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Chemical Structure| 38732-07-9 Chemical Structure| 38732-07-9

Structure of 38732-07-9

Chemical Structure| 38732-07-9

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Product Details of [ 38732-07-9 ]

CAS No. :38732-07-9
Formula : C5H6N2O2
M.W : 126.11
SMILES Code : O=C1C(OC)=CC=NN1
MDL No. :MFCD22491588
InChI Key :TUKSMYRSPINTCE-UHFFFAOYSA-N
Pubchem ID :53733299

Safety of [ 38732-07-9 ]

GHS Pictogram:
Signal Word:Warning
Hazard Statements:H302-H315-H319-H335
Precautionary Statements:P261-P305+P351+P338

Application In Synthesis of [ 38732-07-9 ]

* All experimental methods are cited from the reference, please refer to the original source for details. We do not guarantee the accuracy of the content in the reference.

  • Downstream synthetic route of [ 38732-07-9 ]

[ 38732-07-9 ] Synthesis Path-Downstream   1~3

  • 2
  • C5H5ClN2O2 [ No CAS ]
  • [ 38732-07-9 ]
YieldReaction ConditionsOperation in experiment
87% With hydrogen; triethylamine;palladium 10% on activated carbon; In tetrahydrofuran; at 20℃; under 750.075 Torr; for 2.0h; 5.5 g of this solid are placed in the presence of 1 g palladium (10% on carbon) and 2 g of Et3N in 200 mL of THF. The reaction medium is agitated in a hydrogen atmosphere (lbar) for 2h at ambient temperature. After filtering through celite, the filtrate is concentrated to dryness. 4.5 g of white solid are obtained (yield 87%) . TLC silica gel 60 F 254 Merck, CH2Cl2-MeOH: 90:10, Rf=0.22.
  • 3
  • [ 38732-07-9 ]
  • [ 207998-82-1 ]
YieldReaction ConditionsOperation in experiment
89% This solid is placed in the presence of 39 g (696 mmoles) of KOH in 600 mL water. The reaction medium is agitated overnight at 100C then cooled to 0C and brought to pH 4-5 using an aqueous HCl solution (IN) . The precipitate obtained is filtered then vacuum dried. 4 g of white solid are obtained (yield 89%) . TLC silica gel 60 F 254 Merck,CH2Cl2-MeOH: 90:10, Rf=O.15.
 

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