Alternatived Products of [ 42951-39-3 ]
Product Details of [ 42951-39-3 ]
CAS No. : | 42951-39-3 |
MDL No. : | MFCD04972092 |
Formula : |
C17H25N
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Boiling Point : |
- |
Linear Structure Formula : | - |
InChI Key : | MOVCYDNEZZZSLV-UHFFFAOYSA-N |
M.W : |
243.39
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Pubchem ID : | 170708 |
Synonyms : |
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Application In Synthesis of [ 42951-39-3 ]
* All experimental methods are cited from the reference, please refer to the original source for details. We do not guarantee the accuracy of the content in the reference.
- Downstream synthetic route of [ 42951-39-3 ]
Yield | Reaction Conditions | Operation in experiment |
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... falling within the ambit of the formula 1-R8 -pyrrole and carbazole compounds falling within the ambit of the formula 9-R8 -carbazole which are useful in the practice of the processes of this invention for producing the aforesaid methanes and alkanes of Formulas I, XI and XVI. ... 2-Phenylindole, 1-Propyl-2-methylindole, 1-Benzyl-2-methylindole, 1-Butyl-2-methylindole, 1-Octyl-2-methylindole, 2-Ethyl-5-methylindole, 1-Benzyl-5-fluoroindole, 1-Methyl-6-nitroindole, ... |
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The following compounds are exemplary of indoles, pyrroles and carbazoles useful in the practice of this invention. ... 1-Benzyl-2-methylindole, 1-Butyl-2-methylindole, 1-Octyl-2-methylindole, 2-Ethyl-5-methylindole, ... |
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The following compounds are exemplary of indoles useful in the practice of this invention. ... 1,2-Dimethylindole, 1-Ethyl-2-methylindole, 1-Propyl-2-methylindole, 1-Butyl-2-methylindole, 1-Octyl-2-methylindole, 2-Ethylindole, 2-Ethyl-1-methylindole, 1-Isopropylindole, ... |
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The following compounds are exemplary of indoles, pyrroles and carbazoles useful in the practice of this invention. ... 2-Phenylindole, 1-Propyl-2-methylindole, 1-Benzyl-2-methylindole, 1-Butyl-2-methylindole, 1-Octyl-2-methylindole, 2-Ethyl-5-methylindole, 1-Benzyl-5-fluoroindole, 1-Methyl-6-nitroindole, ... |
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The following compounds are exemplary of indoles useful in the practice of this invention. ... 2-Phenylindole, 1-Propyl-2-methylindole, 1-Benzyl-2-methylindole, 1-Butyl-2-methylindole, 1-Octyl-2-methylindole, 2-Ethyl-5-methylindole, 1-Benzyl-5-fluoroindole, 1-Methyl-6-nitroindole, ... |
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2-Methylindol, n-Octylbromid, KOH/DMSO; |
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- 2
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[ 42951-39-3 ]
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1-dicyanomethylene-3-dimethylpropionyliminoisoindoline
[ No CAS ]
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1-Dicyanomethylene-3-(2,2-dimethylpropionylamino)-3-(2-methyl-1-n-octylindol-3-yl)isoindoline
[ No CAS ]
Yield | Reaction Conditions | Operation in experiment |
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With toluene-4-sulfonic acid In acetone; toluene |
1 1-Dicyanomethylene-3-(2,2-dimethylpropionylamino)-3-(2-methyl- 1-n-octylindol-3-yl)isoindoline
Example 1 1-Dicyanomethylene-3-(2,2-dimethylpropionylamino)-3-(2-methyl- 1-n-octylindol-3-yl)isoindoline 2.8 g of 1-dicyanomethylene-3-dimethylpropionyliminoisoindoline are stirred together with 2.43 g of 1-n-octyl-2-methylindole and 0.2 g of p-toluenesulfonic acid in 15 ml of toluene and 10 ml acetone at room temperature for 6 hours. This is followed by concentrating the solvent mixture, resulting in the formation of a precipitate. The precipitate is filtered off, washed with toluene and dried. 3 g of the compound of the formula STR17 are isolated as colourless crystals having a melting point of 178°-179° C. In thermography, this colour former develops a red-violet marking. |
- 3
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[ 85-44-9 ]
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[ 42951-39-3 ]
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[ 60316-84-9 ]
Yield | Reaction Conditions | Operation in experiment |
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15.A EXAMPLE 15
A. Following a procedure similar to that described in Example 14A but employing 7.4 g. of phthalic anhydride and 16.0 g. of 1-n-octyl-2-methylindole there was obtained 6.9 g. of 2-(1-n-octyl-2-methyl-3-indolylcarbonyl)benzoic acid, m.p. 121°-123° C. |
- 4
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[ 42951-39-3 ]
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[ 21528-38-1 ]
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[ 75-36-5 ]
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3-[2,2-bis(1-n-octyl-2-methylindol-3-yl)ethenyl]-3-(4-diethylaminophenyl)phthalide
[ No CAS ]
Yield | Reaction Conditions | Operation in experiment |
60.6% |
With calcium hydroxide; sodium hydroxide; acetic anhydride In methanol; toluene |
12 Example 12
Example 12 Production of 3-[2,2-bis(1-n-octyl-2-methylindol-3-yl)ethenyl]-3-(4-diethylaminophenyl)phthalide First, 48.6 g (0.2 mole) of 1-n-octyl-2-methylindole, 7.85 g (0.1 mole) of acetyl chloride and 30 mL of acetic anhydride were stirred together at 50-55°C for 8 hours. Then, 7.4 g (0.1 mole) of calcium hydroxide, 29.7 g (0.1 mol) of 2-(4-diethylaminobenzoyl)benzoic acid and 50 mL of toluene were added and the mixture was stirred at 60-65°C for 4 hours. After cooling, 250 mL of toluene and 250 g of 10% aqueous sodium hydroxide solution were added and the mixture was stirred at reflux for 1 hour. The toluene layer was then taken, washed with warm water, filtered and concentrated. The residue was stirred with 200 mL of methanol at reflux for 1 hour. After cooling, the precipitate was recovered by filtration and dried to provide 47.8 g (yield 60.6%) of a pale greyish-white powder. m.p. 106-107°C. This product was identified as the object phthalide compound based on the following analyses. MS (m/z): 789 (M+) |
- 5
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[ 111-86-4 ]
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[ 21906-31-0 ]
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[ 42951-39-3 ]
- 6
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C17H26BrN
[ No CAS ]
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[ 42951-39-3 ]
Yield | Reaction Conditions | Operation in experiment |
90 mg |
With copper(l) iodide; K3PO4 In N,N-dimethyl-formamide at 110℃; Inert atmosphere; |
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- 7
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N-(2-chlorophenyl)octylamine
[ No CAS ]
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[ 67-64-1 ]
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[ 42951-39-3 ]
Yield | Reaction Conditions | Operation in experiment |
83% |
at 90℃; for 16h; Sealed tube; Inert atmosphere; |
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- 8
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[ 615-41-8 ]
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[ 42951-39-3 ]
Yield | Reaction Conditions | Operation in experiment |
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Multi-step reaction with 2 steps
1: C39H51ClNOPPd; N-[2-(di(1-adamantyl)phosphino)phenyl]morpholine; caesium carbonate / toluene / 6 h / 90 °C / Sealed tube; Inert atmosphere
2: 16 h / 90 °C / Sealed tube; Inert atmosphere |
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- 9
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[ 111-86-4 ]
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[ 615-41-8 ]
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[ 67-64-1 ]
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[ 42951-39-3 ]
Yield | Reaction Conditions | Operation in experiment |
44% |
With N-[2-(di(1-adamantyl)phosphino)phenyl]morpholine; C39H51ClNOPPd; caesium carbonate In toluene at 90℃; for 16h; |
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- 10
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[ 111-86-4 ]
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[ 694-80-4 ]
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[ 67-64-1 ]
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[ 42951-39-3 ]
Yield | Reaction Conditions | Operation in experiment |
62% |
With N-[2-(di(1-adamantyl)phosphino)phenyl]morpholine; C39H51ClNOPPd; caesium carbonate In toluene at 90℃; for 16h; |
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- 11
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[ 111-86-4 ]
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[ 42951-39-3 ]
Yield | Reaction Conditions | Operation in experiment |
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Multi-step reaction with 2 steps
1: C39H51ClNOPPd; N-[2-(di(1-adamantyl)phosphino)phenyl]morpholine; caesium carbonate / toluene / 6 h / 90 °C / Sealed tube; Inert atmosphere
2: 16 h / 90 °C / Sealed tube; Inert atmosphere |
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