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[ CAS No. 4671-77-6 ] {[proInfo.proName]}

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Chemical Structure| 4671-77-6
Chemical Structure| 4671-77-6
Structure of 4671-77-6 * Storage: {[proInfo.prStorage]}
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Product Details of [ 4671-77-6 ]

CAS No. :4671-77-6 MDL No. :MFCD01631212
Formula : C4H12O6P2 Boiling Point : -
Linear Structure Formula :- InChI Key :JKTORXLUQLQJCM-UHFFFAOYSA-N
M.W : 218.08 Pubchem ID :437082
Synonyms :

Safety of [ 4671-77-6 ]

Signal Word:Danger Class:8
Precautionary Statements:P501-P260-P234-P264-P280-P390-P303+P361+P353-P301+P330+P331-P363-P304+P340+P310-P305+P351+P338+P310-P406-P405 UN#:3261
Hazard Statements:H314-H290 Packing Group:
GHS Pictogram:

Application In Synthesis of [ 4671-77-6 ]

* All experimental methods are cited from the reference, please refer to the original source for details. We do not guarantee the accuracy of the content in the reference.

  • Downstream synthetic route of [ 4671-77-6 ]

[ 4671-77-6 ] Synthesis Path-Downstream   1~49

  • 2
  • [ 4671-77-6 ]
  • [ 7203-67-0 ]
  • [ 1660-97-5 ]
YieldReaction ConditionsOperation in experiment
(i) (heating), (ii) PCl5; Multistep reaction;
  • 3
  • 1,4-butanediphosphonous acid [ No CAS ]
  • [ 4671-77-6 ]
YieldReaction ConditionsOperation in experiment
With dihydrogen peroxide
YieldReaction ConditionsOperation in experiment
Cl2-P(O)-(CH2)4-(O)PCl2, H2O2;
Cl2-P(O)-(CH2)4-(O)PCl2, Cl2, H2O;
1,4-Dibrom-butan, 1. Na-diethylphosphit, Ae., Rueckfluss, -> Ester, 2. konz.HCl, Hydrolyse;
1,4-Dibrom-butan, 1. K-diethylphosphit, Ae., Rueckfluss, -> Ester, 2. konz.HCl, Hydrolyse;
1,4-Dibrom-butan, 1. Na-diethylphosphit, Diglym, Rueckfluss, -> Ester, 2. konz.HCl, Hydrolyse;
1,4-Dibrom-butan, 1. K-diethylphosphit, Diglym, Rueckfluss, -> Ester, 2. konz.HCl, Hydrolyse;
aus dem Ester;

  • 5
  • [ 2917-47-7 ]
  • [ 4671-77-6 ]
  • di-[3-(trimethylsilyl)-1-propylene]butylenediphosphonic acid [ No CAS ]
YieldReaction ConditionsOperation in experiment
57% With dicyclohexyl-carbodiimide In tetrahydrofuran for 75h; Heating;
  • 6
  • zinc perchlorate [ No CAS ]
  • [ 4671-77-6 ]
  • 2Zn(2+)*O3P(CH2)4PO3(4-)*2H2O=Zn2{O3P(CH2)4PO3}*2H2O [ No CAS ]
YieldReaction ConditionsOperation in experiment
In water the aq. soln. of Zn(ClO4)*6H2O is added to the stirred acidic soln. (aq. HCl) of the bisphosphonic acid, to which 2 M NaOH is subsequently added; product is filtd., washed with water/ethanol, dried in air;
  • 7
  • [ 366-18-7 ]
  • copper(ll) sulfate pentahydrate [ No CAS ]
  • [ 7631-95-0 ]
  • [ 4671-77-6 ]
  • [ 7732-18-5 ]
  • [(Cu(2,2'-bipyridine)2)(Cu(2,2'-bipyridine)(H2O))(Mo5O15)(O3PCH2CH2CH2CH2PO3)]*H2O [ No CAS ]
YieldReaction ConditionsOperation in experiment
25% In water High Pressure; hydrothermal; at 180°C for 39 h, Cu:Mo:bpy:acid:H2O=1.0:1.7:1.9:2.5:3760;
  • 8
  • [ 366-18-7 ]
  • copper(ll) sulfate pentahydrate [ No CAS ]
  • [ 7631-95-0 ]
  • [ 4671-77-6 ]
  • [(Cu(2,2'-bipyridine)2)(Cu(2,2'-bipyridine)(H2O))(Mo5O15)(O3PCH2CH2CH2CH2PO3)]*H2O [ No CAS ]
YieldReaction ConditionsOperation in experiment
30% In water soln. CuSO4*5H2O, Na2MoO4*2H2O, 2,2'-bipyridine, 1,4-butylene diphosphonic acid, and water was heated to 180°C for 39 h; elem. anal.;
  • 9
  • nickel(II) chloride hexahydrate [ No CAS ]
  • [ 4671-77-6 ]
  • [Ni(H2O)6][1,4-butylenediphosphonate]*2H2O [ No CAS ]
YieldReaction ConditionsOperation in experiment
36% With NaOH In water; dimethyl sulfoxide to aq. soln. of NiCl2*6H2O and 1,4-butylenediphosphonic acid added aq. NaOH and then added DMSO with vigorous stirring; soln. filtered; compd. crystd. for 40 d; crystals filtered and dried at ambient temp.; elem. anal.;
  • 10
  • copper(II) choride dihydrate [ No CAS ]
  • [ 4671-77-6 ]
  • [Cu2(H2O)2(1,4-butylenediphosphonate)*H2O] [ No CAS ]
YieldReaction ConditionsOperation in experiment
6.9% In sodium hydroxide; water; dimethyl sulfoxide aq. NaOH; to aq. soln. of CuCl2*6H2O and 1,4-butylenediphosphonic acid added DMSO and then added aq. NaOH; soln. filtered and left at ambient temp. for 40d; crystals filtered, washed with water, dried at ambient temp.; elem. anal.;
  • 11
  • copper(II) choride dihydrate [ No CAS ]
  • [ 4671-77-6 ]
  • [Cu(H2O)2(1,4-butylenediphosphonate)] [ No CAS ]
YieldReaction ConditionsOperation in experiment
10% With NaOH In water; isopropyl alcohol to aq. soln. of NiCl2*6H2O and 1,4-butylenediphosphonic acid added aq. NaOH; soln. filtered and layered with isopropyl alc. and left at ambient temp. for 110 d; crystals filtered, washed with water, ethanol, ether and dried at ambient temp.; elem. anal.;
  • 12
  • copper(II) choride dihydrate [ No CAS ]
  • sodium metavanadate dihydrate [ No CAS ]
  • [ 4671-77-6 ]
  • [ 5144-89-8 ]
  • [[Cu2(1,10-phenanthroline)2][V2O4][O3P(CH2)4PO3H]2] [ No CAS ]
YieldReaction ConditionsOperation in experiment
90% In water hydrothermal reaction, Cu:V:1,10-phen:P-compd:H2O molar ratio was 1:1:1:2:556, 120 °C for 72 h; washing with H2O, drying at ambient temp., elem. anal.; some amt. of unknown product was also formed;
  • 13
  • [ 4671-77-6 ]
  • [ 25005-97-4 ]
  • [ 7732-18-5 ]
  • [ 6046-93-1 ]
  • molybdenum(VI) oxide [ No CAS ]
  • [(Cu2(tetra-2-pyridylpyrazine)(H2O)2)Mo5O15(O3P(CH2)4PO3)]*0.33H2O [ No CAS ]
YieldReaction ConditionsOperation in experiment
60% With HF In water by the react. of MoO3 (1.112 mmol), Cu-contg. compd. (0.451 mmol), ligand (0.224 mmol), H2PO3(CH2)4PO3H2 (0.440 mmol), H2O (557 mmol) and HF washeated at 150°C for 72 h; initial pH 1.5; final pH 1.0;
  • 14
  • sodium metavanadate dihydrate [ No CAS ]
  • [ 4671-77-6 ]
  • [ 7732-18-5 ]
  • [ 6147-53-1 ]
  • [ 5144-89-8 ]
  • [(Co(1,10-phenanthroline)2)2(V4O10)(1,4-butylenediphosphonate)(H2O)2]n [ No CAS ]
YieldReaction ConditionsOperation in experiment
50% In water High Pressure; hydrothermal synthesis; mixt. of Co acetate, NaVO3, phenanthroline, 1,4-butylenediphosphonic acid, and H2O (molar ratio: 1:2:2:2:556) heated at 120°C for 72 h; cooled to room temp., ppt. isolated; elem. anal.;
  • 15
  • [ 7631-95-0 ]
  • [ 4671-77-6 ]
  • [ 6147-53-1 ]
  • [ 5144-89-8 ]
  • molybdenum(VI) oxide [ No CAS ]
  • [(Co(1,10-phenanthroline)2(H2O)2)(Co(1,10-phenathroline)2(H2O))((Mo5O15)(O3PCH2CH2CH2CH2PO3)))*(6H2O)] [ No CAS ]
YieldReaction ConditionsOperation in experiment
40% In water High Pressure; Co(OAC)2*4H2O, Na2MoO4, MoO3, 1,10-phenanthroline, P compd. and distd. water homogenized and heated at 180°C for 72 h in Teflon-lined stainless steel vessel under autogenous pressure; elem. anal.;
  • 16
  • [ 553-26-4 ]
  • cobalt(II) sulphate heptahydrate [ No CAS ]
  • [ 4671-77-6 ]
  • ([Co(4,4'-bipyridine)(1,4-buthylenediphosphonate)(H2O)2]*4H2O)n [ No CAS ]
YieldReaction ConditionsOperation in experiment
25% With aq. NaOH In water Co, P and org. compds. dissolved in water, pH adjusted to 4.13 with 1 M aq. NaOH; filtered, dried in desiccator filled with silica gel for 3 mo, cryst. washed with water, dried at ambient temp., elem. anal.;
  • 17
  • cobalt(II) sulphate heptahydrate [ No CAS ]
  • [ 4671-77-6 ]
  • [Co(H2O)6][1,4-butylenediphosphonate]*2H2O [ No CAS ]
YieldReaction ConditionsOperation in experiment
With NaOH In water; dimethyl sulfoxide to aq. soln. of CoSO4*7H2O and 1,4-butylenediphosphonic acid added aq. NaOH and then added DMSO with vigorous stirring; compd. crystd. after 70 d; elem. anal.;
  • 18
  • zinc(II) sulfate heptahydrate [ No CAS ]
  • [ 4671-77-6 ]
  • [Zn(1,4-butylenediphosphonate)]*2H2O [ No CAS ]
YieldReaction ConditionsOperation in experiment
18% With urea In sodium hydroxide; water aq. NaOH; to aq. soln. of ZnSO4*7H2O and 1,4-butylenediphosphonic acid added aq. NaOH; urea added to soln. and dissolved; soln. filtered and left at 55°C for 24 h; crystals filtered, washed with water and dried at ambient temp.; elem. anal.;
  • 19
  • [ 4671-77-6 ]
  • [ 7646-85-7 ]
  • [Zn(1,4-butylenediphosphonate)]*2H2O [ No CAS ]
YieldReaction ConditionsOperation in experiment
In hydrogenchloride; water; dimethyl sulfoxide ZnCl2, 1,4-butylenediphosphonic acid and small amt. of aq. HCl mixed in water and DMSO added to soln. with stirring then aq. NaOH added to soln.; soln. filtered and left at ambient environment for 6 mo; crystals filtered, washed with water and dried at ambient temp.; elem. anal.;
  • 20
  • hexaammonium heptamolybdate tetrahydrate [ No CAS ]
  • [ 874672-21-6 ]
  • [ 4671-77-6 ]
  • [ 7732-18-5 ]
  • [ 6018-89-9 ]
  • [(Ni2(tetra-2-pyridinylpyrazine)2)Mo5O15(O3P(CH2)4PO3)]*6.65H2O [ No CAS ]
YieldReaction ConditionsOperation in experiment
20% With HF In water High Pressure; under conventional hydrothermal conditions; Mo compd., Ni salt, ligand, H2PO3(CH2)4PO3H2, H2O (molar ratio 0.47:1.29:1.00:2.03:2482) and HF heated in stainless steel container at 200°C for 96 h;
  • 21
  • nickel(II) sulfate hexahydrate [ No CAS ]
  • hexaammonium heptamolybdate tetrahydrate [ No CAS ]
  • [ 874672-21-6 ]
  • [ 4671-77-6 ]
  • [ 7732-18-5 ]
  • [(Ni2(tetra-2-pyridinylpyrazine)(H2O)2)Mo5O15(O3P(CH2)4PO3)]*2.25H2O [ No CAS ]
YieldReaction ConditionsOperation in experiment
65% With HF In water High Pressure; under conventional hydrothermal conditions; Mo compd., Ni salt, ligand, H2PO3(CH2)4PO3H2, H2O (molar ratio 0.72:2.01:1.00:2.01:2543) and HF stirred briefly; heated in stainless steel container at 200°C for 96 h;
  • 22
  • Sodium orthovanadate [ No CAS ]
  • [ 4671-77-6 ]
  • [ 128143-86-2 ]
  • copper(II) oxide [ No CAS ]
  • [(Cu2(2,2':4':2'',2'''-quarterpyridyl-6',6''-di-2-pyridine))V2O4(OH)2(O3P(CH2)4PO3)]*4H2O [ No CAS ]
YieldReaction ConditionsOperation in experiment
95% With HF In water High Pressure; mixt. Na3VO4, CuO, bisterpy, H2O3P(CH2)4PO3H2, water, and HF (5.05:2.06:1.00:5.11:4002:47.50) (pH 2.0) was heated to 120°C for 72 h in poly(tetrafluoroethylene) lined stainless steel autoclave under autogenouspressure;
  • 23
  • [ 4671-77-6 ]
  • [ 7664-39-3 ]
  • [ 128143-86-2 ]
  • vanadia [ No CAS ]
  • [ 6046-93-1 ]
  • [(Cu2(2,2':4',4'':2'',2'''-quaterpyridyl-6',6''-di-2-pyridine))V4F2O6(O3P(CH2)4PO3)2] [ No CAS ]
YieldReaction ConditionsOperation in experiment
20% In water High Pressure; mixt. V2O5, Cu(OAc)2*H2O, bisterpy, 1,4-butylenediphosphonic acid, waterand hydrofluoric acid (1.94:1.94:1.00:3.80:3800:39.8) was heated in pol y(tetrafluoroethylene) lined stainless steel container to 200°C for 72 h;
  • 24
  • [ 1148-79-4 ]
  • copper(ll) sulfate pentahydrate [ No CAS ]
  • Sodium orthovanadate [ No CAS ]
  • [ 4671-77-6 ]
  • [(Cu(2,2':6':2''-terpyridine)(H2O))(V3O6)(O3PCH2CH2CH2CH2PO3)] [ No CAS ]
YieldReaction ConditionsOperation in experiment
5% In water High Pressure; soln. CuSO4*5H2O, Na3VO4, terpy and 1,4-butylene diphosphonic acid in water was heated in polytetrafluoroethylene-lined stainless steel autoclave to 120°C for 4 days;
  • 25
  • [ 4671-77-6 ]
  • [ 7664-39-3 ]
  • [ 7732-18-5 ]
  • vanadia [ No CAS ]
  • [ 107-15-3 ]
  • [ethylenediamine(+2H)][V2O2F2(H2O)2(O3P(CH2)4PO3)] [ No CAS ]
YieldReaction ConditionsOperation in experiment
60% In water High Pressure; soln. of V2O5 (0.99 equiv.), P acid (1 equiv.), H2O (297 equiv.), diamine (1.35 equiv.) and HF (7.75 equiv.) was stirred before heating to 180°C for 96 h;
  • 26
  • [ 110-85-0 ]
  • [ 4671-77-6 ]
  • [ 7732-18-5 ]
  • vanadia [ No CAS ]
  • H2N(CH2CH2)2NH2(2+)*2VO(2+)*2HO3P(CH2)4PO3(3-)=(NH2(CH2CH2)2NH2)V2O2(HO3P(CH2)4PO3)2 [ No CAS ]
YieldReaction ConditionsOperation in experiment
65% With HF In water High Pressure; stainless steel container, autogenous pressure, a soln. of V2O5, phosphonic acid, H2O, diamine and HF (1.92:1.00:1459:3.08:15.2 mole ratio) was stirred briefly before heating to 180°C for 96 h with initial andfinal pH values 3.0 and 3.0;
  • 27
  • ammonium vanadate(V) [ No CAS ]
  • [ 4671-77-6 ]
  • [ 7732-18-5 ]
  • 2VO(2+)*4H2O*O3P(CH2)4PO3(4-)=V2O2(H2O)(O3P(CH2)4PO3)*3H2O [ No CAS ]
YieldReaction ConditionsOperation in experiment
85% With HF In water High Pressure; stainless steel container, autogenous pressure, a soln. of NH4VO3, phosphonic acid, H2O and HF (0.95:1.00:557:9.0 mole ratio) was stirred briefly before heating to 200°C for 96 h with initial and final pH values 1.5 and 2.0;
  • 28
  • [ 4671-77-6 ]
  • [ 5970-45-6 ]
  • sodium trizinc (1,4-butylenediphosphonate(3-))(1,4-butylendiphosphonate(4-)) [ No CAS ]
YieldReaction ConditionsOperation in experiment
58% With H2N(CH2)4)NH2*2HCl; (CH3)4NBr; NaF In water; acetic acid High Pressure; mixt. of Zn acetate, diphosphonic acid, H2N(CH2)4NH2*2HCl, Me4NBR, NaF, AcOH and water in molar ratio of 1:2:2:2:8:210:440 heated at 180°C for 72 h; allowed to cool slowly to ambient temp., crystals filtered off, washed with water, dried at ambient temp.; elem. anal.;
  • 29
  • γ-zirconium phosphate dihydrogenphosphate dihydrate [ No CAS ]
  • [ 4671-77-6 ]
  • ZrPO4[O2P(OH)C4H8(OH)PO2]0.5*H2O, γ [ No CAS ]
YieldReaction ConditionsOperation in experiment
In water; acetone contacting ZrPO4O2P(OH)2*2H2O twice with water/acetone soln. of H2O3PC3H7 (80°C, each contact 10 d), maintaining solid in a hydrothermal bomb containing oxygen free water soln. of butyldiphosphonic acid (3 d, 60°C);
  • 30
  • [ 553-26-4 ]
  • copper(ll) sulfate pentahydrate [ No CAS ]
  • [ 4671-77-6 ]
  • [ 7732-18-5 ]
  • [Cu(4,4'-bipyridine)(H2O)2(HO3P(CH2)4PO3H)] [ No CAS ]
YieldReaction ConditionsOperation in experiment
45% With HCl In water High Pressure; Cu compd. (0.52 mmol), bpy (0.52 mmol), and P compd. (0.30 mmol) in water, 3 drops of HCl added, briefly stirred, heated at 200°C for 48 h;
  • 31
  • [ 4671-77-6 ]
  • [ 25005-97-4 ]
  • [ 6147-53-1 ]
  • molybdenum(VI) oxide [ No CAS ]
  • [(Co2(tetra-2-pyridylpyrazine)(H2O)2)Mo5O15(O3P(CH2)4PO3)]*2H2O [ No CAS ]
YieldReaction ConditionsOperation in experiment
35% In water; acetic acid High Pressure; mixt. MoO3, Co(OAc)2*4H2O, tetra-2-pyridylpyrazine, H2PO3(CH2)4PO3H2, concd. AcOH and water (4.90:1.01:1.00:2.01:2511) was heated at 200°C for 96 h in poly(tetrafluoroethylene)-lined stainless steel container;
  • 32
  • [ 4671-77-6 ]
  • [ 6046-93-1 ]
  • [ 34671-83-5 ]
  • molybdenum(VI) oxide [ No CAS ]
  • [(Cu2(2,2'-bipyrimidine)(water)4)Mo5O15(O3P(CH2)4PO3)]*4H2O [ No CAS ]
YieldReaction ConditionsOperation in experiment
62% With HF In hydrogen fluoride aq. HF; High Pressure; adjusting pH of 6.1:1.9:1:2 mixt. of molybdenum trioxide, copper acetate, bipyrimidine and phosphonic acid deriv. in water to 2 by aq. HF, stirring, heating at 120°C for 96 h; isolation of crystals, elem. anal.;
  • 33
  • [ 146406-75-9 ]
  • [ 4671-77-6 ]
  • [ 7664-39-3 ]
  • [ 6046-93-1 ]
  • molybdenum(VI) oxide [ No CAS ]
  • [Cu4(H2O)2(1,4-bis(2,2':6',2''-terpyridin-4'-yl)benzene)2(1,4-butylenediphosphonate)2(Mo4O21F)2]*4H2O [ No CAS ]
  • [Cu4(H2O)2(1,4-bis(2,2':6',2''-terpyridin-4'-yl)benzene)2(1,4-butylenediphosphonate)2(Mo4O21F)2]*6H2O [ No CAS ]
  • 34
  • [ 110-52-1 ]
  • [ 122-52-1 ]
  • [ 4671-77-6 ]
YieldReaction ConditionsOperation in experiment
55% Stage #1: 1,4-dibromo-butane; triethyl phosphite for 0.0833333h; Microwave irradiation; Stage #2: With water; hydrogen bromide for 0.0833333h; Microwave irradiation;
  • 35
  • [ 944540-10-7 ]
  • [ 4671-77-6 ]
  • [ 7732-18-5 ]
  • [ 6046-93-1 ]
  • molybdenum(VI) oxide [ No CAS ]
  • (Cu2(N1,N1,N7,N7-tetrakis(pyridin-2-ylmethyl)-pentane-1,5-diamine)(H2O))Mo6O18(1,4-butylenediphosphonic acid(4-))*14H2O [ No CAS ]
YieldReaction ConditionsOperation in experiment
45% With HF In water High Pressure; Cu-compd., MoO3, P-compd., diamine-compd. in H2O with HF stirred for 15 min before heating to 100°C for 48 h, cooled to room temp.; elem. anal.;
  • 36
  • [ 944540-11-8 ]
  • [ 4671-77-6 ]
  • [ 7732-18-5 ]
  • [ 6046-93-1 ]
  • molybdenum(VI) oxide [ No CAS ]
  • (Cu2(N1,N1,N7,N7-tetrakis(pyridin-2-ylmethyl)-heptane-1,7-diamine)(H2O)2)Mo5O15(1,4-butylenediphosphonic acid(4-))*2H2O [ No CAS ]
YieldReaction ConditionsOperation in experiment
38% With HF In water High Pressure; Cu-compd., MoO3, P-compd., diamine-compd. in H2O with HF stirred brieflybefore heating to 100°C for 48 h; elem. anal.;
  • 37
  • [ 4671-77-6 ]
  • [ 7732-18-5 ]
  • [ 5970-45-6 ]
  • C4H10O6P2(2-)*Zn(1+)*2H2O [ No CAS ]
YieldReaction ConditionsOperation in experiment
With acetic acid
  • 38
  • [ 4671-77-6 ]
  • [ 7664-39-3 ]
  • [ 7732-18-5 ]
  • [ 128143-86-2 ]
  • [ 6046-93-1 ]
  • molybdenum(VI) oxide [ No CAS ]
  • [{Cu2(2,2′:4′,4″:2″,2′″-quarterpyridyl-6′,6″-di-2-pyridine)(H2O)2}Mo2F6O4{dihydro-1,4-butylenediphosphonato}]*2H2O [ No CAS ]
  • [{Cu2(2,2′:4′,4″:2″,2′″-quarterpyridyl-6′,6″-di-2-pyridine)(H2O)}Mo5O15{1,4-butylenediphosphonato}]·4.5H2O [ No CAS ]
YieldReaction ConditionsOperation in experiment
1: 50% 2: 30% at 150℃; for 48h; High pressure; 2 2.2 Synthesis of [{Cu2(bisterpy)(H2O)}Mo5O15{O3P(CH2)4PO3}]·4.5H2O (1·4.5H2O) and [{Cu2(bisterpy)(H2O)2}Mo2F6O4{HO3P(CH2)4PO3H}] (6) A solution of cupric acetate (0.045 g, 0.2263 mmol), molybdenum(VI) oxide (0.087 g, 0.6034 mmol), bisterpy (0.050 g, 0.1078 mmol), 1,4-butylenediphosphonic acid (0.059 g, 0.2694 mmol), H2O (10.00 g, 556 mmol), and HF (0.300 mL, 17.24 mmol) with the mole ratio 2.10:5.60:1.00:2.50:5157.70:159.93 was stirred briefly before heating to 150 °C for 48 h with initial and final pH values of 1.5 and 1.0, respectively. Blue and green crystals were isolated in 30% and 50% yield, respectively, that were suitable for X-ray diffraction. IR (KBr pellet, cm-1): 1·4.5H2O: 3423(m), 1606(m), 1561(m), 1476(m), 1409(m), 1248(w), 1159(w), 952(m), 912(s), 793(m), 671(w), 580(m); 6·2H2O: 3447(m), 1607(m), 1552(w), 1476(m), 1409(m), 1248(w), 1158(w), 949(m), 912(s), 793(m), 671(w), 580(m). Anal. Calc. for 1, Mo5Cu2P2C34H39N6O26.5: C, 25.1; H, 2.40; N, 5.17. Found: C, 24.7; H, 2.55; N, 5.05%. Anal. Calc. for 6, Mo2Cu2P2C34H34N6O12F6: C, 33.6; H, 2.54; N, 6.92; F, 9.39. Found: C, 33.5; H, 2.61; N, 7.04; F, 9.13%.
  • 39
  • [ 66-71-7 ]
  • zinc uranyl acetate heptahydrate [ No CAS ]
  • [ 4671-77-6 ]
  • Zn(phen)(H<SUB>2</SUB>O)<SUB>2</SUB>(UO<SUB>2</SUB>)<SUB>3</SUB>(BDP)<SUB>2</SUB> [ No CAS ]
YieldReaction ConditionsOperation in experiment
In water at 160℃; for 48h; Autoclave;
  • 40
  • [ 4671-77-6 ]
  • [ 7732-18-5 ]
  • [ 5970-45-6 ]
  • [Zn(1,4-butylenediphosphonate)]*2H2O [ No CAS ]
YieldReaction ConditionsOperation in experiment
With acetic acid for 48h;
  • 41
  • [ 4671-77-6 ]
  • [ 7732-18-5 ]
  • [ 5970-45-6 ]
  • 8H2O*5Zn(2+)*2C4H8O6P2(4-)*C4H10O6P2(2-) [ No CAS ]
YieldReaction ConditionsOperation in experiment
With acetic acid for 336h;
  • 42
  • [ 366-18-7 ]
  • zinc uranyl acetate heptahydrate [ No CAS ]
  • [ 4671-77-6 ]
  • Zn2(2,2′-bipyridine)2(UO2)3(H-butane-1,4-diyldiphosphonate)2(H2-butane-1,4-diyldiphosphonate)2 [ No CAS ]
YieldReaction ConditionsOperation in experiment
61% In water at 160℃; for 48h; Autoclave;
  • 43
  • [ 66-71-7 ]
  • zinc uranyl acetate heptahydrate [ No CAS ]
  • [ 4671-77-6 ]
  • Zn(2,2′-bipyridine)(UO2)(propane-1,3-diyldiphosphonate) [ No CAS ]
YieldReaction ConditionsOperation in experiment
41% In water at 180℃; for 72h; Autoclave;
  • 44
  • mercury(I) perchlorate tetrahydrate [ No CAS ]
  • [ 4671-77-6 ]
  • mercurous 1,4-butylenediphosphonate [ No CAS ]
YieldReaction ConditionsOperation in experiment
With perchloric acid In methanol; water; butan-1-ol Schlenk technique; 2.2 Single crystal growth General procedure: For Hg2(HO3P(C6H4)PO3H)(2) compound, Hg2(ClO4)2·4H2O (0.2254g, 0.335mmol), was dissolved in 2mL of concentrated perchloric acid and later diluted to 10mL with distilled water. This acidic aqueous solution was layered with a homogenous mixture of 10mL n-butanol and 1.5mL water. On its top, a 5mL methanol solution of 1,4-phenylenebisphosphonic acid (0.0798g, 0.335mmol) was added slowly using a syringe. Crystals of compound 2 were formed at the butanol-water interphase as well as at the inner walls of Schlenk tube in butanol layer. After a period of two weeks, the aqueous acidic solution was syringed out and the crystals were filtered and air-dried. (0014) The crystal growth experiments for the remaining four mercurous diphosphonates, 3, 4, 6 and 7, were carried out in a similar way. The respective quantities of Hg2(ClO4)2·4H2O and the corresponding phosphonic/bisphosphonic acid employed were 0.1212g (0.180mmol) and 0.0566g (0.180mmol) for compound 3, 0.1372g (0.204mmol) and 0.0445g (0.204mmol) for compound 4, 0.124g (0.184mmol) and 0.0349g (0.184mmol) for compound 6 and 0.152g (0.226mmol) and 0.0461g (0.226mmol) for compound 7.
  • 45
  • rubidium carbonate [ No CAS ]
  • [ 4671-77-6 ]
  • molybdic acid [ No CAS ]
  • Rb<SUB>2</SUB>(Mo<SUB>2</SUB>O<SUB>5</SUB>)(O<SUB>3</SUB>P(CH<SUB>2</SUB>)<SUB>4</SUB>PO<SUB>3</SUB>) [ No CAS ]
YieldReaction ConditionsOperation in experiment
48% In water at 200℃;
  • 46
  • [ 4671-77-6 ]
  • molybdic acid [ No CAS ]
  • [ 534-17-8 ]
  • Cs<SUB>2</SUB>(Mo<SUB>2</SUB>O<SUB>5</SUB>)(O<SUB>3</SUB>P(CH<SUB>2</SUB>)<SUB>4</SUB>PO<SUB>3</SUB>) [ No CAS ]
YieldReaction ConditionsOperation in experiment
50% In water at 200℃;
  • 47
  • [ 4671-77-6 ]
  • [ 506-87-6 ]
  • molybdic acid [ No CAS ]
  • (NH<SUB>4</SUB>)<SUB>2</SUB>(Mo<SUB>2</SUB>O<SUB>5</SUB>)(O<SUB>3</SUB>P(CH<SUB>2</SUB>)<SUB>4</SUB>PO<SUB>3</SUB>) [ No CAS ]
YieldReaction ConditionsOperation in experiment
45% In water at 200℃;
  • 48
  • [ 4671-77-6 ]
  • molybdic acid [ No CAS ]
  • [ 584-08-7 ]
  • K<SUB>2</SUB>(Mo<SUB>2</SUB>O<SUB>5</SUB>)(O<SUB>3</SUB>P(CH<SUB>2</SUB>)<SUB>4</SUB>PO<SUB>3</SUB>) [ No CAS ]
YieldReaction ConditionsOperation in experiment
48% In water at 200℃;
  • 49
  • [ 4671-77-6 ]
  • Na9[A-α-PW9O34]*7H2O [ No CAS ]
  • [ 506-59-2 ]
  • [ 19513-05-4 ]
  • 14C2H7N*14H(1+)*8Na(1+)*26H2O*((PW9O34)2(PW10O37)2Mn12O6(OH)2(O2CCH3)2(C4H8O6P2)2)(22-) [ No CAS ]
YieldReaction ConditionsOperation in experiment
31% Stage #1: Na9[A-α-PW9O34]*7H2O; manganese(III) triacetate dihydrate In aq. acetate buffer at 20℃; for 1h; Stage #2: 1,4-butylenediphosphonic acid In aq. acetate buffer for 2h; Stage #3: N,N-dimethylammonium chloride In aq. acetate buffer
Same Skeleton Products
Historical Records