Home Cart 0 Sign in  

[ CAS No. 41717-32-2 ]

{[proInfo.proName]} ,{[proInfo.pro_purity]}
Cat. No.: {[proInfo.prAm]}
Chemical Structure| 41717-32-2
Chemical Structure| 41717-32-2
Structure of 41717-32-2 * Storage: {[proInfo.prStorage]}

Quality Control of [ 41717-32-2 ]

Related Doc. of [ 41717-32-2 ]

SDS
Alternatived Products of [ 41717-32-2 ]
Alternatived Products of [ 41717-32-2 ]

Product Details of [ 41717-32-2 ]

CAS No. :41717-32-2 MDL No. :MFCD01659779
Formula : C9H5NO Boiling Point : 260.8°C at 760 mmHg
Linear Structure Formula :- InChI Key :-
M.W :143.14 g/mol Pubchem ID :38950
Synonyms :

Safety of [ 41717-32-2 ]

Signal Word:Warning Class:N/A
Precautionary Statements:P280 UN#:N/A
Hazard Statements:H302-H312-H332 Packing Group:N/A
GHS Pictogram:

Application In Synthesis of [ 41717-32-2 ]

  • Downstream synthetic route of [ 41717-32-2 ]

[ 41717-32-2 ] Synthesis Path-Downstream   1~15

  • 1
  • [ 41717-32-2 ]
  • [ 925-90-6 ]
  • [ 91344-52-4 ]
  • 3
  • [ 41717-32-2 ]
  • [ 1875-48-5 ]
  • [ 134965-37-0 ]
  • 4
  • [ 41717-32-2 ]
  • [ 75-36-5 ]
  • [ 91521-13-0 ]
  • [ 91521-14-1 ]
  • [ 91521-12-9 ]
  • 7
  • [ 41717-32-2 ]
  • [ 37586-57-5 ]
  • [ 197971-78-1 ]
  • 8
  • [ 271-89-6 ]
  • [ 19158-51-1 ]
  • [ 41717-32-2 ]
YieldReaction ConditionsOperation in experiment
99% General procedure: With respect to 2 mmol of each alcohol represented by the general formula (1), 4 ml of CH 2 Cl 2 as a solvent, 0.05 equivalent of TEMPO as an N-nitrosyl compound, (A) t-BuOCl, (B) I 2 or (C ) N, N'-diiodo-5,5-dimethylhydantoin (DIH) were mixed in a predetermined amount and stirred for a predetermined time at room temperature.Next, 1.5 equivalents of I 2 and 4 ml of aqueous ammonia were added, and the mixture was stirred at room temperature for 2 hours.
  • 10
  • coumarilic acid amide [ No CAS ]
  • [ 41717-32-2 ]
  • 12
  • [ 41717-32-2 ]
  • [ 106-49-0 ]
  • N2-(4-Methylphenyl)benzo[b]furan-2-carboximidamide [ No CAS ]
  • 13
  • [ 41717-32-2 ]
  • [ 62-53-3 ]
  • [ 72583-88-1 ]
  • 14
  • [ 4265-16-1 ]
  • [ 41717-32-2 ]
YieldReaction ConditionsOperation in experiment
80% With 2,2,6,6-Tetramethyl-1-piperidinyloxy free radical; sodium perchlorate; acetic acid; lithium hexamethyldisilazane; In acetonitrile; for 15h;Electrochemical reaction; General procedure: Preparative electrolysis experiments were performed using 263 APotentiostat/Galvanostat (Princeton Applied Research, USA). 0.1 MNaClO4-CH3CN solution (10 mL) containing aldehydes (1 mmol),TEMPO (0.1 mmol), HMDS (2.5mmol) and AcOH (2.5mmol) was electrolyzedwith stirring in an undivided cell (30 mL) equipped with twoplatinum sheets as anode (1.5 cm2) and cathode (3.0 cm2) respectivelyat a constant potential of 1.5 V vs Ag/Ag+ (0.1MAgNO3 in acetonitrile).The electrode separation was 1 cm. When the reaction was finished,10mL of saturatedNa2SO3 solution was added into the reactionmixtureand stirred for 15 min. Then the mixture was extracted with CH2Cl2(20 mL × 3). The organic layer was dried with anhydrous Na2SO4 andconcentrated in a rotary evaporator. The productswere obtained via purificationof column chromatography and their structures were confirmedby 1H NMR, 13C NMR and MS. NMR was performed on a BrukerAvance III spectrometer. GC-MS was performed on the Thermo TraceISQ instrument with TG 5MS capillary column.
77% With trifluorormethanesulfonic acid; trimethylsilylazide; In acetonitrile; at 20℃; for 0.333333h;Sealed tube; Inert atmosphere; General procedure: To a solution of an aromatic aldehyde 1 (0.500 mmol, 1.0 equiv) and TMSN3 (115 mg, 1.00 mmol,2.0 equiv) in a premixed HFIP/ACN mixture (2.0 mL, 1:1) in a nitrogen-flushed two dram vial wasadded triflic acid (TfOH; 17.7 L, 0.200 mmol, 0.40 equiv) (exotherm and brisk effervescence due tonitrogen gas evolution was immediately observed). The vial was capped and the reaction mixture wasallowed to stir at rt for 20-75 min. The reaction mixture was concentrated under nitrogen. The residueobtained was suspended in CH2Cl2/hexanes mixture and loaded on a silica gel in a 5 g samplecartridge. Purification using a normal phase silica flash column on a CombiFlash purification systemafforded a corresponding aromatic nitrile 2 upon concentration of appropriate fractions.
72% With tert.-butylhydroperoxide; ammonium acetate; iodine; sodium carbonate; In ethanol; at 50℃; for 5h; In a 25 mL two-necked round bottom flask equipped with a thermometer and a magnetic stirrer4 mmolofBenzofuran-2-carbaldehyde (1-19), 6 mmol of NH4OAc, 4 mmol of Na2CO3, 4.4 mmol of TBHP, 0.1 mmol of I2, 5 mL of absolute ethanol Solvent, followed by placing the reaction flask in an oil bath preheated to 50 C and opening the magnetic stirrer for 5 h. The reaction solution By adding sodium thiosulfate solution, stirring, and then extracting with ether, separating the organic layer, and removing the solvent under reduced pressure, The eluate was collected with the mixture of ethyl acetate / petroleum ether in a volume ratio of 1: 100 as the eluent, and the eluate containing the target compound was collected. The solvent was distilled off to give benzofuran-2-carbonitrile with an isolated yield of 72%.
Historical Records

Related Functional Groups of
[ 41717-32-2 ]

Nitriles

Chemical Structure| 50635-21-7

[ 50635-21-7 ]

o-Tolyloxyacetonitrile

Similarity: 0.86

Chemical Structure| 1095085-73-6

[ 1095085-73-6 ]

3-(2-Ethoxyethoxy)benzonitrile

Similarity: 0.79

Chemical Structure| 38791-62-7

[ 38791-62-7 ]

4-Phenoxyphthalonitrile

Similarity: 0.77

Chemical Structure| 60758-86-3

[ 60758-86-3 ]

3-Ethoxy-4-methoxybenzonitrile

Similarity: 0.77

Chemical Structure| 60758-87-4

[ 60758-87-4 ]

3,4-Diethoxybenzonitrile

Similarity: 0.77

Related Parent Nucleus of
[ 41717-32-2 ]

Benzofurans

Chemical Structure| 13391-27-0

[ 13391-27-0 ]

5-Methoxy-2-methylbenzofuran

Similarity: 0.84

Chemical Structure| 79002-39-4

[ 79002-39-4 ]

Benzofuran-5-carbonitrile

Similarity: 0.75

Chemical Structure| 496-16-2

[ 496-16-2 ]

2,3-Dihydrobenzo[b]furan

Similarity: 0.69

Chemical Structure| 50551-63-8

[ 50551-63-8 ]

6-Methoxybenzofuran

Similarity: 0.67

Chemical Structure| 13196-11-7

[ 13196-11-7 ]

Benzofuran-6-ol

Similarity: 0.67