Home Cart 0 Sign in  

[ CAS No. 25677-69-4 ] {[proInfo.proName]}

,{[proInfo.pro_purity]}
Cat. No.: {[proInfo.prAm]}
Chemical Structure| 25677-69-4
Chemical Structure| 25677-69-4
Structure of 25677-69-4 * Storage: {[proInfo.prStorage]}
Cart0 Add to My Favorites Add to My Favorites Bulk Inquiry Inquiry Add To Cart

Quality Control of [ 25677-69-4 ]

Related Doc. of [ 25677-69-4 ]

Alternatived Products of [ 25677-69-4 ]

Product Details of [ 25677-69-4 ]

CAS No. :25677-69-4 MDL No. :MFCD00044208
Formula : C24H16N2 Boiling Point : -
Linear Structure Formula :- InChI Key :HVCVRVKEIKXBIF-UHFFFAOYSA-N
M.W : 332.40 Pubchem ID :11186609
Synonyms :

Safety of [ 25677-69-4 ]

Signal Word:Warning Class:N/A
Precautionary Statements:P261-P305+P351+P338 UN#:N/A
Hazard Statements:H315-H319-H335 Packing Group:N/A
GHS Pictogram:

Application In Synthesis of [ 25677-69-4 ]

* All experimental methods are cited from the reference, please refer to the original source for details. We do not guarantee the accuracy of the content in the reference.

  • Downstream synthetic route of [ 25677-69-4 ]

[ 25677-69-4 ] Synthesis Path-Downstream   1~84

  • 1
  • [ 14371-10-9 ]
  • [ 116529-78-3 ]
  • [ 25677-69-4 ]
YieldReaction ConditionsOperation in experiment
With phosphoric acid; orthoarsenic acid at 135℃;
  • 2
  • [ 66-71-7 ]
  • [ 591-51-5 ]
  • [ 25677-69-4 ]
YieldReaction ConditionsOperation in experiment
80% Stage #1: 1,10-Phenanthroline; phenyllithium In toluene at 0℃; Inert atmosphere; Stage #2: With manganese(IV) oxide In dichloromethane Synthesis of 2-subsituted-1,10-phenanthrolines from 1,10-phenanthroline. General procedure: A solution of 1,10-phenanthroline (1 g) in dry, degassed toluene (200 ml) was cooled to 0 °C under argon and subjected to vigorous stirring. The pre-titrated n-butyl- or phenyllithium solution was added dropwise via syringe in the following way: on addition of the first few drops of alkylating reagent, no permanent color change was observed. On further careful addition (typically one drop) the solution became intensely colored, indicating formation of the addition product. From this point 1.0 equiv of lithium reagent was added slowly and the solution left to stir for 5 min. Quenching with H2O (30 ml), extraction with CH2Cl2 (3 × 100 ml) and reoxidation by MnO2 gave the title product. Work-up by filtration of the CH2Cl2 solution through a short plug of alumina and additional washing with CH2Cl2 (2 × 100 ml) gave, after removal of the solvent, the 2-substututed-1,10-phenanthroline in good yields (2-phenyl-1,10-phenanthroline: 99% and 2-butyl-1,10-phenanthroline: 98%, as white powders).
78% Stage #1: 1,10-Phenanthroline; phenyllithium In hexane; toluene at 0 - 25℃; Inert atmosphere; Schlenk technique; Glovebox; Stage #2: With manganese(IV) oxide In toluene for 6h; Inert atmosphere; Schlenk technique; Glovebox;
38% Stage #1: 1,10-Phenanthroline; phenyllithium In dibutyl ether; toluene at 0 - 20℃; Stage #2: With manganese(IV) oxide In dichloromethane for 2h;
Yield given. Multistep reaction;

  • 3
  • [ 25677-69-4 ]
  • 6,6'-diphenyl-[2,2']bipyridinyl-3,3'-dicarboxylic acid [ No CAS ]
YieldReaction ConditionsOperation in experiment
With potassium permanganate; sodium periodate
With potassium permanganate; sodium periodate; potassium carbonate In water; <i>tert</i>-butyl alcohol for 14h; Heating;
With potassium permanganate; sodium periodate; potassium carbonate In water; <i>tert</i>-butyl alcohol for 14h; Heating;
  • 4
  • [ 25677-69-4 ]
  • disodium 2,9-bis(3-sulfonatophenyl)-1,10-phenanthroline [ No CAS ]
YieldReaction ConditionsOperation in experiment
With sulfuric acid; boric acid
  • 5
  • [ 25677-69-4 ]
  • [ 916900-84-0 ]
YieldReaction ConditionsOperation in experiment
63% With sodium cyanoborohydride; acetic acid In methanol for 6h; Heating;
  • 6
  • [ 25677-69-4 ]
  • [ 916900-90-8 ]
YieldReaction ConditionsOperation in experiment
Multi-step reaction with 5 steps 1: 63 percent / acetic acid; NaBH3CN / methanol / 6 h / Heating 2: PCl3; N,N-dimethylaniline / CH2Cl2 / 1 h / Heating 3: N,N-dimethylaniline / CH2Cl2 / 1 h / Heating 4: S8 / CH2Cl2 / 0.42 h / Heating 5: 77 percent / LiAlH4 / tetrahydrofuran / 1.67 h / Heating
  • 7
  • [ 25677-69-4 ]
  • meso-2,9-diphenyl-1,2,3,4,7,8,9,10-octahydro-1,10-phenanthroline [ No CAS ]
YieldReaction ConditionsOperation in experiment
Multi-step reaction with 5 steps 1: 63 percent / acetic acid; NaBH3CN / methanol / 6 h / Heating 2: PCl3; N,N-dimethylaniline / CH2Cl2 / 1 h / Heating 3: N,N-dimethylaniline / CH2Cl2 / 1 h / Heating 4: S8 / CH2Cl2 / 0.42 h / Heating 5: 41 percent / LiAlH4 / tetrahydrofuran / 0.75 h / Heating
  • 8
  • [ 25677-69-4 ]
  • 4-chloro-3,5-diphenyl-1,2,3,5,6,7-hexahydro-3a,4a-diaza-4-phospha-cyclopenta[<i>def</i>]phenanthrene [ No CAS ]
YieldReaction ConditionsOperation in experiment
Multi-step reaction with 2 steps 1: 63 percent / acetic acid; NaBH3CN / methanol / 6 h / Heating 2: PCl3; N,N-dimethylaniline / CH2Cl2 / 1 h / Heating
  • 9
  • [ 25677-69-4 ]
  • (-)-(3S,5S)-diphenyl-1,2,3,5,6,7-hexahydro-3a,4a-diazacyclopenta[def]phenanthren-4-thione [ No CAS ]
YieldReaction ConditionsOperation in experiment
Multi-step reaction with 7 steps 1: 63 percent / acetic acid; NaBH3CN / methanol / 6 h / Heating 2: PCl3; N,N-dimethylaniline / CH2Cl2 / 1 h / Heating 3: N,N-dimethylaniline / CH2Cl2 / 1 h / Heating 4: S8 / CH2Cl2 / 0.42 h / Heating 5: 77 percent / LiAlH4 / tetrahydrofuran / 1.67 h / Heating 6: 75 percent / HCl / 3 h / 80 °C 7: 56 percent / S8; sodium hydride / tetrahydrofuran / 0.83 h
  • 10
  • [ 25677-69-4 ]
  • 4-((1R,2S,5R)-2-Isopropyl-5-methyl-cyclohexyloxy)-3,5-diphenyl-1,2,3,5,6,7-hexahydro-3a,4a-diaza-4-phospha-cyclopenta[def]phenanthrene [ No CAS ]
YieldReaction ConditionsOperation in experiment
Multi-step reaction with 3 steps 1: 63 percent / acetic acid; NaBH3CN / methanol / 6 h / Heating 2: PCl3; N,N-dimethylaniline / CH2Cl2 / 1 h / Heating 3: N,N-dimethylaniline / CH2Cl2 / 1 h / Heating
  • 11
  • [ 25677-69-4 ]
  • 4-[(1R,2S,5R)-menthyloxy]-3,5-diphenyl-1,2,3,5,6,7-hexahydro-3a,4a-diaza-4-phosphacyclopenta[def]phenanthrene 4-sulfide [ No CAS ]
YieldReaction ConditionsOperation in experiment
Multi-step reaction with 4 steps 1: 63 percent / acetic acid; NaBH3CN / methanol / 6 h / Heating 2: PCl3; N,N-dimethylaniline / CH2Cl2 / 1 h / Heating 3: N,N-dimethylaniline / CH2Cl2 / 1 h / Heating 4: S8 / CH2Cl2 / 0.42 h / Heating
  • 12
  • [ 25677-69-4 ]
  • [ 916900-89-5 ]
YieldReaction ConditionsOperation in experiment
Multi-step reaction with 4 steps 1: 63 percent / acetic acid; NaBH3CN / methanol / 6 h / Heating 2: PCl3; N,N-dimethylaniline / CH2Cl2 / 1 h / Heating 3: N,N-dimethylaniline / CH2Cl2 / 1 h / Heating 4: S8 / CH2Cl2 / 0.42 h / Heating
  • 13
  • [ 25677-69-4 ]
  • (-)-(3S,5S)-diphenyl-1,2,3,5,6,7-hexahydro-3a-aza-cyclopenta[def]phenanthren-4a-azonium chloride [ No CAS ]
YieldReaction ConditionsOperation in experiment
Multi-step reaction with 6 steps 1: 63 percent / acetic acid; NaBH3CN / methanol / 6 h / Heating 2: PCl3; N,N-dimethylaniline / CH2Cl2 / 1 h / Heating 3: N,N-dimethylaniline / CH2Cl2 / 1 h / Heating 4: S8 / CH2Cl2 / 0.42 h / Heating 5: 77 percent / LiAlH4 / tetrahydrofuran / 1.67 h / Heating 6: 75 percent / HCl / 3 h / 80 °C
  • 14
  • [ 25677-69-4 ]
  • [ 457625-39-7 ]
YieldReaction ConditionsOperation in experiment
Multi-step reaction with 3 steps 1: potassium carbonate; sodium periodate; potassium permanganate / 2-methyl-propan-2-ol; H2O / 14 h / Heating 2: 1.99 g / diethyl ether 3: 88 percent / lithium aluminum hydride / tetrahydrofuran / 2 h / 20 °C
Multi-step reaction with 3 steps 1: potassium permanganate; sodium periodate; potassium carbonate / H2O; 2-methyl-propan-2-ol / 14 h / Heating 2: 35 percent / diethyl ether 3: 88 percent / lithium aluminum hydride / tetrahydrofuran / 2 h / 20 °C
  • 15
  • [ 25677-69-4 ]
  • [ 457625-37-5 ]
YieldReaction ConditionsOperation in experiment
Multi-step reaction with 2 steps 1: potassium carbonate; sodium periodate; potassium permanganate / 2-methyl-propan-2-ol; H2O / 14 h / Heating 2: 1.99 g / diethyl ether
Multi-step reaction with 2 steps 1: potassium permanganate; sodium periodate; potassium carbonate / H2O; 2-methyl-propan-2-ol / 14 h / Heating 2: 35 percent / diethyl ether
  • 16
  • [ 25677-69-4 ]
  • (R)-3,3'-bis(hydroxymethyl)-6,6'-diphenyl-2,2'-bipyridine N,N'-dioxide [ No CAS ]
YieldReaction ConditionsOperation in experiment
Multi-step reaction with 6 steps 1.1: potassium carbonate; sodium periodate; potassium permanganate / 2-methyl-propan-2-ol; H2O / 14 h / Heating 2.1: 1.99 g / diethyl ether 3.1: 88 percent / lithium aluminum hydride / tetrahydrofuran / 2 h / 20 °C 4.1: triethylamine / CHCl3 / 24 h / 20 °C 4.2: 75 percent / toluene / 48 h / Heating 5.1: 71 percent / m-chloroperbenzoic acid / CH2Cl2 / 64 h / 20 °C 6.1: 98 percent / aq. NaOH / methanol / 31 h / 20 °C
Multi-step reaction with 6 steps 1.1: potassium permanganate; sodium periodate; potassium carbonate / H2O; 2-methyl-propan-2-ol / 14 h / Heating 2.1: 35 percent / diethyl ether 3.1: 88 percent / lithium aluminum hydride / tetrahydrofuran / 2 h / 20 °C 4.1: triethylamine / CHCl3 / 24 h / 20 °C 4.2: 75 percent / toluene / 48 h / Heating 5.1: 71 percent / m-chloroperbenzoic acid / CH2Cl2 / 64 h / 20 °C 6.1: 98 percent / sodium hydroxide / methanol; H2O / 31 h / 20 °C
  • 17
  • [ 25677-69-4 ]
  • [ 457891-56-4 ]
YieldReaction ConditionsOperation in experiment
Multi-step reaction with 4 steps 1.1: potassium carbonate; sodium periodate; potassium permanganate / 2-methyl-propan-2-ol; H2O / 14 h / Heating 2.1: 1.99 g / diethyl ether 3.1: 88 percent / lithium aluminum hydride / tetrahydrofuran / 2 h / 20 °C 4.1: triethylamine / CHCl3 / 24 h / 20 °C 4.2: 75 percent / toluene / 48 h / Heating
  • 18
  • [ 25677-69-4 ]
  • [ 457891-57-5 ]
YieldReaction ConditionsOperation in experiment
Multi-step reaction with 5 steps 1.1: potassium carbonate; sodium periodate; potassium permanganate / 2-methyl-propan-2-ol; H2O / 14 h / Heating 2.1: 1.99 g / diethyl ether 3.1: 88 percent / lithium aluminum hydride / tetrahydrofuran / 2 h / 20 °C 4.1: triethylamine / CHCl3 / 24 h / 20 °C 4.2: 75 percent / toluene / 48 h / Heating 5.1: 71 percent / m-chloroperbenzoic acid / CH2Cl2 / 64 h / 20 °C
  • 19
  • [ 25677-69-4 ]
  • (S)-3,3'-bis(hydroxymethyl)-6,6'-diphenyl-2,2'-bipyridine N,N'-dioxide [ No CAS ]
YieldReaction ConditionsOperation in experiment
Multi-step reaction with 6 steps 1.1: potassium carbonate; sodium periodate; potassium permanganate / 2-methyl-propan-2-ol; H2O / 14 h / Heating 2.1: 1.99 g / diethyl ether 3.1: 88 percent / lithium aluminum hydride / tetrahydrofuran / 2 h / 20 °C 4.1: triethylamine / CHCl3 / 24 h / 20 °C 4.2: 75 percent / toluene / 48 h / Heating 5.1: 71 percent / m-chloroperbenzoic acid / CH2Cl2 / 64 h / 20 °C 6.1: 85 percent / aq. NaOH / methanol / 31 h / 20 °C
  • 20
  • [ 25677-69-4 ]
  • C46H30N2O4 [ No CAS ]
YieldReaction ConditionsOperation in experiment
Multi-step reaction with 4 steps 1.1: potassium permanganate; sodium periodate; potassium carbonate / H2O; 2-methyl-propan-2-ol / 14 h / Heating 2.1: 35 percent / diethyl ether 3.1: 88 percent / lithium aluminum hydride / tetrahydrofuran / 2 h / 20 °C 4.1: triethylamine / CHCl3 / 24 h / 20 °C 4.2: 75 percent / toluene / 48 h / Heating
  • 21
  • [ 25677-69-4 ]
  • C46H30N2O6 [ No CAS ]
YieldReaction ConditionsOperation in experiment
Multi-step reaction with 5 steps 1.1: potassium permanganate; sodium periodate; potassium carbonate / H2O; 2-methyl-propan-2-ol / 14 h / Heating 2.1: 35 percent / diethyl ether 3.1: 88 percent / lithium aluminum hydride / tetrahydrofuran / 2 h / 20 °C 4.1: triethylamine / CHCl3 / 24 h / 20 °C 4.2: 75 percent / toluene / 48 h / Heating 5.1: 71 percent / m-chloroperbenzoic acid / CH2Cl2 / 64 h / 20 °C
  • 22
  • [ 25677-69-4 ]
  • (2,9-diphenyl-1,10-phenanthrolinato-C,N,N)platinum (II) chloride [ No CAS ]
YieldReaction ConditionsOperation in experiment
87.2% With chloro(6-phenyl-2,2'-bipyridine)platinum In 2-ethoxy-ethanol for 3h; Heating / reflux; 7 Example 7 Production of platinum complex (1b''-9) ((2,9-diphenyl-1,10-phenanthrolinato-C,N,N)platinum (II) chloride) [(1,2,5,6-η4)-1,5-hexadienyl]platinum(II) dichloride (500 mg, 1.44 mmol, 1.0 equivalent) and 2,9-diphenyl-1,10-phenanthroline (574 mg, 1.72 mmol, 1.2 equivalents) were charged into a schlenk flask, whose inside was replaced with nitrogen. Then, 2-ethoxyethanol (10 mL) was added thereto, and the mixture was heated, and allowed to react with stirring under reflux for 3 hours. Then, the solvent was distilled off under reduced pressure. The resulting red orange residue was purified with a silica gel column chromatography (eluent: dichloromethane / methanol = 100/1), and then recrystallized from hexane / dichloromethane. As a result, 706 mg of the platinum complex (1b''-9) was obtained as a red orange powder. Yield 87.2 %. 1H-NMR(500MHz CD2Cl2) :δ 7.11 (dt, J=1.3, 7.4Hz, 1H), 7.16-7.24(m, 1H), 7.49-7.58(m, 4H), 7.63-7.77(m, 1H), 7.80-7.91(m, 5H), 7.96(d, J=8.5Hz, 1H), 8.42(d, J=8.6Hz, 1H), 8.50(d, J=8.5Hz, 1 H).
  • 23
  • chloro(η4-cis,cis-cycloocta-1,5-diene)pentafluorophenylplatinum(II) [ No CAS ]
  • [ 25677-69-4 ]
  • [2,9-diphenyl phenanthrolinato (N,N,C)]pentafluorophenyl platinum (II) [ No CAS ]
YieldReaction ConditionsOperation in experiment
12.7% In acetic acid at 80℃; for 48h; 20 To 0.23 g of pentafluorophenyl(1,5-cyclooctadiene)platinum (II) chloride synthesized in the same manner as with (2) of Example 17, and 0. 59 g of 2, 9-diphenylphenanthroline, 20 ml of acetic acid was added. The mixture was stirred at 80 °C for 2 days. The resulting orange solution was concentrated under reduced pressure, and purified by a silica gel column chromatography (eluent: toluene / chloroform = 1 / 1). As a result, 0.04 g of the platinum complex (1'''-12) was obtained as an orange solid. Yield: 12.7 %. 1H-NMR(CD2Cl2) δ:6.70-6.53(m, 1H), 6.96(dt, J=1.4, 7.4Hz, 1 H),7.02(dt, J=1.3, 7.3Hz, 1H), 7.16-7.22(m, 3H), 7.45-7.47(m, 2 H),7.57(dd, J=7.6, 1.6Hz, 1H), 7.80(d, J=8.4Hz, 1H), 7.89-7.93 (m,2H),7.97(d, J=8.9Hz, 1H), 8.45(d, J=8.7Hz, 1H), 8.51(d, J=8. 4Hz,lH)ppm.
  • 24
  • Cu(phen)+ [ No CAS ]
  • [ 25677-69-4 ]
  • [ 85626-37-5 ]
YieldReaction ConditionsOperation in experiment
In dichloromethane; water; acetonitrile
  • 25
  • tetrakis(acetonitrile)copper(I)tetrafluoroborate [ No CAS ]
  • [ 25677-69-4 ]
  • [ 92205-20-4 ]
YieldReaction ConditionsOperation in experiment
70% In dichloromethane; acetonitrile (under Ar); addn. of the ligand in CH2Cl2 to a soln. of the starting complex in acetonitrile at room temp., stirring for 2 h; solvent is evapd., solid is dissolved in ethanol, filtn., crystn. in a refrigerator, recrystn.(ethanol), elem. anal.;
  • 26
  • [ 25677-69-4 ]
  • copper(l) chloride [ No CAS ]
  • {Cu(I)(2,9-diphenyl-1,10-phenathroline)2}{CuCl2}*0.667CH3CN [ No CAS ]
YieldReaction ConditionsOperation in experiment
In acetonitrile refluxing mixt. (1:1) of CuCl and dpp in CH3CN for 36 h; soln. cooling, volume redn. (argon) on crystn., crystal filtration;
  • 27
  • cobalt(II) chloride hexahydrate [ No CAS ]
  • [ 25677-69-4 ]
  • Co(2,9-diphenyl-1,10-phenanthroline)3Cl2 [ No CAS ]
YieldReaction ConditionsOperation in experiment
In N,N-dimethyl-formamide prepared in situ, addn. of 3 equiv. of ligand;
  • 28
  • [ 14104-20-2 ]
  • bis[(1,2,3-η)-2-butenyl]di(μ-chloro)palladium(II) [ No CAS ]
  • [ 25677-69-4 ]
  • (2,9-diphenyl-1,10-phenanthroline){anti-(1,2,3-η)-2-butenyl}palladium tetrafluoroborate [ No CAS ]
  • (2,9-diphenyl-1,10-phenanthroline){syn-(1,2,3-η)-2-butenyl}palladium tetrafluoroborate [ No CAS ]
YieldReaction ConditionsOperation in experiment
In not given Pd-complex dissolved at 0°C, addn. AgBF4 (immediate formation white ppt.), mixt. kept 20 min, addn. of the phenanthroline, mixt. stirred (20°C, 1h); filtered (Pasteur pipet, cotton plug and Celite column), evapn., recrystn. (CH2Cl2/Et2O);
  • 29
  • K(1+)*AuCl4(1-)*0.5H2O=K[AuCl4]*0.5H2O [ No CAS ]
  • [ 25677-69-4 ]
  • [ 16836-95-6 ]
  • Au(C24H15N2)Cl(1+)*CH3C6H4SO3(1-)={Au(C24H15N2)Cl}(CH3C6H4SO3) [ No CAS ]
YieldReaction ConditionsOperation in experiment
14% In acetonitrile byproducts: 2,5-diphenylphenanthrolinium(1+), Cl(1-), AgCl; refluxing stoich. amts. of phenanthroline derivative and KAuCl4 with 2 equiv. Ag-tosylate (72 h); concn., filtration, extn. of ppt. (boiling MeCN), crystn. on Et2O diffusion into extract; elem. anal.;
  • 30
  • K(1+)*AuCl4(1-)*0.5H2O=K[AuCl4]*0.5H2O [ No CAS ]
  • [ 25677-69-4 ]
  • silver perchlorate [ No CAS ]
  • Au(C24H15N2)Cl(1+)*ClO4(1-)={Au(C24H15N2)Cl}(ClO4) [ No CAS ]
YieldReaction ConditionsOperation in experiment
In acetonitrile byproducts: 2,5-diphenylphenanthrolinium(1+), Cl(1-), AgCl; refluxing stoich. amts. of phenanthroline derivative and KAuCl4 with 2 equiv. AgClO4 (72 h); concn., filtration, extn. of ppt. (boiling MeCN), crystn. on Et2O diffusion into extract; elem. anal.;
  • 31
  • tetraacetonitrileplatinum(II) perchlorate [ No CAS ]
  • [ 25677-69-4 ]
  • {Pt(CH3CN)(C12H6N2(C6H4)(C6H5))}2(2+)*2ClO4(1-)={Pt(CH3CN)(C12H6N2(C6H4)(C6H5))}2(ClO4)2 [ No CAS ]
YieldReaction ConditionsOperation in experiment
12% In acetonitrile the starting complex is added to a refluxing ligand soln. in acetonirile, refluxed for 1 d; filtd., diffusion of diethyl ether into the filtrate, elem. anal.;
  • 32
  • [ 25677-69-4 ]
  • [ 1600-27-7 ]
  • [Hg(C6H4C12H6N2C6H5)Cl]2 [ No CAS ]
YieldReaction ConditionsOperation in experiment
20% With LiCl In methanol; ethanol Hg-salt and the org. compound refluxed for 6 h in EtOH, LiCl in MeOH added, refluxed for 30 min; hot filtered, cooled to room temp., filtered out, washed (ethyl acetate);
  • 33
  • ammonium hexafluorophosphate [ No CAS ]
  • cis-[bis(D8-2,2'-bipyridine)dichlororuthenium(II)] dihydrate [ No CAS ]
  • [ 25677-69-4 ]
  • [Ru(2,9-diphenyl-1,10-phenanthroline)(2,2'-bipyridine-d8)2](PF6)2 [ No CAS ]
YieldReaction ConditionsOperation in experiment
46% In ethylene glycol other Radiation; heating Ru-complex with 1 equiv. substituted phenanthroline (70 W microwave oven, Ar-atmosphere, 30 min), cooling, addn. of excess aq. NH4PF6, stirring at room temp. for 1 h; pptn. on water addn., chromy. (Al2O3, PhMe/MeCN=2:1);
  • 34
  • [ 64443-05-6 ]
  • [ 25677-69-4 ]
  • [ 183294-82-8 ]
YieldReaction ConditionsOperation in experiment
88% In acetonitrile Ar-atmosphere; addn. of 2 equiv. of phen derivative to Cu-complex soln.,stirring for 10 min; pptn. on Et2O addn., filtration, dissoln. in CH2Cl2, crystn. on layeringwith Et2O; elem. anal.;
86% In methanol for 1h; Inert atmosphere;
50% In dichloromethane; acetonitrile at 20℃; for 1h; Inert atmosphere;
50.1% In dichloromethane at 20℃; Inert atmosphere;
In dichloromethane; acetonitrile N2-atmosphere; addn. of 2 equiv. ligand (in 25% CH2Cl2 in MeCN) to Cu-complex, stirring at room temp. for 30 min; evapn., recrystn. (CH2Cl2/Et2O);
In acetonitrile Ar-atmosphere; stirring stoich. amts. for 10 min; evapn., dissoln. in CH2Cl2, crystn. on layering with Et2O; elem. anal.;

  • 35
  • [ 17084-13-8 ]
  • cis-dichloro(2,2′-bipyridine)ruthenium(II)chloride [ No CAS ]
  • [ 25677-69-4 ]
  • [Ru(2,2'-bipyridine)2(2,9-diphenyl-1,10-phenanthroline)](PF6)2 [ No CAS ]
YieldReaction ConditionsOperation in experiment
76% In ethylene glycol reflux (3 h) of soln. of Ru complex and phenanthroline, cooling to room temp.; filtration, addn. of satd. aq. K(PF6) (100°C), cooling, crystn. (0°C, overnight), filtration, washing (water), drying (air), chromy. (silica gel, CH3CN/water/satd. aq. NaNO3 (100:5:0.5)), anion exchangewith K(PF6);
  • 36
  • copper(II) perchlorate hexahydrate [ No CAS ]
  • [ 25677-69-4 ]
  • [Cu(2,9-diphenyl-1,10-phenanthroline)2](ClO4)2 [ No CAS ]
YieldReaction ConditionsOperation in experiment
In methanol stirring stoich. amts. at room temp. for 2 h; crystn. in freezer overnight; elem. anal.;
  • 37
  • ruthenium(III) chloride trihydrate [ No CAS ]
  • [ 25677-69-4 ]
  • [ 175417-56-8 ]
  • [RuCl2(CO)2(C24H16N2)] [ No CAS ]
YieldReaction ConditionsOperation in experiment
72% In N,N-dimethyl-formamide reflux;
  • 38
  • dicarbonyldichlororuthenium [ No CAS ]
  • [ 25677-69-4 ]
  • [ 175417-56-8 ]
  • [RuCl2(CO)2(C24H16N2)] [ No CAS ]
YieldReaction ConditionsOperation in experiment
72% In ethanol; water reflux;
  • 39
  • [ 25677-69-4 ]
  • [ 7787-70-4 ]
  • [ 916061-13-7 ]
YieldReaction ConditionsOperation in experiment
94% In dichloromethane organic ligand and anhydrous CuBr refluxed in CH2Cl2 for 2 h;; diethyl ether added to the CH2Cl2 solution; elem. anal.;
  • 40
  • [ 25677-69-4 ]
  • [ 7789-45-9 ]
  • [ 916061-12-6 ]
YieldReaction ConditionsOperation in experiment
55% In dichloromethane organic ligand and anhydrous CuBr2 stirred in CH2Cl2 at room temp.; after filtration solution slowly evaporated; elem. anal.;
  • 41
  • nickel(II) chloride hexahydrate [ No CAS ]
  • [ 25677-69-4 ]
  • [ 1096688-24-2 ]
YieldReaction ConditionsOperation in experiment
87% In tetrahydrofuran (N2); 2,9-diphenyl-1,10-phenanthroline and NiCl2*6H2O in THF were refluxed for 8 h; filtered, washed with EtOH, Et2O, recrystd. from CH2Cl2, elem. anal.;
50% In ethanol under N2, a slight excess of Ni-compd. soln. was added to N-compd. soln., stirring at room temp. for 9 h; soln. was removed, ppt. was filtered off, washed with Et2O, elem. anal.;
  • 42
  • NiBr2*4H2O [ No CAS ]
  • [ 25677-69-4 ]
  • [ 312539-47-2 ]
YieldReaction ConditionsOperation in experiment
86% In ethanol under N2, a slight excess of Ni-compd. soln. was added to N-compd. soln., stirring at room temp. for 9 h; soln. was removed, ppt. was filtered off, washed with Et2O, elem. anal.;
  • 43
  • dichlorobis(dimethyl sulfoxide)platinum(II) [ No CAS ]
  • [ 25677-69-4 ]
  • [ 1060639-59-9 ]
YieldReaction ConditionsOperation in experiment
81% In chloroform to stirred suspn. Pt complex in CHCl3 was added ligand, suspn. was heated to reflux for 24 h; ppt. was collected by filtration, washed with Et2O, dried in air; elem. anal.;
  • 44
  • nickel(II) bromide hexahydrate [ No CAS ]
  • [ 25677-69-4 ]
  • [ 312539-47-2 ]
YieldReaction ConditionsOperation in experiment
82.1% In tetrahydrofuran (N2); 2,9-diphenyl-1,10-phenanthroline and NiBr2*6H2O in THF were refluxed for 8 h; filtered, washed with EtOH, Et2O, recrystd. from CH2Cl2, elem. anal.;
  • 45
  • cobalt(II) chloride hexahydrate [ No CAS ]
  • [ 25677-69-4 ]
  • [ 1106741-36-9 ]
YieldReaction ConditionsOperation in experiment
80.5% In tetrahydrofuran (N2); 2,9-diphenyl-1,10-phenanthroline and CoCl2*6H2O in THF were refluxed for 8 h; filtered, washed with EtOH, Et2O, recrystd. from CH2Cl2/CH3CN, elem. anal.;
  • 46
  • [ 64443-05-6 ]
  • [ 25677-69-4 ]
  • [ 6588-06-3 ]
  • [ 1190867-50-5 ]
YieldReaction ConditionsOperation in experiment
71% In acetone Ar; ligands dissolved in acetone, Cu compd. (1:1:1 molar ratio) added. stirred at room temp. for 2 h; ppt. filtered off, recrystd. (acetone/Et2O), filtered off, elem. anal.;
  • 47
  • N,N'-bis(3,4,5-trimethoxyphenylmethyl)-2-amino-4-imino-pent-2-ene [ No CAS ]
  • [ 25677-69-4 ]
  • copper (I) tert-butoxide [ No CAS ]
  • [ 1254173-70-0 ]
YieldReaction ConditionsOperation in experiment
In toluene (N2); a soln. of Cu compd. added to a soln. of ligands, stirred; filtered, evapd., recrystd. from toluene/hexane at -30°C; obtained impure;
  • 48
  • [ 1197011-75-8 ]
  • [ 25677-69-4 ]
  • [ 1254173-66-4 ]
YieldReaction ConditionsOperation in experiment
In not given byproducts: C6H5CHCH2; under vac.;
  • 49
  • [ 25677-69-4 ]
  • N,N'-di(benzyl)-2-amino-4-iminopent-2-ene [ No CAS ]
  • copper (I) tert-butoxide [ No CAS ]
  • [ 1254173-66-4 ]
YieldReaction ConditionsOperation in experiment
59% In diethyl ether (N2); a flask charged with ligands and Cu compd., Et2O added, stirred; filtered, evapd., washed (hexane), dried (vac.); elem. anal.;
  • 50
  • copper(II) choride dihydrate [ No CAS ]
  • [ 25677-69-4 ]
  • [ 1214737-43-5 ]
YieldReaction ConditionsOperation in experiment
74.9% In tetrahydrofuran (N2), ligand and Cu salt (1:1) stirred in THF for 8 h; filtered;
  • 51
  • [ 25677-69-4 ]
  • copper(l) chloride [ No CAS ]
  • [ 132069-08-0 ]
YieldReaction ConditionsOperation in experiment
73.5% In dichloromethane (N2), ligand and Cu salt (1:1) stirred in Ch2Cl2 for 8 h; filtered, elem. anal.;
  • 52
  • [ 25677-69-4 ]
  • [ 916061-13-7 ]
YieldReaction ConditionsOperation in experiment
Multi-step reaction with 2 steps 1: dichloromethane 2: acetone
  • 53
  • ammonium hexafluorophosphate [ No CAS ]
  • tetrakis(2-phenylquinoline-C2,N')(μ-dichloro)diiridium(III) [ No CAS ]
  • [ 25677-69-4 ]
  • [Ir(2-phenylquinoline)2(2,9-diphenyl-1,10-phenanthroline)]PF6 [ No CAS ]
YieldReaction ConditionsOperation in experiment
76% Stage #1: tetrakis(2-phenylquinoline-C2,N')(μ-dichloro)diiridium(III); 2,9-diphenyl-1,10-phenanthroline In methanol; dichloromethane Inert atmosphere; Reflux; Stage #2: ammonium hexafluorophosphate In methanol; dichloromethane; water
  • 54
  • [ 25677-69-4 ]
  • [ 1032154-74-7 ]
  • (-)-(R)-2,9-diphenyl-1,2,3,4-tetrahydro-1,10-phenanthroline [ No CAS ]
YieldReaction ConditionsOperation in experiment
87 % ee Stage #1: 2,9-diphenyl-1,10-phenanthroline With Ru(trifluoromethanesulfonate)(N-(p-toluenesulfonyl)-1,2-diphenylethylenediamine)(η6-cymene); hydrogen In methanol at 25℃; for 24h; Inert atmosphere; Schlenk technique; Glovebox; Stage #2: at 25℃; for 12h; Overall yield = 90 %; Overall yield = 100 %Spectr.; enantioselective reaction;
  • 55
  • [ 66-71-7 ]
  • [ 25677-69-4 ]
YieldReaction ConditionsOperation in experiment
Multi-step reaction with 4 steps 1: nitrobenzene / 120 °C 2: potassium hexacyanoferrate(III); sodium hydroxide / water / 0 °C 3: trichlorophosphate; phosphorus pentachloride / 110 °C 4: tetrakis(triphenylphosphine) palladium(0); sodium carbonate; tetrabutylammomium bromide / water; toluene / 5 h / 100 °C / Inert atmosphere
Multi-step reaction with 2 steps 1: phosphorus tribromide / nitrobenzene / 5.5 h / 170 °C 2: cesium fluoride; tetrakis(triphenylphosphine) palladium(0) / 1,2-dimethoxyethane / 48 h / 100 °C / Inert atmosphere
  • 56
  • [ 15302-99-5 ]
  • [ 25677-69-4 ]
YieldReaction ConditionsOperation in experiment
Multi-step reaction with 3 steps 1: potassium hexacyanoferrate(III); sodium hydroxide / water / 0 °C 2: trichlorophosphate; phosphorus pentachloride / 110 °C 3: tetrakis(triphenylphosphine) palladium(0); sodium carbonate; tetrabutylammomium bromide / water; toluene / 5 h / 100 °C / Inert atmosphere
  • 57
  • [ 25677-69-4 ]
  • chloro-[2-(9-phenyl-1,10-phenanthrolin-2-yl)phenyl]palladium [ No CAS ]
YieldReaction ConditionsOperation in experiment
With dichloro bis(acetonitrile) palladium(II) In chloroform; acetonitrile at 60℃; for 13h;
  • 58
  • [ 29176-55-4 ]
  • [ 98-80-6 ]
  • [ 25677-69-4 ]
YieldReaction ConditionsOperation in experiment
70% With tetrakis(triphenylphosphine) palladium(0); tetrabutylammomium bromide; sodium carbonate In water; toluene at 100℃; for 5h; Inert atmosphere;
46% With tetrakis(triphenylphosphine) palladium(0); sodium carbonate In water; toluene for 48h; Schlenk technique; Reflux; 2.6. General synthesis of phenanthroline ligands General procedure: Diaryl-substituted phenanthrolines were prepared by combining thedihalo-substituted phenanthroline with the appropriate phenylboronicacid in a 100 mL Schlenk flask. The solids were suspended in 30 mL oftoluene and 20 mL of 2 M Na2CO3(aq), then purged with Ar for 15 min.Subsequently, Pd(PPh3)4 (0.175 g, 0.15 mmol) was added to the flask,purged for an additional 15 min, then heated at reflux under Ar whilerapidly stirring. After 48 h, the biphasic mixture was cooled to roomtemperature and the two layers were isolated. The aqueous layer waswashed with dichloromethane and all organic fractions were combined,dried using anhydrous MgSO4, and filtered. The solvent was removedby rotary evaporation, and the solids were recrystallized with minimaltoluene followed by vacuum filtration. If necessary, the volume of theresulting filtrate was reduced and hexanes added to induce precipitation.The mixture was vacuum filtered and resulting white solids were collected. 2.6.1. 2,9-Diphenyl-1,10-phenanthroline (Ph2phen) [43]Starting materials: 2,9-dichloro-1,10-phenanthroline (0.250 g,1.00 mmol), phenyl boronic acid (0.428 g, 3.51 mmol), Pd(PPh3)4(0.175 g, 0.150 mmol). Yield = 0.153 g (0.460 mmol, 46%).
  • 59
  • [ 39588-59-5 ]
  • [ 25677-69-4 ]
YieldReaction ConditionsOperation in experiment
Multi-step reaction with 2 steps 1: trichlorophosphate; phosphorus pentachloride / 110 °C 2: tetrakis(triphenylphosphine) palladium(0); sodium carbonate; tetrabutylammomium bromide / water; toluene / 5 h / 100 °C / Inert atmosphere
  • 60
  • ammonium hexafluorophosphate [ No CAS ]
  • copper(II) nitrate trihydrate [ No CAS ]
  • [ 25677-69-4 ]
  • copper(II) bis(2,9-diphenyl-1,10-phenanthroline) hexafluophosphate [ No CAS ]
YieldReaction ConditionsOperation in experiment
In ethanol; dichloromethane at 20℃; for 144h; Inert atmosphere;
  • 61
  • ammonium hexafluorophosphate [ No CAS ]
  • [{Ir(μ-Cl)(2-(p-tolyl)pyridinato)2}2] [ No CAS ]
  • [ 25677-69-4 ]
  • [iridium(III)(2-( p-tolyl)pyridine)2(2,9-diphenyl-1,10-phenanthroline)]hexafluorophosphate [ No CAS ]
YieldReaction ConditionsOperation in experiment
56% Stage #1: [{Ir(μ-Cl)(2-(p-tolyl)pyridinato)2}2]; 2,9-diphenyl-1,10-phenanthroline In methanol; dichloromethane Inert atmosphere; Reflux; Stage #2: ammonium hexafluorophosphate In water at 20℃;
  • 62
  • [iridium(III)(μ-chloro)(2-phenylpyridine)2]2 [ No CAS ]
  • ammonium hexafluorophosphate [ No CAS ]
  • [ 25677-69-4 ]
  • [ 1443009-63-9 ]
YieldReaction ConditionsOperation in experiment
78.5% Stage #1: [iridium(III)(μ-chloro)(2-phenylpyridine)2]2; 2,9-diphenyl-1,10-phenanthroline In ethylene glycol for 16h; Reflux; Inert atmosphere; Stage #2: ammonium hexafluorophosphate In water Inert atmosphere; Synthesis of [Ir(ppy)2(dmphen)]PF6 (complex 1) General procedure: [Ir(ppy)2Cl]2 (0.069 g, 0.064 mmol)and 2,9-dimethyl-1,10-penanthroline (0.027 mg, 0.128 mmol) were heated to reflux in an ethylene glycol solution (20 ml) for 16 h. The mixture was transferred into a separation funnel with water (90 ml) and washed through three extractions with diethyl ether (60 ml).A concentrated solution of ammonium hexafluorophosphate in water was slowly added intothe aqueous layer, yielding a colored suspension. The precipitate was collected by filtration[13]
Stage #1: [iridium(III)(μ-chloro)(2-phenylpyridine)2]2; 2,9-diphenyl-1,10-phenanthroline In methanol; dichloromethane Inert atmosphere; Reflux; Stage #2: ammonium hexafluorophosphate In methanol; dichloromethane; water Inert atmosphere;
  • 63
  • [ 14592-56-4 ]
  • [ 25677-69-4 ]
  • chloro-[2-(9-phenyl-1,10-phenanthrolin-2-yl)phenyl]palladium [ No CAS ]
YieldReaction ConditionsOperation in experiment
89% In methanol; benzene at 50℃; for 6h;
  • 64
  • [ 14592-56-4 ]
  • [ 25677-69-4 ]
  • dichloro-(2-phenyl-1,10-phenanthroline)palladium [ No CAS ]
YieldReaction ConditionsOperation in experiment
67% In dichloromethane at 40℃; for 4h;
  • 65
  • bis[μ-chloro-bis(2-phenylisoquinolinato-C2,N)iridium(III)] [ No CAS ]
  • ammonium hexafluorophosphate [ No CAS ]
  • [ 25677-69-4 ]
  • C54H36IrN4(1+)*F6P(1-) [ No CAS ]
YieldReaction ConditionsOperation in experiment
58% Stage #1: bis[μ-chloro-bis(2-phenylisoquinolinato-C2,N)iridium(III)]; 2,9-diphenyl-1,10-phenanthroline In methanol; dichloromethane Reflux; Inert atmosphere; Stage #2: ammonium hexafluorophosphate In water
YieldReaction ConditionsOperation in experiment
38% Stage #1: In toluene at 0 - 20℃; for 15h; Inert atmosphere; Stage #2: With manganese(IV) oxide In dichloromethane 2.2.8 2.2 Synthesis of 2,9-di-sec-butyl-1,10-phenanthroline (di-sec-butylphen) (1) General procedure: Compound 1 was synthesized as previously described [ 13] by reacting an anhydrous toluene solution of 1,10-phenanthroline (1.00 g, 4.23 mmol) with sec-butyl-lithium (12.84 ml of 1.45 M, 16.92 mmol). The reaction was stirred at 0° C. under an argon atmosphere and the alkyl-lithium reagent was added in a drop-wise fashion over a 20 minute period. This solution was allowed to stir at room temperature for an additional 15 hours under an inert atmosphere. The reaction mixture was then quenched with H2O (30.0 ml) and the organic layer separated. The aqueous layer was extracted three times with CH2Cl2 (20.0 mL), and the combined organic layers were treated with excess MnO2 (15.0 g). This reaction mixture was stirred overnight and then gravity filtered through celite. This amber filtrate was dried with MgSO4, gravity filtered, and the solvent was removed by rotary evaporation to yield an amber oil. The crude oil was purified by flash chromatography (basic alumina; 100% hexane wash; elution with 20% CH2Cl2 in hexanes) to yield a pale yellow/white solid. 1H NMR chemical shifts, peak multiplicities and peak integrations, and the UV-vis absorption maxima have been previously reported [13].
  • 67
  • tetrakis(acetonitrile)copper(I)tetrafluoroborate [ No CAS ]
  • [ 1219961-25-7 ]
  • [ 25677-69-4 ]
  • Cu(2,9-diphenyl-1,10-phenanthroline)(bis((S)-2-isocyano-3,3-dimethylbutyl)phenylphosphonate)BF<SUB>4</SUB> [ No CAS ]
YieldReaction ConditionsOperation in experiment
In dichloromethane Inert atmosphere;
  • 68
  • tetrakis(acetonitrile)copper(I)tetrafluoroborate [ No CAS ]
  • [ 1219961-25-7 ]
  • [ 25677-69-4 ]
  • C44H45CuN4O3P(1+)*BF4(1-) [ No CAS ]
YieldReaction ConditionsOperation in experiment
In dichloromethane at 20℃; for 2h;
  • 69
  • tetrakis(acetonitrile)copper(I)tetrafluoroborate [ No CAS ]
  • [ 25677-69-4 ]
  • [ 1486481-56-4 ]
  • C44H29CuN4O3P(1+)*BF4(1-) [ No CAS ]
YieldReaction ConditionsOperation in experiment
In dichloromethane at 20℃; for 2h;
  • 70
  • [ 25677-69-4 ]
  • 2,9-diphenyl-1,2,3,4-tetrahydro-1,10-phenanthroline [ No CAS ]
YieldReaction ConditionsOperation in experiment
96% With N-((1R,2R)-2-amino-1,2-diphenylethyl)-3,5-bis(trifluoromethyl)benzenesulfonamide; formic acid; bis[dichloro(pentamethylcyclopentadienyl)iridium(III)] In isopropyl alcohol at 40℃; for 24h; Inert atmosphere; regioselective reaction;
  • 71
  • [iridium(III)(μ-chloro)(2-phenylpyridine)2]2 [ No CAS ]
  • ammonium hexafluorophosphate [ No CAS ]
  • [ 25677-69-4 ]
  • [Ir(2,9-diphenyl-1,10-phenanthroline)(2-phenylpyridine)2](PF6) [ No CAS ]
YieldReaction ConditionsOperation in experiment
Stage #1: [iridium(III)(μ-chloro)(2-phenylpyridine)2]2; 2,9-diphenyl-1,10-phenanthroline In methanol; dichloromethane for 6h; Reflux; Stage #2: ammonium hexafluorophosphate In methanol; dichloromethane; water
  • 72
  • [ 25677-69-4 ]
  • [ 60100-09-6 ]
  • 2,9-diphenyl-1,10-phenanthroline-4,7-dicarboxamide [ No CAS ]
YieldReaction ConditionsOperation in experiment
81% With ammonium peroxydisulfate; benzaldehyde In ethyl acetate at 30℃; for 24h; Irradiation; Sealed tube; Inert atmosphere;
  • 73
  • [ 25677-69-4 ]
  • [ 2923-28-6 ]
  • 2,9-diphenylphenanthroline silver(I) complex [ No CAS ]
YieldReaction ConditionsOperation in experiment
100% In dichloromethane at 20℃; for 0.166667h;
  • 74
  • [ 17084-13-8 ]
  • [ 34795-02-3 ]
  • [ 25677-69-4 ]
  • [Ru(2,2'-bipyridine)2(2,9-diphenyl-1,10-phenanthroline)](PF6)2 [ No CAS ]
YieldReaction ConditionsOperation in experiment
72% Stage #1: cis-dichlorobis(2,2'-bipyridyl)ruthenium(II); 2,9-diphenyl-1,10-phenanthroline In ethylene glycol for 6h; Reflux; Inert atmosphere; Stage #2: potassium hexafluorophosphate In ethylene glycol Inert atmosphere;
  • 75
  • [ 14099-01-5 ]
  • [ 25677-69-4 ]
  • fac-[Re(2,9-diphenyl-1,10-phenanthroline)(CO)3Cl] [ No CAS ]
YieldReaction ConditionsOperation in experiment
56% In toluene for 6h; Schlenk technique; Inert atmosphere; Darkness; Reflux; 2.7. General synthesis of Re(I)-phenanthroline complexes General procedure: Re(R2phen) complexes were prepared by combining Re(CO)5Cl,diaryl-substituted phenanthrolines, and 5 mL toluene in a 50 mLSchlenk flask. The mixture was purged with Ar for 15 min prior toheating at reflux in the dark. After 6 h, the yellow mixture was cooled toroom temperature and 25 mL of hexanes were added to induce furtherprecipitation. The yellow solids were collected by vacuum filtration andrinsed with hexanes. 2.7.1. fac-[Re(Ph2phen)(CO)3Cl] (Re(Ph2phen)) [46]Starting materials: Re(CO)5Cl (0.050 g, 0.14 mmol), Ph2phen(0.045 g, 0.14 mmol). Yellow solid; yield = 0.049 g (0.077 mmol,56%). 1H NMR (500 MHz, 298 K, CDCl3): δ (ppm) = 8.57 (d, 2H,J = 8.3 Hz), 8.06 (s, 2H), 7.94 (d, 2H, J = 8.3 Hz), 7.82-7.74 (broadsinglet, 4H), 7.62-7.58 (m, 6H). FTIR (CH2Cl2) ν(CO): 2024 cm-1,1924 cm-1, 1888 cm-1.
  • 76
  • [ 25677-69-4 ]
  • [ 90076-65-6 ]
  • copper dichloride [ No CAS ]
  • [Cu(2,9-diphenyl-1,10-phenanthroline)2](chloride)(trifluoromethanesulfonimide) [ No CAS ]
YieldReaction ConditionsOperation in experiment
38% Stage #1: 2,9-diphenyl-1,10-phenanthroline; copper dichloride In ethanol at 20℃; for 1.5h; Inert atmosphere; Stage #2: bis(trifluoromethane)sulfonimide lithium In ethanol; water for 3h; Inert atmosphere;
  • 77
  • [ 7681-65-4 ]
  • [ 25677-69-4 ]
  • [ 90076-65-6 ]
  • [Cu(2,9-diphenyl-1,10-phenanthroline)2](trifluoromethanesulfonimide) [ No CAS ]
YieldReaction ConditionsOperation in experiment
50% Stage #1: copper(l) iodide; 2,9-diphenyl-1,10-phenanthroline In ethanol at 20℃; for 1h; Inert atmosphere; Stage #2: bis(trifluoromethane)sulfonimide lithium In ethanol for 2h; Inert atmosphere;
  • 78
  • [ 14104-20-2 ]
  • [ 25677-69-4 ]
  • C8H12CuIN4(1+)*BF4(1-) [ No CAS ]
  • C21H17ClN4Pd [ No CAS ]
  • C47H36CuN7Pd(2+)*2BF4(1-) [ No CAS ]
YieldReaction ConditionsOperation in experiment
94.3% Stage #1: silver tetrafluoroborate; C21H17ClN4Pd In dichloromethane; acetone at 0℃; for 0.25h; Inert atmosphere; Schlenk technique; Stage #2: 2,9-diphenyl-1,10-phenanthroline; C8H12CuIN4(1+)*BF4(1-) In dichloromethane; acetone at 0℃; for 20h; Inert atmosphere; Schlenk technique;
  • 79
  • [ 25677-69-4 ]
  • C17H22CuN7Pd(2+)*2BF4(1-) [ No CAS ]
  • C37H32CuN7Pd(2+)*2BF4(1-) [ No CAS ]
YieldReaction ConditionsOperation in experiment
92.9% In nitromethane; acetonitrile at 0℃; for 20h; Inert atmosphere; Schlenk technique;
  • 80
  • [ 64443-05-6 ]
  • [ 25677-69-4 ]
  • C49H35BF2N6 [ No CAS ]
  • C73H51BCuF2N8(1+)*F6P(1-) [ No CAS ]
YieldReaction ConditionsOperation in experiment
35.6% Stage #1: tetrakis(actonitrile)copper(I) hexafluorophosphate; 2,9-diphenyl-1,10-phenanthroline In dichloromethane at 20℃; for 0.25h; Inert atmosphere; Stage #2: C49H35BF2N6 In dichloromethane at 20℃; Inert atmosphere;
  • 81
  • [ 39069-02-8 ]
  • [ 98-80-6 ]
  • [ 25677-69-4 ]
YieldReaction ConditionsOperation in experiment
69.3% With tetrakis(triphenylphosphine) palladium(0); cesium fluoride In 1,2-dimethoxyethane at 100℃; for 48h; Inert atmosphere;
  • 82
  • zinc(II)-bis(5,15-(2,4,6-trimethylphenyl))porphyrin [ No CAS ]
  • [ 64443-05-6 ]
  • [ 15854-87-2 ]
  • [ 25677-69-4 ]
  • [ 183294-82-8 ]
  • C38H32N4Zn*C5H4IN [ No CAS ]
YieldReaction ConditionsOperation in experiment
In dichloromethane-d2 at 24.84℃;
  • 83
  • [ 64443-05-6 ]
  • [ 25677-69-4 ]
  • [ 85626-37-5 ]
YieldReaction ConditionsOperation in experiment
100 %Spectr. In dichloromethane-d2
  • 84
  • phosphomolybdic heteropolyacid monohydrate [ No CAS ]
  • [ 25677-69-4 ]
  • [ 33513-42-7 ]
  • 3H(1+)*2C24H16N2*2C3H7NO*Mo12O40P(3-) [ No CAS ]
YieldReaction ConditionsOperation in experiment
In chloroform; acetonitrile for 168h;
Same Skeleton Products
Historical Records