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Chemical Structure| 33240-31-2 Chemical Structure| 33240-31-2

Structure of 33240-31-2

Chemical Structure| 33240-31-2

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Product Details of [ 33240-31-2 ]

CAS No. :33240-31-2
Formula : C14H9I
M.W : 304.13
SMILES Code : IC1=CC=C2C=CC3=C(C=CC=C3)C2=C1
MDL No. :MFCD16876977

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Application In Synthesis of [ 33240-31-2 ]

* All experimental methods are cited from the reference, please refer to the original source for details. We do not guarantee the accuracy of the content in the reference.

  • Downstream synthetic route of [ 33240-31-2 ]

[ 33240-31-2 ] Synthesis Path-Downstream   1~1

  • 1
  • [ 1892-54-2 ]
  • [ 33240-31-2 ]
YieldReaction ConditionsOperation in experiment
45% With tert.-butylnitrite; copper(II) iodide; In acetonitrile; at 0℃; for 1.33333h; General procedure: 3-amino-phenanthrene of 30g (155 mmol), of 36.7g CuBr2 (15 5 mmol) is dissolved in anhydrous acetonitrile 300 ml. Of 40.4ml tert- Butyl nitrile (535 mmol) is added in portions at 0C . The suspension was stirred for an additional hour, then poured into ice-water 400 ml, and stirred for about 20 minutes. The precipitated solid is filtered off with suction, dissolved in dichloromethane, washed several times with water. The organic phase was evaporated in a rotary evaporator is recrystallized from toluene / heptane. A yield of 21.9g (85 mmol) (55% of theory).
 

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