[ CAS No. 24539-92-2 ] {[proInfo.proName]}

Name: 24539-92-2|5-Ethyl-2-hydroxyacetophenone|98%
Brand: Ambeed
SKU: A120558
Price: 18.0 USD
Availability: InStock
Rating: 92 (26 reviews)

,{[proInfo.pro_purity]}

Cat. No.: {[proInfo.prAm]}

DV 2D 3D

3d Animation Molecule Structure of 24539-92-2

Structure of 24539-92-2 * Storage: {[proInfo.prStorage]}

Cart0 Add to My Favorites Add to My Favorites Bulk Inquiry Inquiry Add To Cart

Search after Editing

* Storage: {[proInfo.prStorage]}

For Research Only 110K+ Compounds Competitive Price 1-2 Day Shipping

Quality Control of [ 24539-92-2 ]

COA NMR CNMR HPLC LC-MS

Related Doc. of [ 24539-92-2 ]

SDS Specification

Alternatived Products of [ 24539-92-2 ]

Product Details of [ 24539-92-2 ]

CAS No. :	24539-92-2	MDL No. :	MFCD00053308
Formula :	C₁₀H₁₂O₂	Boiling Point :	-
Linear Structure Formula :	-	InChI Key :	GSTOHKXQBZZTPF-UHFFFAOYSA-N
M.W :	164.20	Pubchem ID :	2758850
Synonyms :

Safety of [ 24539-92-2 ]

Signal Word:	Warning	Class:	N/A
Precautionary Statements:	P261-P305+P351+P338	UN#:	N/A
Hazard Statements:	H302-H315-H319-H335	Packing Group:	N/A
GHS Pictogram:

Application In Synthesis of [ 24539-92-2 ]

* All experimental methods are cited from the reference, please refer to the original source for details. We do not guarantee the accuracy of the content in the reference.

Upstream synthesis route of [ 24539-92-2 ]
Downstream synthetic route of [ 24539-92-2 ]

[ 24539-92-2 ] Synthesis Path-Upstream 1~1

1
[ 24539-92-2 ]
[ 29976-82-7 ]

Reference： [1] Journal of Medicinal Chemistry, 2002, vol. 45, # 19, p. 4188 - 4201

Same Skeleton Products

Related Products

Historical Records

Related Functional Groups of
[ 24539-92-2 ]

Aryls

[ 55108-28-6 ]

1,1'-(2-Hydroxy-5-methyl-1,3-phenylene)diethanone

Similarity: 1.00

[ 55108-29-7 ]

3-Acetyl-2-hydroxybenzaldehyde

Similarity: 1.00

[ 1198-66-9 ]

3',5'-Dimethyl-2'-hydroxyacetophenone

Similarity: 1.00

[ 118-93-4 ]

2'-Hydroxyacetophenone

Similarity: 1.00

[ 699-91-2 ]

2'-Hydroxy-3'-methylacetophenone

Similarity: 1.00

Ketones

[ 55108-28-6 ]

1,1'-(2-Hydroxy-5-methyl-1,3-phenylene)diethanone

Similarity: 1.00

[ 55108-29-7 ]

3-Acetyl-2-hydroxybenzaldehyde

Similarity: 1.00

[ 1198-66-9 ]

3',5'-Dimethyl-2'-hydroxyacetophenone

Similarity: 1.00

[ 118-93-4 ]

2'-Hydroxyacetophenone

Similarity: 1.00

[ 699-91-2 ]

2'-Hydroxy-3'-methylacetophenone

Similarity: 1.00

Purity	Size	Price	VIP Price	USA Stock *0-1 Day	Global Stock *5-7 Days	Quantity
{[ item.p_purity ]}	{[ item.pr_size ]}	{[ getRatePrice(item.pr_usd, 1,1) ]} {[ getRatePrice(item.pr_usd,item.pr_rate,item.mem_rate) ]}	{[ getRatePrice(item.pr_usd, 1,1) ]}	Inquiry {[ getRatePrice(item.pr_usd,item.pr_rate,item.mem_rate) ]} {[ getRatePrice(item.pr_usd,1,item.mem_rate) ]}	{[ item.pr_usastock ]}	Inquiry -	{[ item.pr_chinastock ]}	Inquiry -

Yield	Reaction Conditions	Operation in experiment
96%	With aluminium trichloride 1.) 70 -> 80 deg C, 2 h, 2.) 120 deg C, 40 min;
90%	With aluminium trichloride
66.7%	With aluminum (III) chloride at 130℃; for 2h;	22 Intermediate 55: 1 -(5-ethyl-2-hydroxyphenyl)ethanone To aluminium trichloride (5.07 g, 38.0 mmol) was added 4-ethylphenyl acetate (3.28 g, 20 mmol) dropwise. The mixture was heated to 130 °C for 120 minutes then cooled. The yellow oil was slowly poured into water and extracted with EtOAc (2x80 ml). The combined organic layers were washed with brine, then dried over MgS04 and concentrated in vacuo to give a yellow oil. The oil was purified by silica gel chromatography (hexane/EtOAc = 10/1 ) to obtain the title compound 1 -(5-ethyl-2-hydroxyphenyl)ethanone (2.33 g, 13.34 mmol, 66.7 % yield) as a pale yellow oil. m/z: [M + H]+ Calcd for C10H13O2 165.1 ; Found 164

20.1%	With aluminum (III) chloride In dichloromethane for 10h; Cooling with ice; Reflux;
	With aluminium trichloride
	With aluminium trichloride at 140℃; for 0.25h; Yield given;
	With aluminium trichloride
	Stage #1: p-ethylphenyl acetate With aluminum (III) chloride at 120℃; for 6h; Stage #2: With water Cooling;	2 Synthesis of substituted o-hydroxyacetophenone General procedure: Powdered anhydrous AlCl3 (186 g, 1.4 mol) was added little by little to acetic acid phenyl ester b1 (95.3 g, 0.7 mol) in a round-bottomed flask in an ice-water bath. The resultant mixture was heated to 120 °C for 6 h in an oil bath. Then the reaction mixture was added a lot of crushed ice for hydrolysis. The new formed organic layer in the reaction mixture was extracted by EtOAc, dried over anhydrous Na2SO4, and filtered off by suction filtration. The solvent was removed under reduced pressure to give the crude product, which was then purified by chromatography on silica using petroleum ether/ethyl acetate as the eluent. o-hydroxyacetophenone c1 (20.1 g, 21%) was obtained
	With aluminum (III) chloride at 120℃;
		77.a 6-Ethyl-4-(N-Ethylsulfonyl-N-Methyl)Amino-2,2-Dimethyl-Chroman a) 5-Ethyl-2-hydroxyacetophenone is obtained analogously to the procedure indicated in Example 63 b) from 4-ethylphenyl acetate and anhydrous, active aluminum chloride. Slightly yellowish-colored oil.

Yield	Reaction Conditions	Operation in experiment
85%	With nitric acid In acetic acid for 2.5h; Ambient temperature;
44%	With sulfuric acid; nitric acid at -20℃;
	With sulfuric acid; nitric acid

Yield	Reaction Conditions	Operation in experiment
86%	With pyridine; hydroxylamine hydrochloride In methanol for 5h; Heating;
	With pyridine; hydroxylamine hydrochloride

[ CAS No. 24539-92-2 ] {[proInfo.proName]}

Quality Control of [ 24539-92-2 ]

Related Doc. of [ 24539-92-2 ]

Product Details of [ 24539-92-2 ]

Safety of [ 24539-92-2 ]

Application In Synthesis of [ 24539-92-2 ]

[ 24539-92-2 ] Synthesis Path-Upstream 1~1

[ 24539-92-2 ] Synthesis Path-Downstream 1~53

Related Functional Groups of
[ 24539-92-2 ]

Aryls

Ketones

Precautionary Statements-General

Prevention

Response

Storage

Disposal

Physical hazards

Health hazards

Environmental hazards

Inquiry

Yield	Reaction Conditions	Operation in experiment
	Multi-step reaction with 2 steps 1: pyridine 2: AlCl₃
	Multi-step reaction with 2 steps 1: 95 percent / NaOH 2: 90 percent / AlCl₃
	Multi-step reaction with 2 steps 1.1: sulfuric acid / 0.17 h / 20 °C 2.1: aluminum (III) chloride / 6 h / 120 °C 2.2: Cooling

	Multi-step reaction with 2 steps 1: sulfuric acid / 20 °C 2: aluminum (III) chloride / 120 °C
	Multi-step reaction with 2 steps 1: sulfuric acid / 0.33 h / 20 °C 2: aluminum (III) chloride / dichloromethane / 10 h / Cooling with ice; Reflux
	Multi-step reaction with 2 steps 1: acetic anhydride

Yield	Reaction Conditions	Operation in experiment
	Multi-step reaction with 7 steps 1: 96 percent / tetrahydrofuran / 0 deg C, 5 min and 65 deg C, 20 min 2: 47 percent / TFA / CH₂Cl₂ / 0 deg C and room t., 30 min 3: 70 percent / 65percent HNO₃ / hexane / 2 h / Ambient temperature 4: 88 percent / 2,4,6-collidine / CH₂Cl₂ / 0.42 h / -50 °C 5: 83 percent / LiCl, Et₃N / Cl₂Pd(PPh₃)2 / acetonitrile; H₂O / within 30 min to 70 deg C and 1 h, 70 deg C 6: 14 percent / tetrahydrofuran / 0.42 h / -50 °C 7: 80 percent / H₂ / 10percent Pd/C / methanol / 22 h / Ambient temperature
	Multi-step reaction with 7 steps 1: 96 percent / tetrahydrofuran / 0 deg C, 5 min and 65 deg C, 20 min 2: 47 percent / TFA / CH₂Cl₂ / 0 deg C and room t., 30 min 3: 70 percent / 65percent HNO₃ / hexane / 2 h / Ambient temperature 4: 88 percent / 2,4,6-collidine / CH₂Cl₂ / 0.42 h / -50 °C 5: 32 percent / Ph₃P, Et₄NCl, Et₃N / Pd(OAc)2, Ph₃P / H₂O; acetonitrile / 15 min, room t. and 40 min, 50 deg C 6: 14 percent / tetrahydrofuran / 0.42 h / -50 °C 7: 80 percent / H₂ / 10percent Pd/C / methanol / 22 h / Ambient temperature
	Multi-step reaction with 7 steps 1: 96 percent / tetrahydrofuran / 0 deg C, 5 min and 65 deg C, 20 min 2: 35 percent / TFA / CH₂Cl₂ / 0 deg C and room t., 30 min 3: 70 percent / 65percent HNO₃ / acetic acid / 2 h / Ambient temperature 4: 88 percent / 2,4,6-collidine / CH₂Cl₂ / 0.42 h / -50 °C 5: 83 percent / LiCl, Et₃N / Cl₂Pd(PPh₃)2 / acetonitrile; H₂O / within 30 min to 70 deg C and 1 h, 70 deg C 6: 14 percent / tetrahydrofuran / 0.42 h / -50 °C 7: 80 percent / H₂ / 10percent Pd/C / methanol / 22 h / Ambient temperature

Yield	Reaction Conditions	Operation in experiment
	Multi-step reaction with 6 steps 1: 96 percent / tetrahydrofuran / 0 deg C, 5 min and 65 deg C, 20 min 2: 47 percent / TFA / CH₂Cl₂ / 0 deg C and room t., 30 min 3: 70 percent / 65percent HNO₃ / hexane / 2 h / Ambient temperature 4: 88 percent / 2,4,6-collidine / CH₂Cl₂ / 0.42 h / -50 °C 5: 42 percent / Ph₃P, Et₄NCl, Et₃N / Pd(OAc)2, Ph₃P / H₂O; acetonitrile / 15 min, room t. and 40 min, 50 deg C 6: 10 percent / tetrahydrofuran / 0.42 h / -50 °C
	Multi-step reaction with 6 steps 1: 96 percent / tetrahydrofuran / 0 deg C, 5 min and 65 deg C, 20 min 2: 35 percent / TFA / CH₂Cl₂ / 0 deg C and room t., 30 min 3: 70 percent / 65percent HNO₃ / acetic acid / 2 h / Ambient temperature 4: 88 percent / 2,4,6-collidine / CH₂Cl₂ / 0.42 h / -50 °C 5: 42 percent / Ph₃P, Et₄NCl, Et₃N / Pd(OAc)2, Ph₃P / H₂O; acetonitrile / 15 min, room t. and 40 min, 50 deg C 6: 10 percent / tetrahydrofuran / 0.42 h / -50 °C
	Multi-step reaction with 6 steps 1: 96 percent / tetrahydrofuran / 0 deg C, 5 min and 65 deg C, 20 min 2: 47 percent / Et₃SiH, TFA / CH₂Cl₂ / 0 deg C and room t., 30 min 3: 70 percent / 65percent HNO₃ / hexane / 2 h / Ambient temperature 4: 88 percent / 2,4,6-collidine / CH₂Cl₂ / 0.42 h / -50 °C 5: 42 percent / Ph₃P, Et₄NCl, Et₃N / Pd(OAc)2, Ph₃P / H₂O; acetonitrile / 15 min, room t. and 40 min, 50 deg C 6: 10 percent / tetrahydrofuran / 0.42 h / -50 °C

Yield	Reaction Conditions	Operation in experiment
	Multi-step reaction with 5 steps 1: 96 percent / tetrahydrofuran / 0 deg C, 5 min and 65 deg C, 20 min 2: 47 percent / TFA / CH₂Cl₂ / 0 deg C and room t., 30 min 3: 70 percent / 65percent HNO₃ / hexane / 2 h / Ambient temperature 4: 88 percent / 2,4,6-collidine / CH₂Cl₂ / 0.42 h / -50 °C 5: 83 percent / LiCl, Et₃N / Cl₂Pd(PPh₃)2 / acetonitrile; H₂O / within 30 min to 70 deg C and 1 h, 70 deg C
	Multi-step reaction with 5 steps 1: 96 percent / tetrahydrofuran / 0 deg C, 5 min and 65 deg C, 20 min 2: 47 percent / TFA / CH₂Cl₂ / 0 deg C and room t., 30 min 3: 70 percent / 65percent HNO₃ / hexane / 2 h / Ambient temperature 4: 88 percent / 2,4,6-collidine / CH₂Cl₂ / 0.42 h / -50 °C 5: 32 percent / Ph₃P, Et₄NCl, Et₃N / Pd(OAc)2, Ph₃P / H₂O; acetonitrile / 15 min, room t. and 40 min, 50 deg C
	Multi-step reaction with 5 steps 1: 96 percent / tetrahydrofuran / 0 deg C, 5 min and 65 deg C, 20 min 2: 35 percent / TFA / CH₂Cl₂ / 0 deg C and room t., 30 min 3: 70 percent / 65percent HNO₃ / acetic acid / 2 h / Ambient temperature 4: 88 percent / 2,4,6-collidine / CH₂Cl₂ / 0.42 h / -50 °C 5: 83 percent / LiCl, Et₃N / Cl₂Pd(PPh₃)2 / acetonitrile; H₂O / within 30 min to 70 deg C and 1 h, 70 deg C

Yield	Reaction Conditions	Operation in experiment
	Multi-step reaction with 3 steps 1: 96 percent / tetrahydrofuran / 0 deg C, 5 min and 65 deg C, 20 min 2: 47 percent / TFA / CH₂Cl₂ / 0 deg C and room t., 30 min 3: 70 percent / 65percent HNO₃ / hexane / 2 h / Ambient temperature
	Multi-step reaction with 3 steps 1: 96 percent / tetrahydrofuran / 0 deg C, 5 min and 65 deg C, 20 min 2: 35 percent / TFA / CH₂Cl₂ / 0 deg C and room t., 30 min 3: 70 percent / 65percent HNO₃ / acetic acid / 2 h / Ambient temperature
	Multi-step reaction with 3 steps 1: 96 percent / tetrahydrofuran / 0 deg C, 5 min and 65 deg C, 20 min 2: 47 percent / Et₃SiH, TFA / CH₂Cl₂ / 0 deg C and room t., 30 min 3: 70 percent / 65percent HNO₃ / hexane / 2 h / Ambient temperature

Yield	Reaction Conditions	Operation in experiment
	Multi-step reaction with 4 steps 1: 96 percent / tetrahydrofuran / 0 deg C, 5 min and 65 deg C, 20 min 2: 47 percent / TFA / CH₂Cl₂ / 0 deg C and room t., 30 min 3: 70 percent / 65percent HNO₃ / hexane / 2 h / Ambient temperature 4: 88 percent / 2,4,6-collidine / CH₂Cl₂ / 0.42 h / -50 °C
	Multi-step reaction with 4 steps 1: 96 percent / tetrahydrofuran / 0 deg C, 5 min and 65 deg C, 20 min 2: 35 percent / TFA / CH₂Cl₂ / 0 deg C and room t., 30 min 3: 70 percent / 65percent HNO₃ / acetic acid / 2 h / Ambient temperature 4: 88 percent / 2,4,6-collidine / CH₂Cl₂ / 0.42 h / -50 °C
	Multi-step reaction with 4 steps 1: 96 percent / tetrahydrofuran / 0 deg C, 5 min and 65 deg C, 20 min 2: 47 percent / Et₃SiH, TFA / CH₂Cl₂ / 0 deg C and room t., 30 min 3: 70 percent / 65percent HNO₃ / hexane / 2 h / Ambient temperature 4: 88 percent / 2,4,6-collidine / CH₂Cl₂ / 0.42 h / -50 °C

Yield	Reaction Conditions	Operation in experiment
	Multi-step reaction with 4 steps 1: 44 percent / conc. HNO₃, conc. H₂SO₄ / -20 °C 2: 60 percent / H₂ / 5percent Pd/C / ethanol 3: pyridine / CH₂Cl₂ / 1 h / 20 °C 4: 82 percent / H₂, CH₃COOH / 5percent Pd/C / 20 °C / 3102.9 Torr
	Multi-step reaction with 4 steps 1: 44 percent / conc. HNO₃, conc. H₂SO₄ / -20 °C 2: 60 percent / H₂ / 5percent Pd/C / ethanol 3: pyridine / CH₂Cl₂ / 1 h / 20 °C 4: 70 percent / CF₃COOH / 0.5 h / Heating
	Multi-step reaction with 4 steps 1: 44 percent / conc. HNO₃, conc. H₂SO₄ / -20 °C 2: 60 percent / H₂ / 5percent Pd/C / ethanol 3: pyridine / CH₂Cl₂ / 1 h / 20 °C 4: 13 percent / H₂, CH₃COOH / 5percent Pd/C / 20 °C / 3102.9 Torr

Yield	Reaction Conditions	Operation in experiment
	Multi-step reaction with 2 steps 1: 44 percent / conc. HNO₃, conc. H₂SO₄ / -20 °C 2: 60 percent / H₂ / 5percent Pd/C / ethanol
	Multi-step reaction with 2 steps 1: sulfuric acid; nitric acid 2: hydrogen / palladium on activated charcoal / ethanol

Yield	Reaction Conditions	Operation in experiment
	Multi-step reaction with 3 steps 1: 44 percent / conc. HNO₃, conc. H₂SO₄ / -20 °C 2: 60 percent / H₂ / 5percent Pd/C / ethanol 3: diethyl ether / 1 h / 0 °C
	Multi-step reaction with 3 steps 1: sulfuric acid; nitric acid 2: hydrogen / palladium on activated charcoal / ethanol 3: diethyl ether

Yield	Reaction Conditions	Operation in experiment
	Multi-step reaction with 3 steps 1: 1.) NaH; 2.) LDA / 1.) THF; 2.) THF, -78 deg C, 15 min. 2: 90 percent / NaOMe / ethanol / 19 h / Heating 3: 1.) Et₃N, CH₃SO₂Cl; 2.) LiAlH₄ / 1.) THF, -23 deg C, 1 h; 2.) ether, room temp., 2 h
	Multi-step reaction with 4 steps 1: 1) NaH / 1) THF, 2a) THF, -78 deg C, 15 min, 2b) -78 deg C to RT 2: 90 percent / NaOEt / ethanol / 19 h / Heating 3: NEt₃ / tetrahydrofuran / -20 °C 4: LiAlH₄ / diethyl ether / Ambient temperature

Yield	Reaction Conditions	Operation in experiment
20%	With dmap In 1,2-dichloro-benzene at 130℃; for 8h;	Compound 172: 1-[2-(6,7-Dimethoxy-quinolin-4-yloxy)-5-ethylphenyl]-ethanone Compound 172: 1-[2-(6,7-Dimethoxy-quinolin-4-yloxy)-5-ethylphenyl]-ethanone; 3-Ethyl-6-hydroxyacetophenone (341 mg), 4-chloro-6,7-dimethoxyquinoline (154 mg), and 4-dimethylaminopyridine (254 mg) were suspended in o-dichlorobenzene (6.5 ml), and the suspension was stirred at 130°C for 8 hr. The reaction solution was cooled to room temperature, water was then added to the reaction solution, and the mixture was extracted with ethyl acetate. The ethyl acetate layer was then washed with water and saturated brine and was dried over anhydrous sodium sulfate. The solvent was removed therefrom by distillation under the reduced pressure, and the residue was purified by thin layer chromatography using acetone-hexane to give the title compound (48 mg, yield 20%). 1H-NMR (CDCl3, 400 MHz): δ 1.21 (t, J = 7.6 Hz, 3H), 2.44 (s, 3H), 2.65 (q, J = 7.6 Hz, 2H), 3.96 (s, 3H), 3.97 (s, 3H), 6.35 (d, J = 5.6 Hz, 1H), 7.00 (d, J = 8.0 Hz, 1H), 7.32 - 7.37 (m, 2H), 7.48 (s, 1H), 7.67 (s, 1H), 8.42 (d, J = 5.6 Hz, 1H) Mass spectrometric value (ESI-MS, m/z): 352 (M+1)+
20%	With dmap In 1,2-dichloro-benzene at 160℃;

Yield	Reaction Conditions	Operation in experiment
20%	With trichlorophosphate at 0 - 20℃;	3 Synthesis of 6-substituted 4-oxo-4H-chromene-3-carbaldehydes General procedure: POCl3 (112.6 g, 0.72 mol) was added slowly to a well stirred and cooled (0-5 °C) mixture of N,N-dimethylformamide (53.6 g, 0.72 mol), o-hydroxyacetophenone c1 (20.1 g, 0.14 mol) for 30 min. The ice bath was removed and the mixture was further stirred for 8-12 h at room temperature. The orange-yellow colored organic mass was poured into crushed ice (400 g) with stirring, extracted with EtOAc (8 * 50 mL) and the layers were separated. The organic layer was dried over anhydrous Na2SO4 and the solvent was removed under reduced pressure. Thus obtained residue was subjected to column chromatography purification on silica gel .
	With trichlorophosphate at 20℃;
	With trichlorophosphate at 80℃; for 12h;

Precautionary Statements-General
Code	Phrase
P101	If medical advice is needed,have product container or label at hand.
P102	Keep out of reach of children.
P103	Read label before use
Prevention
Code	Phrase
P201	Obtain special instructions before use.
P202	Do not handle until all safety precautions have been read and understood.
P210	Keep away from heat/sparks/open flames/hot surfaces. - No smoking.
P211	Do not spray on an open flame or other ignition source.
P220	Keep/Store away from clothing/combustible materials.
P221	Take any precaution to avoid mixing with combustibles
P222	Do not allow contact with air.
P223	Keep away from any possible contact with water, because of violent reaction and possible flash fire.
P230	Keep wetted
P231	Handle under inert gas.
P232	Protect from moisture.
P233	Keep container tightly closed.
P234	Keep only in original container.
P235	Keep cool
P240	Ground/bond container and receiving equipment.
P241	Use explosion-proof electrical/ventilating/lighting/equipment.
P242	Use only non-sparking tools.
P243	Take precautionary measures against static discharge.
P244	Keep reduction valves free from grease and oil.
P250	Do not subject to grinding/shock/friction.
P251	Pressurized container: Do not pierce or burn, even after use.
P260	Do not breathe dust/fume/gas/mist/vapours/spray.
P261	Avoid breathing dust/fume/gas/mist/vapours/spray.
P262	Do not get in eyes, on skin, or on clothing.
P263	Avoid contact during pregnancy/while nursing.
P264	Wash hands thoroughly after handling.
P265	Wash skin thouroughly after handling.
P270	Do not eat, drink or smoke when using this product.
P271	Use only outdoors or in a well-ventilated area.
P272	Contaminated work clothing should not be allowed out of the workplace.
P273	Avoid release to the environment.
P280	Wear protective gloves/protective clothing/eye protection/face protection.
P281	Use personal protective equipment as required.
P282	Wear cold insulating gloves/face shield/eye protection.
P283	Wear fire/flame resistant/retardant clothing.
P284	Wear respiratory protection.
P285	In case of inadequate ventilation wear respiratory protection.
P231 + P232	Handle under inert gas. Protect from moisture.
P235 + P410	Keep cool. Protect from sunlight.
Response
Code	Phrase
P301	IF SWALLOWED:
P304	IF INHALED:
P305	IF IN EYES:
P306	IF ON CLOTHING:
P307	IF exposed:
P308	IF exposed or concerned:
P309	IF exposed or if you feel unwell:
P310	Immediately call a POISON CENTER or doctor/physician.
P311	Call a POISON CENTER or doctor/physician.
P312	Call a POISON CENTER or doctor/physician if you feel unwell.
P313	Get medical advice/attention.
P314	Get medical advice/attention if you feel unwell.
P315	Get immediate medical advice/attention.
P320
P302 + P352	IF ON SKIN: wash with plenty of soap and water.
P321
P322
P330	Rinse mouth.
P331	Do NOT induce vomiting.
P332	IF SKIN irritation occurs:
P333	If skin irritation or rash occurs:
P334	Immerse in cool water/wrap n wet bandages.
P335	Brush off loose particles from skin.
P336	Thaw frosted parts with lukewarm water. Do not rub affected area.
P337	If eye irritation persists:
P338	Remove contact lenses, if present and easy to do. Continue rinsing.
P340	Remove victim to fresh air and keep at rest in a position comfortable for breathing.
P341	If breathing is difficult, remove victim to fresh air and keep at rest in a position comfortable for breathing.
P342	If experiencing respiratory symptoms:
P350	Gently wash with plenty of soap and water.
P351	Rinse cautiously with water for several minutes.
P352	Wash with plenty of soap and water.
P353	Rinse skin with water/shower.
P360	Rinse immediately contaminated clothing and skin with plenty of water before removing clothes.
P361	Remove/Take off immediately all contaminated clothing.
P362	Take off contaminated clothing and wash before reuse.
P363	Wash contaminated clothing before reuse.
P370	In case of fire:
P371	In case of major fire and large quantities:
P372	Explosion risk in case of fire.
P373	DO NOT fight fire when fire reaches explosives.
P374	Fight fire with normal precautions from a reasonable distance.
P376	Stop leak if safe to do so. Oxidising gases (section 2.4) 1
P377	Leaking gas fire: Do not extinguish, unless leak can be stopped safely.
P378
P380	Evacuate area.
P381	Eliminate all ignition sources if safe to do so.
P390	Absorb spillage to prevent material damage.
P391	Collect spillage. Hazardous to the aquatic environment
P301 + P310	IF SWALLOWED: Immediately call a POISON CENTER or doctor/physician.
P301 + P312	IF SWALLOWED: call a POISON CENTER or doctor/physician IF you feel unwell.
P301 + P330 + P331	IF SWALLOWED: Rinse mouth. Do NOT induce vomiting.
P302 + P334	IF ON SKIN: Immerse in cool water/wrap in wet bandages.
P302 + P350	IF ON SKIN: Gently wash with plenty of soap and water.
P303 + P361 + P353	IF ON SKIN (or hair): Remove/Take off Immediately all contaminated clothing. Rinse SKIN with water/shower.
P304 + P312	IF INHALED: Call a POISON CENTER or doctor/physician if you feel unwell.
P304 + P340	IF INHALED: Remove victim to fresh air and Keep at rest in a position comfortable for breathing.
P304 + P341	IF INHALED: If breathing is difficult, remove victim to fresh air and keep at rest in a position comfortable for breathing.
P305 + P351 + P338	IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.
P306 + P360	IF ON CLOTHING: Rinse Immediately contaminated CLOTHING and SKIN with plenty of water before removing clothes.
P307 + P311	IF exposed: call a POISON CENTER or doctor/physician.
P308 + P313	IF exposed or concerned: Get medical advice/attention.
P309 + P311	IF exposed or if you feel unwell: call a POISON CENTER or doctor/physician.
P332 + P313	IF SKIN irritation occurs: Get medical advice/attention.
P333 + P313	IF SKIN irritation or rash occurs: Get medical advice/attention.
P335 + P334	Brush off loose particles from skin. Immerse in cool water/wrap in wet bandages.
P337 + P313	IF eye irritation persists: Get medical advice/attention.
P342 + P311	IF experiencing respiratory symptoms: call a POISON CENTER or doctor/physician.
P370 + P376	In case of fire: Stop leak if safe to Do so.
P370 + P378	In case of fire:
P370 + P380	In case of fire: Evacuate area.
P370 + P380 + P375	In case of fire: Evacuate area. Fight fire remotely due to the risk of explosion.
P371 + P380 + P375	In case of major fire and large quantities: Evacuate area. Fight fire remotely due to the risk of explosion.
Storage
Code	Phrase
P401
P402	Store in a dry place.
P403	Store in a well-ventilated place.
P404	Store in a closed container.
P405	Store locked up.
P406	Store in corrosive resistant/ container with a resistant inner liner.
P407	Maintain air gap between stacks/pallets.
P410	Protect from sunlight.
P411
P412	Do not expose to temperatures exceeding 50 oC/ 122 oF.
P413
P420	Store away from other materials.
P422
P402 + P404	Store in a dry place. Store in a closed container.
P403 + P233	Store in a well-ventilated place. Keep container tightly closed.
P403 + P235	Store in a well-ventilated place. Keep cool.
P410 + P403	Protect from sunlight. Store in a well-ventilated place.
P410 + P412	Protect from sunlight. Do not expose to temperatures exceeding 50 oC/122oF.
P411 + P235	Keep cool.
Disposal
Code	Phrase
P501	Dispose of contents/container to ...
P502	Refer to manufacturer/supplier for information on recovery/recycling

[ CAS No. 24539-92-2 ] {[proInfo.proName]}

Quality Control of [ 24539-92-2 ]

Related Doc. of [ 24539-92-2 ]

Product Details of [ 24539-92-2 ]

Safety of [ 24539-92-2 ]

Application In Synthesis of [ 24539-92-2 ]

[ 24539-92-2 ] Synthesis Path-Upstream 1~1

[ 24539-92-2 ] Synthesis Path-Downstream 1~53

Related Functional Groups of [ 24539-92-2 ]

Aryls

Ketones

Precautionary Statements-General

Prevention

Response

Storage

Disposal

Physical hazards

Health hazards

Environmental hazards

Inquiry

Related Functional Groups of
[ 24539-92-2 ]