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type | HazMat fee |
Excepted Quantity | Free |
Inaccessible (Haz class 6.1), Domestic | USD 41.00 |
Inaccessible (Haz class 6.1), International | USD 64.00 |
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Purity | Size | Price | VIP Price | USA Stock *0-1 Day | Global Stock *5-7 Days | Quantity | |||||
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* Storage: {[proInfo.prStorage]}
CAS No. : | 24966-39-0 | MDL No. : | MFCD00004833 |
Formula : | C6H4Cl2S | Boiling Point : | - |
Linear Structure Formula : | - | InChI Key : | N/A |
M.W : | 179.07 g/mol | Pubchem ID : | - |
Synonyms : |
|
Signal Word: | Danger | Class: | 6.1 |
Precautionary Statements: | P501-P261-P270-P271-P264-P280-P337+P313-P305+P351+P338-P361+P364-P332+P313-P301+P310+P330-P302+P352+P312-P304+P340+P311-P403+P233-P405 | UN#: | 2811 |
Hazard Statements: | H301+H311+H331-H315-H319 | Packing Group: | Ⅲ |
GHS Pictogram: |
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Yield | Reaction Conditions | Operation in experiment |
---|---|---|
80% | With N-chloro-succinimide; potassium acetate In dichloromethane | a) 2,6-dichlorobenzenesulfonyl chloride Into a mixture of 200 milliliters (hereinafter "mL") of acetic acid, water and dichloromethane (3/1/4, v/v/v), 2,6 dichlorobenzenethiol (10.0 grams (hereinafter "g"), 55.8 millimoles (hereinafter "mmol"), N-chlorosuccinimide (37.28 g, 279 mmol) and potassium acetate (2.29 g, 27.9 mmol) were added. The resulting mixture was stirred at 0° C., then warmed to room temperature overnight. The mixture was then diluted with 200 mL of dichloromethane, and washed with water (100 mL*3). The organic layer was dried (Na2SO4) and concentrated to give the desired product (11 g, 80percent). 1H NMR (CDCl3): δ7.57 (d, 2H), 7.47 (t, 1H). |
80% | With N-chloro-succinimide; potassium acetate In dichloromethane | a 2,6-dichlorobenzenesulfonyl chloride Into a mixture of 200 milliliters (hereinafter "mL") of acetic acid, water and dichloromethane (3/1/4, v/v/v), 2,6 dichlorobenzenethiol (10.0 grams (hereinafter "g"), 55.8 millimoles (hereinafter "mmol"), N-chlorosuccinimide (37.28 g, 279 mmol) and potassium acetate (2.29 g, 27.9 mmol) were added. The resulting mixture was stirred at 0° C., then warmed to room temperature overnight. The mixture was then diluted with 200 mL of dichloromethane, and washed with water (100 mL*3). The organic layer was dried (Na2SO4) and concentrated to give the desired product (11 g, 80percent). 1H NMR (CDCl3): δ 7.57 (d, 2H), 7.47 (t, 1H). |
Yield | Reaction Conditions | Operation in experiment |
---|---|---|
48% | In xylene at 145 - 170℃; |
Yield | Reaction Conditions | Operation in experiment |
---|---|---|
55% | With palladium diacetate In tetrahydrofuran at 67℃; |
Yield | Reaction Conditions | Operation in experiment |
---|---|---|
97% | With sodium hydroxide In water; isopropyl alcohol 1.) 0 deg C, 10 min, 2.) rt, 2 h; |
Yield | Reaction Conditions | Operation in experiment |
---|---|---|
96% | With ammonia In ethanol a) 50 deg C, b) room temp., 2 h; |
Yield | Reaction Conditions | Operation in experiment |
---|---|---|
98% | With sodium perborate In methanol; water for 2h; Ambient temperature; | |
98% | With dihydrogen peroxide In water; ethyl acetate at 20℃; for 0.583333h; Green chemistry; | General procedure for the oxidation of thiols to disulfides General procedure: In another study, a mixture of the VO-AMPD(at)SBA-15 (0.004 g), thiol (1 mmol) and H2O2 (0.4 mL) was stirred at room temperature in ethyl acetate (2 mL). The progress was monitored by TLC. After completion of the reaction, VO-AMPD(at)SBA-15 catalyst was separated from the mixture by filtration. Then products were extracted with ethyl acetate and dried, and the solvent was removed to give the pure disulfides. |
97% | With nitrourea In dichloromethane at 20℃; for 0.85h; chemoselective reaction; |
95% | With urea hydrogen peroxide adduct In ethanol at 20℃; for 0.6h; | Typical procedure for the synthesis of disulfides catalyzed by Co(at)MCM-41 or Fe(at)MCM-41: as a typical procedure General procedure: A mixture of thiols (1 mmol), UHP (5 mmol), and Co orFeMCM-41 (20 mg) was stirred at room temperature inethanol and the progress of the reaction was monitored by TLC.After completion of the reaction, the catalyst was removed andthe products were extracted with CH2Cl2 (3 × 10 mL). Theresults are shown in Table 7. |
95% | With urea hydrogen peroxide adduct In ethanol at 20℃; for 0.4h; | General procedure for oxidative coupling of thiols to disulfides with UHP catalyzed by Cr-MCM-41 and Mn-MCM-41 General procedure: Thiols ((1 mmol), 5 mmol UHP, and 4 mL acetone as solvent along with 25 mg catalyst were added to a 10-mL two-necked flask equipped with a stirrer. The progress of the reaction was monitored by TLC. After completion of the reaction, the catalyst was removed and the pure products were extracted with CH2Cl2(3 9 10 mL). The results are presented in Table 6. |
94% | With sodium periodate In water at 20℃; for 0.0333333h; | |
94% | With urea hydrogen peroxide adduct In acetonitrile at 20℃; for 0.35h; | |
93% | With dihydrogen peroxide In acetonitrile at 20℃; for 0.666667h; Green chemistry; | |
92% | With [Mn(III)(BHBPDI)Cl]; oxygen In ethanol at 20℃; for 4h; | |
92% | With dihydrogen peroxide In ethanol at 20℃; for 0.75h; Green chemistry; | General procedure for the oxidative coupling of thiols to the disulfides General procedure: A mixture of thiol (1 mmol), hydrogen peroxide (0.5 mL) and the catalyst (0.005 g) in ethanol (2 mL) was stirred at ambient temperature. Reaction progress was monitored by TLC (acetone: n-hexane, 2:8). After completion of the reaction, catalyst was separated by an external magnet and washed with ethyl acetate; next, the product was extracted with ethyl acetate (5 mL 9 4). The organic layer was dried over anhydrous Na2SO4 (1.5 g). Finally, the organic solvents were evaporated, and the corresponding disulfides were obtained in high to excellent yields (88-98%). |
91% | With dimethyl sulfoxide at 80 - 90℃; for 4h; | 4.6. General preparation of disulfides (9{z}) General procedure: An equimolar mixture of thiophenol (10{z}) and DMSO was heated at 80-90 °C for 4 h. The reaction was cooled to room temperature, diethyl ether was added and washed with water (×5). The organic phase was dried over anhydrous magnesium sulfate and evaporated to dryness in vacuo to give (9{z}). |
91% | With 1,3-dibromo-5,5-dimethylimidazolidine-2,4-dione In chloroform at 25℃; for 0.0833333h; | |
88% | With bis(4-methoxyphenyl)telluride; 5,15,10,20-tetraphenylporphyrin In dichloromethane at 0℃; for 0.25h; Irradiation; | |
85% | With sodium hydrogensulfite; periodic acid In water at 20℃; for 1.66667h; | |
71% | With melamine hydrogen peroxide In acetonitrile for 0.17h; Reflux; | |
With iodine In methanol | ||
With [K.18-crown-6][Br3]n In acetonitrile at 20℃; | ||
With 3,6-bis(dimethylamino)-9-(2,4,6-trimethylphenyl)-9H-telluroxanthen-9-ylium hexafluorophosphate; oxygen In chloroform-d1; water for 2h; Irradiation; |
Yield | Reaction Conditions | Operation in experiment |
---|---|---|
87% | With 1,8-diazabicyclo[5.4.0]undec-7-ene In acetonitrile at 50℃; for 1h; |
Yield | Reaction Conditions | Operation in experiment |
---|---|---|
With 1,8-diazabicyclo[5.4.0]undec-7-ene In acetonitrile at 50℃; |
Yield | Reaction Conditions | Operation in experiment |
---|---|---|
With 1,8-diazabicyclo[5.4.0]undec-7-ene In acetonitrile at 50℃; |
Yield | Reaction Conditions | Operation in experiment |
---|---|---|
With 1,8-diazabicyclo[5.4.0]undec-7-ene In acetonitrile at 50℃; |
Yield | Reaction Conditions | Operation in experiment |
---|---|---|
18% | With selenium; n-butyllithium In diethyl ether; hexane 1.) 0 deg C, 15 min, 2.) 20 deg C, 15 min, 3.) 0 deg C 30 min; 20 deg C, 1 h; |
Yield | Reaction Conditions | Operation in experiment |
---|---|---|
85% | In dichloromethane at -78 - 0℃; for 4h; |
Yield | Reaction Conditions | Operation in experiment |
---|---|---|
85% | With 1-ethyl-2,2,4,4,4-pentakis(dimethylamino)-2λ5,4λ5-catenadi(phosphazene) In toluene Heating; |
Yield | Reaction Conditions | Operation in experiment |
---|---|---|
69.2% | Stage #1: 3-O-(methylsulfonyl)-20-secoebelin-20-al lactone With N-Bromosuccinimide In tetrachloromethane for 0.0833333h; Irradiation; Stage #2: 2,6-dichlorothiophenol With triethylamine In tetrachloromethane at 20℃; for 1h; |
Yield | Reaction Conditions | Operation in experiment |
---|---|---|
Stage #1: 2,6-dichlorothiophenol With sodium methylate In methanol at 20℃; Stage #2: 3-chloro-6-methoxypyridazine In toluene Heating; |
Yield | Reaction Conditions | Operation in experiment |
---|---|---|
60% | Stage #1: 2,6-dichlorothiophenol With potassium carbonate In N,N-dimethyl-formamide at 25℃; for 0.5h; Stage #2: tributyl-(1,3,3,3-tetrafluoro-2-<i>p</i>-tolyl-propenyl)-stannane In N,N-dimethyl-formamide at 25℃; for 6h; |
Yield | Reaction Conditions | Operation in experiment |
---|---|---|
75% | Stage #1: 2,6-dichlorothiophenol With potassium carbonate In N,N-dimethyl-formamide at 25℃; for 0.5h; Stage #2: (Z)-3,3,3-trifluoro-2-(4-chlorophenyl)-1-fluoro-tributylstanylprop-1-ene In N,N-dimethyl-formamide at 25℃; for 6h; |
Yield | Reaction Conditions | Operation in experiment |
---|---|---|
95% | Stage #1: 2,6-dichlorothiophenol With potassium carbonate In N,N-dimethyl-formamide at 25℃; for 0.5h; Stage #2: (Z)-3,3,3-trifluoro-2-(4-methoxyphenyl)-1-fluoro-1-tributylstannylprop-1-ene In N,N-dimethyl-formamide at 25℃; for 6h; |
Yield | Reaction Conditions | Operation in experiment |
---|---|---|
76% | Stage #1: 2,6-dichlorothiophenol With potassium carbonate In N,N-dimethyl-formamide at 25℃; for 0.5h; Stage #2: Tributyl-[(Z)-1,3,3,3-tetrafluoro-2-(4-fluoro-phenyl)-propenyl]-stannane In N,N-dimethyl-formamide at 25℃; for 6h; |
Yield | Reaction Conditions | Operation in experiment |
---|---|---|
97% | Stage #1: 2,6-dichlorothiophenol With potassium carbonate In N,N-dimethyl-formamide at 25℃; for 0.5h; Stage #2: tributyl-(1,3,3,3-tetrafluoro-2-<i>m</i>-tolyl-propenyl)-stannane In N,N-dimethyl-formamide at 25℃; for 6h; |
Yield | Reaction Conditions | Operation in experiment |
---|---|---|
40% | With tin(IV) chloride In dichloromethane at 20℃; for 4h; |
Yield | Reaction Conditions | Operation in experiment |
---|---|---|
100% | With di-tert-butyl-diazodicarboxylate; triphenylphosphine In dichloromethane at 20℃; | 22.22a 22a) Methyl 3-[(2,6-dichlorophenyl)thio]methyl}-5-(1-methylethyl)-4-isoxazolecarboxylate To a solution of 2,6-dichlorobenzenethiol (530 mg, 2.96 mmol), methyl 3-(hydroxymethyl)-5-(1-methylethyl)-4-isoxazolecarboxylate (629 mg, 2.46 mmol) and triphenylphosphine (1.29 g, 4.93 mmol) in dichloromethane (20 mL) was added di-tert-butyl azodicarboxylate (1.14 g, 4.93 mmol). The solution was stirred at ambient temperature overnight. The solution was then adsorbed onto silica gel and purified by chromatography (silica gel, 0-100% ethyl acetate in hexanes gradient elution) to afford methyl 3-[(2,6-dichlorophenyl)thio]methyl}-5-(1-methylethyl)-4-isoxazolecarboxylate (886 mg, 100%). 1H-NMR (400 MHz, CDCl3) δ 7.52-7.35 (m, 3H), 4.18 (s, 3H), 3.72 (s, 2H), 3.64 (septet, J=7 Hz, 1H), 1.20 (d, J=7 Hz, 6H). LRMS (APCI) m/z 360 (M+H)+. |
Yield | Reaction Conditions | Operation in experiment |
---|---|---|
80% | With sodium hydride In N,N-dimethyl-formamide at 80℃; for 3h; |
Yield | Reaction Conditions | Operation in experiment |
---|---|---|
Multi-step reaction with 5 steps 1: 85 percent / CH2Cl2 / 4 h / -78 - 0 °C 2: 96 percent / MeOH, NaOMe / 0.5 h / Ambient temperature 3: 1.) Bu2SnO, 2.) Bu4NBr / 1.) C6H6, reflux, overnight, 2.) C6H6, reflux, 3,5 h 4: 82 percent / 4-allyl-1,2-dimethoxybenzene, 2,6-di-tert-butyl-4-methylpyridine, triflic anhydride / CH2Cl2 / 0.25 h / -78 °C 5: 92 percent / LiAlH4 / diethyl ether / 0.5 h / 0 °C | ||
Multi-step reaction with 5 steps 1: 85 percent / CH2Cl2 / 4 h / -78 - 0 °C 2: 96 percent / MeOH, NaOMe / 0.5 h / Ambient temperature 3: 1.) Bu2SnO, 2.) Bu4NBr / 1.) C6H6, reflux, overnight, 2.) C6H6, reflux, 3,5 h 4: 81 percent / 4-allyl-1,2-dimethoxybenzene, 2,6-di-tert-butyl-4-methylpyridine, triflic anhydride / CH2Cl2 / 0.25 h / -78 °C 5: 92 percent / LiAlH4 / diethyl ether / 0.5 h / 0 °C |
Tags: 24966-39-0 synthesis path| 24966-39-0 SDS| 24966-39-0 COA| 24966-39-0 purity| 24966-39-0 application| 24966-39-0 NMR| 24966-39-0 COA| 24966-39-0 structure
Precautionary Statements-General | |
Code | Phrase |
P101 | If medical advice is needed,have product container or label at hand. |
P102 | Keep out of reach of children. |
P103 | Read label before use |
Prevention | |
Code | Phrase |
P201 | Obtain special instructions before use. |
P202 | Do not handle until all safety precautions have been read and understood. |
P210 | Keep away from heat/sparks/open flames/hot surfaces. - No smoking. |
P211 | Do not spray on an open flame or other ignition source. |
P220 | Keep/Store away from clothing/combustible materials. |
P221 | Take any precaution to avoid mixing with combustibles |
P222 | Do not allow contact with air. |
P223 | Keep away from any possible contact with water, because of violent reaction and possible flash fire. |
P230 | Keep wetted |
P231 | Handle under inert gas. |
P232 | Protect from moisture. |
P233 | Keep container tightly closed. |
P234 | Keep only in original container. |
P235 | Keep cool |
P240 | Ground/bond container and receiving equipment. |
P241 | Use explosion-proof electrical/ventilating/lighting/equipment. |
P242 | Use only non-sparking tools. |
P243 | Take precautionary measures against static discharge. |
P244 | Keep reduction valves free from grease and oil. |
P250 | Do not subject to grinding/shock/friction. |
P251 | Pressurized container: Do not pierce or burn, even after use. |
P260 | Do not breathe dust/fume/gas/mist/vapours/spray. |
P261 | Avoid breathing dust/fume/gas/mist/vapours/spray. |
P262 | Do not get in eyes, on skin, or on clothing. |
P263 | Avoid contact during pregnancy/while nursing. |
P264 | Wash hands thoroughly after handling. |
P265 | Wash skin thouroughly after handling. |
P270 | Do not eat, drink or smoke when using this product. |
P271 | Use only outdoors or in a well-ventilated area. |
P272 | Contaminated work clothing should not be allowed out of the workplace. |
P273 | Avoid release to the environment. |
P280 | Wear protective gloves/protective clothing/eye protection/face protection. |
P281 | Use personal protective equipment as required. |
P282 | Wear cold insulating gloves/face shield/eye protection. |
P283 | Wear fire/flame resistant/retardant clothing. |
P284 | Wear respiratory protection. |
P285 | In case of inadequate ventilation wear respiratory protection. |
P231 + P232 | Handle under inert gas. Protect from moisture. |
P235 + P410 | Keep cool. Protect from sunlight. |
Response | |
Code | Phrase |
P301 | IF SWALLOWED: |
P304 | IF INHALED: |
P305 | IF IN EYES: |
P306 | IF ON CLOTHING: |
P307 | IF exposed: |
P308 | IF exposed or concerned: |
P309 | IF exposed or if you feel unwell: |
P310 | Immediately call a POISON CENTER or doctor/physician. |
P311 | Call a POISON CENTER or doctor/physician. |
P312 | Call a POISON CENTER or doctor/physician if you feel unwell. |
P313 | Get medical advice/attention. |
P314 | Get medical advice/attention if you feel unwell. |
P315 | Get immediate medical advice/attention. |
P320 | |
P302 + P352 | IF ON SKIN: wash with plenty of soap and water. |
P321 | |
P322 | |
P330 | Rinse mouth. |
P331 | Do NOT induce vomiting. |
P332 | IF SKIN irritation occurs: |
P333 | If skin irritation or rash occurs: |
P334 | Immerse in cool water/wrap n wet bandages. |
P335 | Brush off loose particles from skin. |
P336 | Thaw frosted parts with lukewarm water. Do not rub affected area. |
P337 | If eye irritation persists: |
P338 | Remove contact lenses, if present and easy to do. Continue rinsing. |
P340 | Remove victim to fresh air and keep at rest in a position comfortable for breathing. |
P341 | If breathing is difficult, remove victim to fresh air and keep at rest in a position comfortable for breathing. |
P342 | If experiencing respiratory symptoms: |
P350 | Gently wash with plenty of soap and water. |
P351 | Rinse cautiously with water for several minutes. |
P352 | Wash with plenty of soap and water. |
P353 | Rinse skin with water/shower. |
P360 | Rinse immediately contaminated clothing and skin with plenty of water before removing clothes. |
P361 | Remove/Take off immediately all contaminated clothing. |
P362 | Take off contaminated clothing and wash before reuse. |
P363 | Wash contaminated clothing before reuse. |
P370 | In case of fire: |
P371 | In case of major fire and large quantities: |
P372 | Explosion risk in case of fire. |
P373 | DO NOT fight fire when fire reaches explosives. |
P374 | Fight fire with normal precautions from a reasonable distance. |
P376 | Stop leak if safe to do so. Oxidising gases (section 2.4) 1 |
P377 | Leaking gas fire: Do not extinguish, unless leak can be stopped safely. |
P378 | |
P380 | Evacuate area. |
P381 | Eliminate all ignition sources if safe to do so. |
P390 | Absorb spillage to prevent material damage. |
P391 | Collect spillage. Hazardous to the aquatic environment |
P301 + P310 | IF SWALLOWED: Immediately call a POISON CENTER or doctor/physician. |
P301 + P312 | IF SWALLOWED: call a POISON CENTER or doctor/physician IF you feel unwell. |
P301 + P330 + P331 | IF SWALLOWED: Rinse mouth. Do NOT induce vomiting. |
P302 + P334 | IF ON SKIN: Immerse in cool water/wrap in wet bandages. |
P302 + P350 | IF ON SKIN: Gently wash with plenty of soap and water. |
P303 + P361 + P353 | IF ON SKIN (or hair): Remove/Take off Immediately all contaminated clothing. Rinse SKIN with water/shower. |
P304 + P312 | IF INHALED: Call a POISON CENTER or doctor/physician if you feel unwell. |
P304 + P340 | IF INHALED: Remove victim to fresh air and Keep at rest in a position comfortable for breathing. |
P304 + P341 | IF INHALED: If breathing is difficult, remove victim to fresh air and keep at rest in a position comfortable for breathing. |
P305 + P351 + P338 | IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. |
P306 + P360 | IF ON CLOTHING: Rinse Immediately contaminated CLOTHING and SKIN with plenty of water before removing clothes. |
P307 + P311 | IF exposed: call a POISON CENTER or doctor/physician. |
P308 + P313 | IF exposed or concerned: Get medical advice/attention. |
P309 + P311 | IF exposed or if you feel unwell: call a POISON CENTER or doctor/physician. |
P332 + P313 | IF SKIN irritation occurs: Get medical advice/attention. |
P333 + P313 | IF SKIN irritation or rash occurs: Get medical advice/attention. |
P335 + P334 | Brush off loose particles from skin. Immerse in cool water/wrap in wet bandages. |
P337 + P313 | IF eye irritation persists: Get medical advice/attention. |
P342 + P311 | IF experiencing respiratory symptoms: call a POISON CENTER or doctor/physician. |
P370 + P376 | In case of fire: Stop leak if safe to Do so. |
P370 + P378 | In case of fire: |
P370 + P380 | In case of fire: Evacuate area. |
P370 + P380 + P375 | In case of fire: Evacuate area. Fight fire remotely due to the risk of explosion. |
P371 + P380 + P375 | In case of major fire and large quantities: Evacuate area. Fight fire remotely due to the risk of explosion. |
Storage | |
Code | Phrase |
P401 | |
P402 | Store in a dry place. |
P403 | Store in a well-ventilated place. |
P404 | Store in a closed container. |
P405 | Store locked up. |
P406 | Store in corrosive resistant/ container with a resistant inner liner. |
P407 | Maintain air gap between stacks/pallets. |
P410 | Protect from sunlight. |
P411 | |
P412 | Do not expose to temperatures exceeding 50 oC/ 122 oF. |
P413 | |
P420 | Store away from other materials. |
P422 | |
P402 + P404 | Store in a dry place. Store in a closed container. |
P403 + P233 | Store in a well-ventilated place. Keep container tightly closed. |
P403 + P235 | Store in a well-ventilated place. Keep cool. |
P410 + P403 | Protect from sunlight. Store in a well-ventilated place. |
P410 + P412 | Protect from sunlight. Do not expose to temperatures exceeding 50 oC/122oF. |
P411 + P235 | Keep cool. |
Disposal | |
Code | Phrase |
P501 | Dispose of contents/container to ... |
P502 | Refer to manufacturer/supplier for information on recovery/recycling |
Physical hazards | |
Code | Phrase |
H200 | Unstable explosive |
H201 | Explosive; mass explosion hazard |
H202 | Explosive; severe projection hazard |
H203 | Explosive; fire, blast or projection hazard |
H204 | Fire or projection hazard |
H205 | May mass explode in fire |
H220 | Extremely flammable gas |
H221 | Flammable gas |
H222 | Extremely flammable aerosol |
H223 | Flammable aerosol |
H224 | Extremely flammable liquid and vapour |
H225 | Highly flammable liquid and vapour |
H226 | Flammable liquid and vapour |
H227 | Combustible liquid |
H228 | Flammable solid |
H229 | Pressurized container: may burst if heated |
H230 | May react explosively even in the absence of air |
H231 | May react explosively even in the absence of air at elevated pressure and/or temperature |
H240 | Heating may cause an explosion |
H241 | Heating may cause a fire or explosion |
H242 | Heating may cause a fire |
H250 | Catches fire spontaneously if exposed to air |
H251 | Self-heating; may catch fire |
H252 | Self-heating in large quantities; may catch fire |
H260 | In contact with water releases flammable gases which may ignite spontaneously |
H261 | In contact with water releases flammable gas |
H270 | May cause or intensify fire; oxidizer |
H271 | May cause fire or explosion; strong oxidizer |
H272 | May intensify fire; oxidizer |
H280 | Contains gas under pressure; may explode if heated |
H281 | Contains refrigerated gas; may cause cryogenic burns or injury |
H290 | May be corrosive to metals |
Health hazards | |
Code | Phrase |
H300 | Fatal if swallowed |
H301 | Toxic if swallowed |
H302 | Harmful if swallowed |
H303 | May be harmful if swallowed |
H304 | May be fatal if swallowed and enters airways |
H305 | May be harmful if swallowed and enters airways |
H310 | Fatal in contact with skin |
H311 | Toxic in contact with skin |
H312 | Harmful in contact with skin |
H313 | May be harmful in contact with skin |
H314 | Causes severe skin burns and eye damage |
H315 | Causes skin irritation |
H316 | Causes mild skin irritation |
H317 | May cause an allergic skin reaction |
H318 | Causes serious eye damage |
H319 | Causes serious eye irritation |
H320 | Causes eye irritation |
H330 | Fatal if inhaled |
H331 | Toxic if inhaled |
H332 | Harmful if inhaled |
H333 | May be harmful if inhaled |
H334 | May cause allergy or asthma symptoms or breathing difficulties if inhaled |
H335 | May cause respiratory irritation |
H336 | May cause drowsiness or dizziness |
H340 | May cause genetic defects |
H341 | Suspected of causing genetic defects |
H350 | May cause cancer |
H351 | Suspected of causing cancer |
H360 | May damage fertility or the unborn child |
H361 | Suspected of damaging fertility or the unborn child |
H361d | Suspected of damaging the unborn child |
H362 | May cause harm to breast-fed children |
H370 | Causes damage to organs |
H371 | May cause damage to organs |
H372 | Causes damage to organs through prolonged or repeated exposure |
H373 | May cause damage to organs through prolonged or repeated exposure |
Environmental hazards | |
Code | Phrase |
H400 | Very toxic to aquatic life |
H401 | Toxic to aquatic life |
H402 | Harmful to aquatic life |
H410 | Very toxic to aquatic life with long-lasting effects |
H411 | Toxic to aquatic life with long-lasting effects |
H412 | Harmful to aquatic life with long-lasting effects |
H413 | May cause long-lasting harmful effects to aquatic life |
H420 | Harms public health and the environment by destroying ozone in the upper atmosphere |
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