Alternatived Products of [ 37086-84-3 ]
Product Details of [ 37086-84-3 ]
CAS No. : | 37086-84-3 |
MDL No. : | MFCD28363965 |
Formula : |
C10H12O3
|
Boiling Point : |
- |
Linear Structure Formula : | - |
InChI Key : | - |
M.W : |
180.20
|
Pubchem ID : | - |
Synonyms : |
|
Safety of [ 37086-84-3 ]
Signal Word: | |
Class: | |
Precautionary Statements: | |
UN#: | |
Hazard Statements: | |
Packing Group: | |
Application In Synthesis of [ 37086-84-3 ]
* All experimental methods are cited from the reference, please refer to the original source for details. We do not guarantee the accuracy of the content in the reference.
- Downstream synthetic route of [ 37086-84-3 ]
- 1
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[ 2568-25-4 ]
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[ 36220-92-5 ]
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[ 51591-52-7 ]
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[ 7022-98-2 ]
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[ 37086-84-3 ]
- 3
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[ 2568-25-4 ]
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[ 6656-60-6 ]
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[ 51591-52-7 ]
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[ 37086-84-3 ]
- 4
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[ 57-55-6 ]
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[ 93-97-0 ]
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[ 37086-84-3 ]
Yield | Reaction Conditions | Operation in experiment |
91% |
With tetrabutylammonium benzoate In acetonitrile at 40℃; Green chemistry; regioselective reaction; |
4.2 General procedure for regioselective mono benzoylation
General procedure: Diols and polyol reactants (100 mg) were allowed to react with benzoic anhydride (1.1 equiv) in acetonitrile (1 mL) at 40°C for 8-12 h in the presence of TBAOBz (0.2 equiv). The reaction mixture was directly purified by flash column chromatography (hexanes/EtOAc=2:1 to 1:1), affording the pure selectively protected derivatives. |
90% |
With DBN In ethyl acetate at 40℃; Green chemistry; regioselective reaction; |
|
85% |
With N-ethyl-N,N-diisopropylamine In acetonitrile at 40℃; Green chemistry; regioselective reaction; |
|
80% |
With dmap; triethylamine In dichloromethane at 20℃; |
|
Reference:
[1]Zhang, Xiaoling; Ren, Bo; Ge, Jiantao; Pei, Zhichao; Dong, Hai
[Tetrahedron, 2016, vol. 72, # 7, p. 1005 - 1010]
[2]Ren, Bo; Zhang, Mengyao; Xu, Shijie; Gan, Lu; Zhang, Li; Tang, Lin
[European Journal of Organic Chemistry, 2019, vol. 2019, # 29, p. 4757 - 4762]
[3]Ren, Bo; Gan, Lu; Zhang, Li; Yan, Ningning; Dong, Hai
[Organic and Biomolecular Chemistry, 2018, vol. 16, # 31, p. 5591 - 5597]
[4]Liu, Hong-Xin; Dang, Ya-Qian; Yuan, Yun-Fei; Xu, Zhi-Fang; Qiu, Sheng-Xiang; Tan, Hai-Bo
[Organic Letters, 2016, vol. 18, # 21, p. 5584 - 5587]
- 5
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[ 644-32-6 ]
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[ 57-55-6 ]
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[ 37086-84-3 ]
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