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Chemical Structure| 35648-87-4 Chemical Structure| 35648-87-4

Structure of 35648-87-4

Chemical Structure| 35648-87-4

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Product Details of [ 35648-87-4 ]

CAS No. :35648-87-4
Formula : C14H22O6
M.W : 286.32
SMILES Code : OCCOCCOC1=CC=C(OCCOCCO)C=C1
MDL No. :MFCD01109251

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Application In Synthesis of [ 35648-87-4 ]

* All experimental methods are cited from the reference, please refer to the original source for details. We do not guarantee the accuracy of the content in the reference.

  • Downstream synthetic route of [ 35648-87-4 ]

[ 35648-87-4 ] Synthesis Path-Downstream   1~1

  • 1
  • [ 118591-58-5 ]
  • [ 123-31-9 ]
  • [ 35648-87-4 ]
YieldReaction ConditionsOperation in experiment
73.6% With potassium carbonate; lithium bromide; In acetonitrile; for 24h;Reflux; Inert atmosphere; In a 250 mL three-necked flask, 2.61 g of hydroquinone and 13.12 g of K2CO3 were added, and a vacuum was applied for 3 to 5 times, and a nitrogen-filled cycle was performed.Exhaust oxygen and moisture from the system. Under the protection of nitrogen,12.35 g of diethylene glycol mono-p-toluenesulfonate, 0.02 g of LiBr and 150 mL of anhydrous acetonitrile were added and heated to reflux for 24 h. The reaction is completed,Stop heating. After cooling, it was filtered, and the filter cake was dissolved with water (100 mL).Extracted with CH2Cl2 (100 mL×2), and the organic phase and filtrate were combined.It was steamed to give a dark brown oil. Dissolve the oil with 100 mL of CH 2 Cl 2 ,It was washed with a mixed solution (saturated saline: 1% sodium hydroxide solution = 3:1, 50 mL × 3).Dry over anhydrous magnesium sulfate. Filtered, steamed to a light brown powder,The yield was 73.6%.
 

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