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Chemical Structure| 2968-12-9 Chemical Structure| 2968-12-9

Structure of 2968-12-9

Chemical Structure| 2968-12-9

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Product Details of [ 2968-12-9 ]

CAS No. :2968-12-9
Formula : C9H9FOS
M.W : 184.23
SMILES Code : CC(CSC1=CC=CC=C1F)=O
MDL No. :MFCD12145408

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Application In Synthesis of [ 2968-12-9 ]

* All experimental methods are cited from the reference, please refer to the original source for details. We do not guarantee the accuracy of the content in the reference.

  • Downstream synthetic route of [ 2968-12-9 ]

[ 2968-12-9 ] Synthesis Path-Downstream   1~1

  • 1
  • [ 14135-38-7 ]
  • [ 67-64-1 ]
  • [ 2968-12-9 ]
YieldReaction ConditionsOperation in experiment
82% With tert.-butylhydroperoxide; di-tert-butyl peroxide; at 120℃; for 24h; General procedure: Under air atmosphere, disulfides or diselenides (0.3mmol), DTBP (1.0 eq.) TBHP (2.0 eq.) and acetone (2 mL) were added to a screw-cappedvial. The reaction vial was placed in a temperature-controlled aluminum-heatingblock set at 120 oC. The reaction progresswas monitored by TLC. After the completion of the reaction, the vial was removedfrom the heating block and was left to cool to the ambient temperature. Thesolution was filtered though a short column of silica gel and washed withEtOAc. The filtrate was concentrated under reduced pressure to leave a crudeproduct, which was purified by flash column chromatography on silica gel with Petroleumether/EtOAc as an eluent to give the desired product.
 

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