g,0.1mmol)inplaceofH2oxandadjustthepH valueofthemixtureto6.0.Thecolorlesscrystalsof 4 wereobtained, washedwithdistilledwater(5mL),anddriedinairtogive0.0709g(yield51.1%basedonZn).Anal.calcd.(%)forC68H47N8O13.5S2Zn2: C,58.88;H,3.42;N,8.08.found:C,58.66;H,3.58;N, 8.68.IR(KBr,cm1): 3588(m),3393(w),3078(s),1608(m)1547(m),1491(s),1408(w),1326(s),1300(s),1169(s),1137(s),1102(s),1069(s),1017(s),866(s),823(w),780(s),739(m),694 (s),583(s),505(m).

Reference： [1]Yang, Xiao-Le; Shangguan, Yi-Qing; Hu, Huai-Ming; Xu, Bing; Wang, Bao-Cheng; Xie, Juan; Yuan, Fei; Yang, Meng-Lin; Dong, Fa-Xin; Xue, Gang-Lin [Journal of Solid State Chemistry, 2014, vol. 216, p. 13 - 22]

30
1,4-bis(4-pyridylethenyl)benzene [ No CAS ]
zinc nitrate tetrahydrate [ No CAS ]
[ 127-19-5 ]
[ 2449-35-6 ]
[Zn2(bpeb)(sdb)2]·2DMA·2H2O [ No CAS ]

Yield	Reaction Conditions	Operation in experiment
66%	With sodium hydroxide In dimethyl sulfoxide at 120℃; for 48h; Sealed tube;

Reference： [1]Park, In-Hyeok; Medishetty, Raghavender; Kim, Ja-Yeon; Lee, Shim Sung; Vittal, Jagadese J. [Angewandte Chemie - International Edition, 2014, vol. 53, # 22, p. 5591 - 5595][Angew.Chem.Int.Ed, 2014, vol. 126, # 22, p. 5697 - 5701,5]

31
1,4-bis(4-pyridylethenyl)benzene [ No CAS ]
zinc nitrate tetrahydrate [ No CAS ]
[ 2449-35-6 ]
[ 7732-18-5 ]
[ 33513-42-7 ]
[Zn2(bpeb)(sdb)2]·DMF [ No CAS ]

Yield	Reaction Conditions	Operation in experiment
78%	With sodium hydroxide In dimethyl sulfoxide at 120℃; for 48h; Sealed tube;

Reference： [1]Park, In-Hyeok; Medishetty, Raghavender; Kim, Ja-Yeon; Lee, Shim Sung; Vittal, Jagadese J. [Angewandte Chemie - International Edition, 2014, vol. 53, # 22, p. 5591 - 5595][Angew.Chem.Int.Ed, 2014, vol. 126, # 22, p. 5697 - 5701,5]

32
1,4-bis(4-pyridylethenyl)benzene [ No CAS ]
zinc nitrate tetrahydrate [ No CAS ]
[ 2449-35-6 ]
[ 33513-42-7 ]
[Zn2(bpeb)(sdb)2]·DMF·1.5H2O [ No CAS ]

Yield	Reaction Conditions	Operation in experiment
83%	With sodium hydroxide In dimethyl sulfoxide at 130℃; for 48h; Sealed tube;

Reference： [1]Park, In-Hyeok; Medishetty, Raghavender; Kim, Ja-Yeon; Lee, Shim Sung; Vittal, Jagadese J. [Angewandte Chemie - International Edition, 2014, vol. 53, # 22, p. 5591 - 5595][Angew.Chem.Int.Ed, 2014, vol. 126, # 22, p. 5697 - 5701,5]

33
cadmium(II) nitrate tetrhydrate [ No CAS ]
[ 2449-35-6 ]
[ 25372-07-0 ]
Cd⁽²⁺⁾*C₁₄H₈O₆S^(2-)*C₁₂H₁₀N₄ [ No CAS ]

Yield	Reaction Conditions	Operation in experiment
47%	With sodium hydroxide In water at 160℃; for 72h;

Reference： [1]Yang, Bin; Chen, Ning; Tse, Kwong-Ming; Lee, Heow-Pueh [Zeitschrift fur Anorganische und Allgemeine Chemie, 2015, vol. 641, # 3-4, p. 601 - 605]

34
manganese(II) chloride tetrahydrate [ No CAS ]
[ 127-19-5 ]
[ 2449-35-6 ]
[Mn₄(4,4′-sulfonyldibenzoic acid)₄(DMA)₂]*3DMA [ No CAS ]

Yield	Reaction Conditions	Operation in experiment
63%	With formic acid In methanol at 110℃; for 72h; Autoclave;

Reference： [1]Bhattacharya, Saurav; Bhattacharyya, Aninda J.; Natarajan, Srinivasan [Inorganic Chemistry, 2015, vol. 54, # 4, p. 1254 - 1271]

35
aluminium(III) chloride hexahydrate [ No CAS ]
[ 2449-35-6 ]
[ 33513-42-7 ]
[Al(OH)(SDBA)]·0.25DMF [ No CAS ]

Yield	Reaction Conditions	Operation in experiment
98%	Stage #1: aluminium(III) chloride hexahydrate; bis(4-carboxyphenyl)sulfone With sodium hydroxide In water at 150℃; for 12h; Autoclave; Stage #2: N,N-dimethyl-formamide at 150℃; for 1h; Microwave irradiation;

Reference： [1]Reimer, Nele; Reinsch, Helge; Inge, A. Ken; Stock, Norbert [Inorganic Chemistry, 2015, vol. 54, # 2, p. 492 - 501]

36
gadolinium(III) nitrate hexahydrate [ No CAS ]
[ 2449-35-6 ]
[ 33513-42-7 ]
[Gd(4,4'-sulfonyldibenzoate)(NO₃)(dimethylformamide)₂]*H₂O [ No CAS ]

Yield	Reaction Conditions	Operation in experiment
62%	In ethanol at 74.84℃; for 72h; High pressure;	Solvothermal synthesis of I. A reaction mixture of Gd(NO3)3*6H2O (0.015 g, 0.033 mmol), H2Sfdb (0.010 g, 0.033 mmol), DMF (1 mL) and C2H5OH (0.5mL) was stirred for 20 min in air to form a solution, the solution was placed in vial (5 mL), then the vial was sealed and heated at 348 K for three days, followed by slow cooling (5 K/h). The colorless block crystals were washed with DMF and dried in air (the yield was ~62%).

Reference： [1]Zhang; Han [Russian Journal of Coordination Chemistry/Koordinatsionnaya Khimiya, 2015, vol. 41, # 5, p. 334 - 338][Koord. Khim., 2015, vol. 41, # 5, p. 334 - 338,5]

37
nickel(II) nitrate hexahydrate [ No CAS ]
[ 143131-66-2 ]
[ 2449-35-6 ]
C₁₄H₈O₆S^(2-)*C₁₂H₁₂N₆*Ni⁽²⁺⁾*2H₂O [ No CAS ]

Yield	Reaction Conditions	Operation in experiment
56%	With sodium carbonate; In water; at 140℃; for 72h;	A mixture of Ni(NO3)2·6H2O(29.1 mg, 0.1 mmol), H2E1 (30.4 mg, 0.1 mmol), Na2CO3 (10.6 mg, 0.1 mmol), and pbtx (24.0 mg, 0.1 mmol) was dissolved in 10 mL of distilled water. The final mixture was sealed in a 15 mL Parr Teflon-lined stainless-steel vessel and heated at 140 C for three days, and then the reaction system was cooled to room temperature. Green crystals were obtained in 56% (35.8 mg) yield (based on Ni). Elemental analysis (EA) (%) Calcd for(C26H24N6Ni1O8S1): C, 48.84; N, 13.14; H, 3.75. Found: C, 48.77; N, 13.25; H, 3.61.FT-IR(KBr, cm-1): 3379(br), 3114(w), 1601(m), 1550(m), 1396(s), 1280(m), 1166(m),1010(m), 866(w), 744(s), 677(m), 616(m), 488(w).

Reference： [1]Journal of Coordination Chemistry,2015,vol. 68,p. 1676 - 1687

38
cobalt(II) nitrate hexahydrate [ No CAS ]
[ 143131-66-2 ]
[ 2449-35-6 ]
C₁₄H₈O₆S^(2-)*C₁₂H₁₂N₆*Co⁽²⁺⁾*2H₂O [ No CAS ]

Yield	Reaction Conditions	Operation in experiment
56%	With sodium carbonate; In water; at 140℃; for 72h;	A mixture of Co(NO3)2·6H2O (29.1 mg, 0.1 mmol), H2E1 (30.4 mg, 0.1 mmol), Na2CO3 (10.6 mg, 0.1 mmol), and pbtx (24.0 mg, 0.1 mmol) was dissolved in 10 mL of distilled water. The final mixture was sealed in a 15 mL Parr Teflon-lined stainless-steel vessel and heated at 140 C for three days, and then the reaction system was cooled to room temperature. Purple crystals were obtained in 56% (36.1 mg) yield (based on Co). EA (%) Calcd for (C26H24N6Co1O8S1): C,48.83; N, 13.14; H, 4.07. Found: C, 48.93; N, 13.27; H, 3.98. FT-IR(KBr, cm-1): 3449(br),3148(w), 1595(m), 1544(m), 1393(s), 1278(m), 1166(m), 1018(w), 857(w), 748(s), 677(w),615(w), 490(w).

Reference： [1]Journal of Coordination Chemistry,2015,vol. 68,p. 1676 - 1687

39
[ 2449-35-6 ]
1,4-bis(2-methylimidazol-1-ylmethyl)-2,3,5,6-tetramethylbenzene [ No CAS ]
[ 5743-04-4 ]
[Cd(1,4-bis(2-methylimidazol-1-ylmethyl)-2,3,5,6-tetramethylbenzene)(sbda)]_n [ No CAS ]

Yield	Reaction Conditions	Operation in experiment
78%	In water at 150℃; for 96h;	2.2.2. Synthesis of [Cd(bmimx)(bdc)H₂O]_n₍₂₎ General procedure: A mixture of Cd(Ac)2*2H2O (26.7 mg, 0.1 mmol), bmimx (32.3 mg, 0.1 mmol) and H2bdc (16.6 mg, 0.1 mmol) in 10 mL distilled H2O was kept in a 25 mL Teflon-lined stainless steel vessel at 150 °C for four days. After the mixture was cooled to room temperature at a rate of 5 °C/h, colorless crystals of 2 were obtained in a yield of 65% (based on Cd).

Reference： [1]Mu, Ya-Juan; Xie, Ji-Xing; Ran, Yun-Gen; Han, Bo; Qin, Gui-Fang [Polyhedron, 2015, vol. 89, p. 20 - 28]

40
cadmium(II) nitrate hexahydrate [ No CAS ]
[ 2449-35-6 ]
[ 39242-17-6 ]
[Cd(4,4'-sulfonyldibenzoato)(2,6-bis(1-imdazoly)pyridine)]*1.5(H₂O) [ No CAS ]

Yield	Reaction Conditions	Operation in experiment
32%	With sodium hydrogencarbonate; In water; at 160℃; for 72h;Autoclave;	A mixture of Cd(NO3)26H2O (0.030 g, 0.1 mmol), 4,40-H2sdb(0.025 g, 0.1 mmol), NaHCO3 (0.016 g, 0.2 mmol) and H2O (10 mL)was placed in a 23 mL Teflon-lined stainless steel reactor underautogenous pressure at 160 C for 72 h and then cooled to roomtemperature slowly. Colorless block crystals were obtained in 32%yield based on Cd(NO3)24H2O. Anal. calcd. for C50H40Cd2N10O15S2(1309.86): C, 45.81; H, 3.05; N, 10.69%. Found: C, 45.87; H, 3.12; N,10.62%. IR (cm1): 3422(w), 1712(m), 1675(s), 1587(m), 1509(m),1389(m), 1378(m), 1109(w), 1025(w), 958(m), 893(m), 826(m),778(w), 690(w), 674(w), 589(w), 562(w).

Reference： [1]Journal of Molecular Structure,2015,vol. 1100,p. 1 - 5

41
europium(III) nitrate hexahydrate [ No CAS ]
[ 2449-35-6 ]
[ 7732-18-5 ]
3C₁₄H₈O₆S^(2-)*2Eu⁽³⁺⁾*5H₂O [ No CAS ]

Yield	Reaction Conditions	Operation in experiment
56%	In water at 130℃; for 72h; High pressure; Autoclave;	Synthesis of {Eu₂(SDB)₃(H₂O)₅}_n A mixture of Eu(NO3)3·6H2O (222.982 mg, 0.5 mmol), 4,4-sulfonyldibenzoic acid (H2SDB) (153.145 mg, 0.5 mmol), and deionized water (6 mL) was placed in a 23 mL Teflon-lined stainless steel vessel. The mixture was sealed and heated at 130 °C for three days, and then cooled to room temperature at a rate of 5 °C/h. Yellow block-shaped crystals suitable for X-ray analysis were obtained in 56% yield (based on H2SDB). Anal found/Calcd for C42H34S3Eu2O23: C, 38.55; H, 2.65% (calculated: C, 38.59; H, 2.60%). IR (KBr,cm-1): 3433(m), 2364(m), 1435(m), 1408(s), 1377(s), 1300(s), 1098(s), 1019(w), 850(w),777(w), 736(s), 687(w), 613(m), 576(w).