Type	HazMat fee for 500 gram (Estimated)
Excepted Quantity	USD 0.00
Limited Quantity	USD 15-60
Inaccessible (Haz class 6.1), Domestic	USD 80+
Inaccessible (Haz class 6.1), International	USD 150+
Accessible (Haz class 3, 4, 5 or 8), Domestic	USD 100+
Accessible (Haz class 3, 4, 5 or 8), International	USD 200+

CAS No. :	498-81-7
Formula :	C₁₀H₂₀O
M.W :	156.27
SMILES Code :	CC1CCC(CC1)C(C)(C)O
English Name :	2-(4-Methylcyclohexyl)propan-2-ol
MDL No. :	MFCD00013760

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Yield	Reaction Conditions	Operation in experiment
93.5%	With 5%-palladium/activated carbon; hydrogen; In methanol; for 12h;	A mixture of compound 1 (2.6mmol), 74 methanol (10mL), and 5% 75 Pd/C (0.38mmol) was stirred under an atmosphere of hydrogen for 12h. The Pd/C was then removed by suction filtration, and the filtrate was concentrated under reduced pressure. The residue was purified by silica gel column chromatography (Petroleum ether/ethy acetate=20:1 v/v) to give 76 compound 5 (380mg, 93.5%) as a colorless oil. 1H NMR (500MHz, CDCl3) delta 1.71-1.80 (m, 4H), 1.52 (m, 1H), 1.23-1.20 (m, 1H), 1.13 (s, 6H), 1.03-1.00 (m, 2H), 0.87-0.90 (m, 2H), 0.85-0.86 (d, J=6.5Hz, 3H). (0047) 13C NMR (126MHz, CDCl3) delta 73.07, 48.98, 35.49, 35.49, 32.83, 27.54, 27.54, 27.13, 27.13, 22.70. ESI-MS: m/z=179 [M+Na]+.
	Pd-C; In ethanol;	a. 2-(4-Methylcyclohexyl)propan-2-ol <strong>[98-55-5]alpha-Terpineol</strong> (6.17 g) in ethanol (130 ml) was hydrogenated for 1 h at atmospheric pressure using 10% Pd-C catalyst (290 mg). The catalyst was then removed by filtration through Kieselguhr and the solvent was removed under reduced pressure to leave the title compound as an oil (5.93 g). Distillation gave an oil (4.56 g) b.p. (13 mm) 98; numax (film) 3375, 2940, 1445, 1160, 1140, and 910 cm-1; deltaH (60 MHz, CDCl3) 0.6-2.0(m).

Yield	Reaction Conditions	Operation in experiment
1: 5.71% 2: 49.16% 3: 34.44%	With deuterioporphyrin dimethyl ester ferric chloride In dichloromethane at 130℃; for 18h;	1 Embodiment 1 Embodiment 1The main component of the starting material in the mass fraction (GC method): trans-p-menthane 71.91%, cis-menthane 25.39%; 1.38% 2,6-dimethyl octane. Equipped with a ventilation tube, a reflux condenser, a thermometer round bottom flask was added calculated amount of p-menthane 100g, plus5mg into (i.e., catalyst concentration 50mg / kg) was dissolved 0.5mLCH2Cl2, having the structural formula (I) of the metalloporphyrin, wherein R1 = R3 = H, R2 = CH3, R4 = (CH2) 2COOCH3, M = Fe, X = Cl formed transparent homogeneous solution after stirring, the mixture is heated to 130 , when the heating temperature was raised to the set temperature of air introduced into commercially available control the gas flow rate of 60mL / min incubation the reaction 18H, products were analyzed by the GC trace, menthane conversion rate of 17.78%, the reaction selectivity and Meng Meng oxazolidinone alcohol was 77.49%.The method of post-processing of the reaction liquid: is filtered to remove precipitated solid catalyst, transferred to the distillation still in the filtrate, the filtrate by adding a small amount of solid NaOH is weakly alkaline, to Meng Wan unreacted separation by distillation of the crude product obtained after meng Wanchun, after rectification of the crude product the product meng Wanchun, the main components in the product to : (1) the P-menthane-1-ol 49.16%, (2) the P-menthane-2-ol 1.03%, (3) the P-menthane-3-ol 2.46%, (4) to which-4-ol 5.71%, (5) the P-menthane-8-ol 34.44%, (6) the P-menthane-2-ketone 3.90 and (7) the P-menthane-3-ketone 1.18%.
	With C₃₂H₃₂CoN₄O₄ at 130℃; for 17h; Overall yield = 10.2 %; chemoselective reaction;	2.2. Hydroxylation procedure General procedure: The oxidation of p-menthane was carried out in liquid phase in a 250 mL four-necked glass flask equipped with a heating magnetic whisk, a reflux condenser, a thermometer and a breather pipe. Air was fed to the reactor through the air bottle and the flow rate was measured by a rotameter. In a typical procedure, 100 g p-menthane and a certain amount of metalloporphyrin were added. When the reaction temperature reached 100-160 °C, air was pumped into the mixture with a flow rate of 20-100 mL/min. The reaction mixture was sampled and identified by GC or GC-MS every 1 h.

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CAS No.: 498-81-7

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CAS No.: 498-81-7

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Precautionary Statements-General
Code	Phrase
P101	If medical advice is needed,have product container or label at hand.
P102	Keep out of reach of children.
P103	Read label before use
Prevention
Code	Phrase
P201	Obtain special instructions before use.
P202	Do not handle until all safety precautions have been read and understood.
P210	Keep away from heat/sparks/open flames/hot surfaces. - No smoking.
P211	Do not spray on an open flame or other ignition source.
P220	Keep/Store away from clothing/combustible materials.
P221	Take any precaution to avoid mixing with combustibles
P222	Do not allow contact with air.
P223	Keep away from any possible contact with water, because of violent reaction and possible flash fire.
P230	Keep wetted
P231	Handle under inert gas.
P232	Protect from moisture.
P233	Keep container tightly closed.
P234	Keep only in original container.
P235	Keep cool
P240	Ground/bond container and receiving equipment.
P241	Use explosion-proof electrical/ventilating/lighting/equipment.
P242	Use only non-sparking tools.
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P261	Avoid breathing dust/fume/gas/mist/vapours/spray.
P262	Do not get in eyes, on skin, or on clothing.
P263	Avoid contact during pregnancy/while nursing.
P264	Wash hands thoroughly after handling.
P265	Wash skin thouroughly after handling.
P270	Do not eat, drink or smoke when using this product.
P271	Use only outdoors or in a well-ventilated area.
P272	Contaminated work clothing should not be allowed out of the workplace.
P273	Avoid release to the environment.
P280	Wear protective gloves/protective clothing/eye protection/face protection.
P281	Use personal protective equipment as required.
P282	Wear cold insulating gloves/face shield/eye protection.
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P284	Wear respiratory protection.
P285	In case of inadequate ventilation wear respiratory protection.
P231 + P232	Handle under inert gas. Protect from moisture.
P235 + P410	Keep cool. Protect from sunlight.
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Code	Phrase
P301	IF SWALLOWED:
P304	IF INHALED:
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P312	Call a POISON CENTER or doctor/physician if you feel unwell.
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P314	Get medical advice/attention if you feel unwell.
P315	Get immediate medical advice/attention.
P320
P302 + P352	IF ON SKIN: wash with plenty of soap and water.
P321
P322
P330	Rinse mouth.
P331	Do NOT induce vomiting.
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P335	Brush off loose particles from skin.
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P337	If eye irritation persists:
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P342	If experiencing respiratory symptoms:
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P352	Wash with plenty of soap and water.
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P372	Explosion risk in case of fire.
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P378
P380	Evacuate area.
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P390	Absorb spillage to prevent material damage.
P391	Collect spillage. Hazardous to the aquatic environment
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P301 + P312	IF SWALLOWED: call a POISON CENTER or doctor/physician IF you feel unwell.
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P302 + P334	IF ON SKIN: Immerse in cool water/wrap in wet bandages.
P302 + P350	IF ON SKIN: Gently wash with plenty of soap and water.
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P304 + P312	IF INHALED: Call a POISON CENTER or doctor/physician if you feel unwell.
P304 + P340	IF INHALED: Remove victim to fresh air and Keep at rest in a position comfortable for breathing.
P304 + P341	IF INHALED: If breathing is difficult, remove victim to fresh air and keep at rest in a position comfortable for breathing.
P305 + P351 + P338	IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.
P306 + P360	IF ON CLOTHING: Rinse Immediately contaminated CLOTHING and SKIN with plenty of water before removing clothes.
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P308 + P313	IF exposed or concerned: Get medical advice/attention.
P309 + P311	IF exposed or if you feel unwell: call a POISON CENTER or doctor/physician.
P332 + P313	IF SKIN irritation occurs: Get medical advice/attention.
P333 + P313	IF SKIN irritation or rash occurs: Get medical advice/attention.
P335 + P334	Brush off loose particles from skin. Immerse in cool water/wrap in wet bandages.
P337 + P313	IF eye irritation persists: Get medical advice/attention.
P342 + P311	IF experiencing respiratory symptoms: call a POISON CENTER or doctor/physician.
P370 + P376	In case of fire: Stop leak if safe to Do so.
P370 + P378	In case of fire:
P370 + P380	In case of fire: Evacuate area.
P370 + P380 + P375	In case of fire: Evacuate area. Fight fire remotely due to the risk of explosion.
P371 + P380 + P375	In case of major fire and large quantities: Evacuate area. Fight fire remotely due to the risk of explosion.
Storage
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P401
P402	Store in a dry place.
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P411
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P402 + P404	Store in a dry place. Store in a closed container.
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P411 + P235	Keep cool.
Disposal
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Physical hazards
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H200	Unstable explosive
H201	Explosive; mass explosion hazard
H202	Explosive; severe projection hazard
H203	Explosive; fire, blast or projection hazard
H204	Fire or projection hazard
H205	May mass explode in fire
H220	Extremely flammable gas
H221	Flammable gas
H222	Extremely flammable aerosol
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H231	May react explosively even in the absence of air at elevated pressure and/or temperature
H240	Heating may cause an explosion
H241	Heating may cause a fire or explosion
H242	Heating may cause a fire
H250	Catches fire spontaneously if exposed to air
H251	Self-heating; may catch fire
H252	Self-heating in large quantities; may catch fire
H260	In contact with water releases flammable gases which may ignite spontaneously
H261	In contact with water releases flammable gas
H270	May cause or intensify fire; oxidizer
H271	May cause fire or explosion; strong oxidizer
H272	May intensify fire; oxidizer
H280	Contains gas under pressure; may explode if heated
H281	Contains refrigerated gas; may cause cryogenic burns or injury
H290	May be corrosive to metals
Health hazards
Code	Phrase
H300	Fatal if swallowed
H301	Toxic if swallowed
H302	Harmful if swallowed
H303	May be harmful if swallowed