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Type | HazMat fee for 500 gram (Estimated) |
Excepted Quantity | USD 0.00 |
Limited Quantity | USD 15-60 |
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Purity | Size | Price | VIP Price | USA Stock *0-1 Day | Global Stock *5-7 Days | Quantity | |||||
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* Storage: {[proInfo.prStorage]}
CAS No. : | 51200-87-4 | MDL No. : | MFCD00154171 |
Formula : | C5H11NO | Boiling Point : | - |
Linear Structure Formula : | - | InChI Key : | GUQMDNQYMMRJPY-UHFFFAOYSA-N |
M.W : | 101.15 | Pubchem ID : | 62010 |
Synonyms : |
|
Signal Word: | Danger | Class: | 3,8 |
Precautionary Statements: | P210-P233-P240-P241-P242-P243-P261-P264-P270-P271-P272-P280-P301+P312-P303+P361+P353-P304+P340-P305+P351+P338-P310-P322-P330-P333+P313-P362-P370+P378-P403+P233-P403+P235-P405-P501 | UN#: | 2924 |
Hazard Statements: | H225-H302+H312+H332-H315-H317-H318-H335 | Packing Group: | Ⅲ |
GHS Pictogram: |
* All experimental methods are cited from the reference, please refer to the original source for details. We do not guarantee the accuracy of the content in the reference.
Yield | Reaction Conditions | Operation in experiment |
---|---|---|
In benzene |
Yield | Reaction Conditions | Operation in experiment |
---|---|---|
(i) Na2CO3, CH2Cl2, (ii) NaCN, DMF; Multistep reaction; |
Yield | Reaction Conditions | Operation in experiment |
---|---|---|
With oxygen 1.) CH3CN, irradiation, 4 h, 2.) CH3CN, 14 h; Yield given. Multistep reaction. Yields of byproduct given; |
Yield | Reaction Conditions | Operation in experiment |
---|---|---|
65% | In benzene Heating; |
Yield | Reaction Conditions | Operation in experiment |
---|---|---|
59% | In benzene Heating; |
Yield | Reaction Conditions | Operation in experiment |
---|---|---|
100% | With sodium hydroxide In dichloromethane; water |
Yield | Reaction Conditions | Operation in experiment |
---|---|---|
100% | With sodium hydroxide In dichloromethane; water |
Yield | Reaction Conditions | Operation in experiment |
---|---|---|
74% | With potassium carbonate In dimethyl sulfoxide microwave irradiation; |
Yield | Reaction Conditions | Operation in experiment |
---|---|---|
81% | With potassium carbonate In dimethyl sulfoxide microwave irradiation; |
Yield | Reaction Conditions | Operation in experiment |
---|---|---|
74% | With potassium carbonate In dimethyl sulfoxide microwave irradiation; |
Yield | Reaction Conditions | Operation in experiment |
---|---|---|
Multi-step reaction with 3 steps 1.1: 100 percent / NaOH / CH2Cl2; H2O 2.1: sBuLi; 1,3-dimethylhexahydro-2-pyrimidinone / tetrahydrofuran / 2.5 h / -78 - 0 °C 2.2: 60 percent / CD3OD / tetrahydrofuran 3.1: aq. HCl / diethyl ether |
Yield | Reaction Conditions | Operation in experiment |
---|---|---|
Multi-step reaction with 2 steps 1.1: 100 percent / NaOH / CH2Cl2; H2O 2.1: sBuLi; 1,3-dimethylhexahydro-2-pyrimidinone / tetrahydrofuran / 2.5 h / -78 - 0 °C 2.2: 60 percent / NH4Cl / tetrahydrofuran |
Yield | Reaction Conditions | Operation in experiment |
---|---|---|
Multi-step reaction with 2 steps 1.1: 100 percent / NaOH / CH2Cl2; H2O 2.1: sBuLi / tetrahydrofuran / 0.5 h / -78 °C 2.2: 95 percent / CD3OD / tetrahydrofuran |
Yield | Reaction Conditions | Operation in experiment |
---|---|---|
Multi-step reaction with 2 steps 1.1: 100 percent / NaOH / CH2Cl2; H2O 2.1: sBuLi; 1,3-dimethylhexahydro-2-pyrimidinone / tetrahydrofuran / 2.5 h / -78 - 0 °C 2.2: 60 percent / CD3OD / tetrahydrofuran |
Yield | Reaction Conditions | Operation in experiment |
---|---|---|
Multi-step reaction with 3 steps 1.1: 100 percent / NaOH / CH2Cl2; H2O 2.1: sBuLi; 1,3-dimethylhexahydro-2-pyrimidinone / tetrahydrofuran / 2.5 h / -78 - 0 °C 2.2: 60 percent / CD3OD / tetrahydrofuran 3.1: 13 percent / aq. HCl / diethyl ether |
Yield | Reaction Conditions | Operation in experiment |
---|---|---|
Multi-step reaction with 3 steps 1.1: 100 percent / NaOH / CH2Cl2; H2O 2.1: sBuLi / tetrahydrofuran / 0.5 h / -78 °C 2.2: 95 percent / CD3OD / tetrahydrofuran 3.1: sBuLi / tetrahydrofuran / 0.5 h / -78 °C 3.2: CD3OD / tetrahydrofuran |
Yield | Reaction Conditions | Operation in experiment |
---|---|---|
Multi-step reaction with 3 steps 1.1: 100 percent / NaOH / CH2Cl2; H2O 2.1: sBuLi / tetrahydrofuran / 0.5 h / -78 °C 2.2: 95 percent / CD3OD / tetrahydrofuran 3.1: sBuLi; 1,3-dimethylhexahydro-2-pyrimidinone / tetrahydrofuran / 2.5 h / -78 - 0 °C 3.2: 34 percent / NH4Cl / tetrahydrofuran |
Yield | Reaction Conditions | Operation in experiment |
---|---|---|
Multi-step reaction with 2 steps 1.1: 100 percent / NaOH / CH2Cl2; H2O 2.1: sBuLi; 1,3-dimethylhexahydro-2-pyrimidinone / tetrahydrofuran / 2.5 h / -78 - 0 °C 2.2: 45 percent / tetrahydrofuran |
Yield | Reaction Conditions | Operation in experiment |
---|---|---|
Multi-step reaction with 3 steps 1.1: 100 percent / NaOH / CH2Cl2; H2O 2.1: sBuLi; 1,3-dimethylhexahydro-2-pyrimidinone / tetrahydrofuran / 2.5 h / -78 - 0 °C 2.2: 45 percent / tetrahydrofuran 3.1: 99 percent / aq. HCl / diethyl ether |
Yield | Reaction Conditions | Operation in experiment |
---|---|---|
Multi-step reaction with 2 steps 1.1: 100 percent / NaOH / CH2Cl2; H2O 2.1: sBuLi; 1,3-dimethylhexahydro-2-pyrimidinone / tetrahydrofuran / 2.5 h / -78 - 0 °C 2.2: 41 percent / tetrahydrofuran |
Yield | Reaction Conditions | Operation in experiment |
---|---|---|
With methanesulfonic acid; In butan-1-ol; at 80 - 120℃; for 2.86667h; | 1,2, 3, 9-TETRAHYDRO-9-METHYL-4H-CARBAZOL-4-ONE (13.26 g = 66. 5 mmole) and methane- SULFONIC acid (10.23 g = 106. 4 mmole) in 1-butanol (45 ML) were heated to 90C. In 2 minutes 4, 4-DIMETHYL-OXAZOLIDINE (10.09 G = 99. 9 mmole) in 1-butanol (8 ML) was added. After 50 minutes at 80C 2-METHYLIMIDAZOLE (27.32 G--_ 332. 5 mmole) and 1-butanol (8 ml) were added. After 2 hours at 120C 180 ML of toluene and 120 ml of water were added at 80C. The layers were separated. The water layer was extracted with 180 ml of toluene and 60 ml of 1-butanol. The combined organic layers were washed twice with 240 ml of water. The organic layer was evaporated to dryness. 150 ml of 1-butanol and 10 ml of 36% M/M hydrochloric acid were added to the residue. At 0C crystallization soon occurred. After 1 hour at 0 C the formed crystals were filtered off, washed with 1butanol and MTBE and subsequently dried : 10.02 G (45.7%) of 1,2, 3, 9-tetrahydro-9-methyl-3-[(2-methyl-1H-imidazol-1-yl)methyl]-4H-carbazol-4-one hydrochloride. The mother liquor contained 2.70 g (12.3%) of product. HPLC: 2 95%. NMR and MS: see Example 8. |
Yield | Reaction Conditions | Operation in experiment |
---|---|---|
With methanesulfonic acid In butan-1-ol at 70 - 120℃; for 2.86667h; | 3 Example 3. Reaction of 5,6, 9, 10-tetrahydro-4H-pyrido [3,2, 1-jk]carbazol-11(8H)- one with 4, 4-DIMETHYL-OXAZOLIDINE. 5,6, 9, 10-TETRAHYDRO-4H-PYRIDO [3,2, 1-jk]carbazol-11(8H)-one (20.00 g = 88. 8 mmole) and METHANESULFONIC acid (13.65 G--_ 142. 0 mmole) in 1-butanol (60 mi) were heated to 70°C. In 2 minutes 4, 4-dimethyl-oxazolidine (13.47 G--_ 133. 2 mmole) in 1-butanol (10 ml) was added. After 50 minutes at 80°C 2-METHYLIMIDAZOLE (36.45 G No. 444. 0 mmole) and butanol (10 ml) were added. After 2 hours at 120°C the reaction mixture was partly evaporated fill 20 ml of 1-butanol was left over. At 70°C, 60 ml of toluene and 40 ml of water were added to the residue. The layers were separated. The water layer was extracted with 60 ml of toluene. The combined TOLUENE LAYERS were washed three times with 80 ml of water. The organic layer was evaporated to dryness and subsequently 100 ml of 1-butanol was added. To the resulting solution 10.0 ml of 36% m/m hydrochloric acid was added. After stirring for 2 hours at room temperature the formed so lid was filtered off and washed with 1-butanol and MTBE. Yield after drying: 12.38 G 5,6, 9,10- TETRAHYDRO-10- ( (2-METHYL-1H-IMIDAZOL-1-YL) METHYL]-4H-PYRIDO [3,2, 1-JK] CARBAZOL- 11 (8H)-one hydrochloride (39.2%). HPLC: 2 95%.'H NMR and MS: see Example 2. The mother liquor contained 3.45 G (10. 9%) of product. |
Yield | Reaction Conditions | Operation in experiment |
---|---|---|
With methanesulfonic acid In butan-1-ol at 70 - 120℃; for 2.86667h; | 6 Example 6. Reaction of 3, 4-dihydro-1(2H)-naphthalenone with 4, 4-dimethyl- oxazolidine. 3, 4-DIHYDRO-1 (2H)-naphthalenone (12.98 G = 88. 8 MMOLE) and methanesulfonic acid (13.65 G = 142. 0 mmole) in 1-butanol (60 ml) were heated to 70°C. In 2 minutes 4,4- DIMETHYL-OXAZOLIDINE (13.46 g = 133. 1 mmole) in 1-butanol (10 ML) was added. After 50 minutes at 80°C 2-methylimidazole (36.45 g = 444. 0 mmole) and 1-butanol (10 ml) were added. After 2 hours at 120°C the reaction mixture was partly evaporated till 20 ML of 1-butanol was left over. At 70°C, 60 ml of toluene and 40 ML of water were added to the residue. The layers were separated. The water layer was extracted with 60 ml of toluene. The combined toluene layers were washed three times with 80 ml of water. The organic layer was evaporated to dryness and subsequently 100 ML of 1-butanol was added. To the resulting solution 10.0 ML of 36% M/M hydrochloric acid was added. The resulting solution was evaporated till an end volume of 50 ML. After stirring for 2 hours at 0°C the formed solid was filtered off and washed with 1-butanol and MTBE. Yield after drying : 14.13 G (57.5%) 3, 4-DIHYDRO-2-[(2-METHYL-1H-IMIDOL- 1-YL) methyl-1 (2H)-NAPHTHALENONE HYDROCHLORIDE. HPLC: No. 95%. 1H NMR and MS: see Example 5. The mother liquor contained 2.33 G (9.5%) of product. |
Yield | Reaction Conditions | Operation in experiment |
---|---|---|
With formaldehyd | 13 EXAMPLE 13 EXAMPLE 13 2-Nitropropane 89 g (1 mole) and 37% formaldehyde 88 g (1 mole) were mixed together and heated to 65° C. There was then added dropwise Oxazolidine A 101 g (1 mole) and after the addition was complete, heating of the reaction mixture at 60°-70° C was continued for 2 hours. Water was then removed by distillation at about 8-12 mm Hg pressure. There was obtained N-(2-methyl-2-nitropropyl)-4,4-dimethyl-1,3-oxazolidine. |
Yield | Reaction Conditions | Operation in experiment |
---|---|---|
77% | With 2-chloro-1-methyl-pyridinium iodide; triethylamine In dichloromethane at 20℃; for 48h; | 10.I To a mixture of 4,4-dimethyloxazolidine (287 μl; 2 mmol; 1 eq) and boc-beta-alanine (416.3 mg; 2.2 mmol; 1.10 eq) in DCM (30 ml), are added triethylamine (832 μl; 6 mmol; 3 eq) and 2-chloro-1-methylpyridinium iodide (1533 mg; 6 mmol; 3 eq). The mixture is stirred for 2 days at RT. The reaction is followed by TLC cyclohexane/EtOAc 1:1). The reaction mixture is then washed twice with NH4Cl sat. solution and twice with NaHCO3 sat. solution. The organic layer is dried over Na2SO4, filtered and concentrated to give 760 mg of an orange oil, which is purified by flash chromatography (cyclohexane / EtOAc gradient, from 9/1 to 1/1 over 30 min). The title product is isolated as a white-o if solid (420.5 mg; 77%). 1H NMR (DMSO-d6, 300 MHz) δ 1.41 (s, 9H), 1.46 (s, 6H), 2.29 (t, J= 6 Hz, 2H), 3.38 (t, J= 6 Hz, 2H), 3.72 (s, 2H), 4.90 (s, 2H), 5.17 (br s, 1H). M+(ESI): 273.23. |
Yield | Reaction Conditions | Operation in experiment |
---|---|---|
77% | With potassium carbonate In dimethyl sulfoxide for 0.0333333h; microwave irradiation; |
Yield | Reaction Conditions | Operation in experiment |
---|---|---|
88% | With potassium carbonate In dimethyl sulfoxide Microwave irradiation; |
Yield | Reaction Conditions | Operation in experiment |
---|---|---|
96% | With potassium carbonate In dimethyl sulfoxide Microwave irradiation; |
Yield | Reaction Conditions | Operation in experiment |
---|---|---|
80% | With potassium carbonate In dimethyl sulfoxide Microwave irradiation; |
Yield | Reaction Conditions | Operation in experiment |
---|---|---|
With 1-hydroxy-7-aza-benzotriazole; 1-ethyl-(3-(3-dimethylamino)propyl)-carbodiimide hydrochloride; N-ethyl-N,N-diisopropylamine In tetrahydrofuran Inert atmosphere; |
Yield | Reaction Conditions | Operation in experiment |
---|---|---|
In dichloromethane at 25℃; for 18h; Large scale; |
Yield | Reaction Conditions | Operation in experiment |
---|---|---|
Multi-step reaction with 3 steps 1: 2-chloro-1-methyl-pyridinium iodide; triethylamine / dichloromethane / 48 h / 20 °C 2: trifluoroacetic acid / dichloromethane / 0.33 h / 20 °C 3: triethylamine / N,N-dimethyl-formamide / 0.33 h |
Yield | Reaction Conditions | Operation in experiment |
---|---|---|
Multi-step reaction with 2 steps 1: 2-chloro-1-methyl-pyridinium iodide; triethylamine / dichloromethane / 48 h / 20 °C 2: trifluoroacetic acid / dichloromethane / 0.33 h / 20 °C |
Yield | Reaction Conditions | Operation in experiment |
---|---|---|
19% | With dmap In tetrahydrofuran; water at 0 - 20℃; |
Yield | Reaction Conditions | Operation in experiment |
---|---|---|
7.7% | With pyridine In tetrahydrofuran; water at 0 - 20℃; |
Yield | Reaction Conditions | Operation in experiment |
---|---|---|
33% | With pyridine In tetrahydrofuran; water at 0 - 20℃; |
Yield | Reaction Conditions | Operation in experiment |
---|---|---|
14% | With pyridine In tetrahydrofuran; water at 0 - 20℃; |
Tags: 51200-87-4 synthesis path| 51200-87-4 SDS| 51200-87-4 COA| 51200-87-4 purity| 51200-87-4 application| 51200-87-4 NMR| 51200-87-4 COA| 51200-87-4 structure
Precautionary Statements-General | |
Code | Phrase |
P101 | If medical advice is needed,have product container or label at hand. |
P102 | Keep out of reach of children. |
P103 | Read label before use |
Prevention | |
Code | Phrase |
P201 | Obtain special instructions before use. |
P202 | Do not handle until all safety precautions have been read and understood. |
P210 | Keep away from heat/sparks/open flames/hot surfaces. - No smoking. |
P211 | Do not spray on an open flame or other ignition source. |
P220 | Keep/Store away from clothing/combustible materials. |
P221 | Take any precaution to avoid mixing with combustibles |
P222 | Do not allow contact with air. |
P223 | Keep away from any possible contact with water, because of violent reaction and possible flash fire. |
P230 | Keep wetted |
P231 | Handle under inert gas. |
P232 | Protect from moisture. |
P233 | Keep container tightly closed. |
P234 | Keep only in original container. |
P235 | Keep cool |
P240 | Ground/bond container and receiving equipment. |
P241 | Use explosion-proof electrical/ventilating/lighting/equipment. |
P242 | Use only non-sparking tools. |
P243 | Take precautionary measures against static discharge. |
P244 | Keep reduction valves free from grease and oil. |
P250 | Do not subject to grinding/shock/friction. |
P251 | Pressurized container: Do not pierce or burn, even after use. |
P260 | Do not breathe dust/fume/gas/mist/vapours/spray. |
P261 | Avoid breathing dust/fume/gas/mist/vapours/spray. |
P262 | Do not get in eyes, on skin, or on clothing. |
P263 | Avoid contact during pregnancy/while nursing. |
P264 | Wash hands thoroughly after handling. |
P265 | Wash skin thouroughly after handling. |
P270 | Do not eat, drink or smoke when using this product. |
P271 | Use only outdoors or in a well-ventilated area. |
P272 | Contaminated work clothing should not be allowed out of the workplace. |
P273 | Avoid release to the environment. |
P280 | Wear protective gloves/protective clothing/eye protection/face protection. |
P281 | Use personal protective equipment as required. |
P282 | Wear cold insulating gloves/face shield/eye protection. |
P283 | Wear fire/flame resistant/retardant clothing. |
P284 | Wear respiratory protection. |
P285 | In case of inadequate ventilation wear respiratory protection. |
P231 + P232 | Handle under inert gas. Protect from moisture. |
P235 + P410 | Keep cool. Protect from sunlight. |
Response | |
Code | Phrase |
P301 | IF SWALLOWED: |
P304 | IF INHALED: |
P305 | IF IN EYES: |
P306 | IF ON CLOTHING: |
P307 | IF exposed: |
P308 | IF exposed or concerned: |
P309 | IF exposed or if you feel unwell: |
P310 | Immediately call a POISON CENTER or doctor/physician. |
P311 | Call a POISON CENTER or doctor/physician. |
P312 | Call a POISON CENTER or doctor/physician if you feel unwell. |
P313 | Get medical advice/attention. |
P314 | Get medical advice/attention if you feel unwell. |
P315 | Get immediate medical advice/attention. |
P320 | |
P302 + P352 | IF ON SKIN: wash with plenty of soap and water. |
P321 | |
P322 | |
P330 | Rinse mouth. |
P331 | Do NOT induce vomiting. |
P332 | IF SKIN irritation occurs: |
P333 | If skin irritation or rash occurs: |
P334 | Immerse in cool water/wrap n wet bandages. |
P335 | Brush off loose particles from skin. |
P336 | Thaw frosted parts with lukewarm water. Do not rub affected area. |
P337 | If eye irritation persists: |
P338 | Remove contact lenses, if present and easy to do. Continue rinsing. |
P340 | Remove victim to fresh air and keep at rest in a position comfortable for breathing. |
P341 | If breathing is difficult, remove victim to fresh air and keep at rest in a position comfortable for breathing. |
P342 | If experiencing respiratory symptoms: |
P350 | Gently wash with plenty of soap and water. |
P351 | Rinse cautiously with water for several minutes. |
P352 | Wash with plenty of soap and water. |
P353 | Rinse skin with water/shower. |
P360 | Rinse immediately contaminated clothing and skin with plenty of water before removing clothes. |
P361 | Remove/Take off immediately all contaminated clothing. |
P362 | Take off contaminated clothing and wash before reuse. |
P363 | Wash contaminated clothing before reuse. |
P370 | In case of fire: |
P371 | In case of major fire and large quantities: |
P372 | Explosion risk in case of fire. |
P373 | DO NOT fight fire when fire reaches explosives. |
P374 | Fight fire with normal precautions from a reasonable distance. |
P376 | Stop leak if safe to do so. Oxidising gases (section 2.4) 1 |
P377 | Leaking gas fire: Do not extinguish, unless leak can be stopped safely. |
P378 | |
P380 | Evacuate area. |
P381 | Eliminate all ignition sources if safe to do so. |
P390 | Absorb spillage to prevent material damage. |
P391 | Collect spillage. Hazardous to the aquatic environment |
P301 + P310 | IF SWALLOWED: Immediately call a POISON CENTER or doctor/physician. |
P301 + P312 | IF SWALLOWED: call a POISON CENTER or doctor/physician IF you feel unwell. |
P301 + P330 + P331 | IF SWALLOWED: Rinse mouth. Do NOT induce vomiting. |
P302 + P334 | IF ON SKIN: Immerse in cool water/wrap in wet bandages. |
P302 + P350 | IF ON SKIN: Gently wash with plenty of soap and water. |
P303 + P361 + P353 | IF ON SKIN (or hair): Remove/Take off Immediately all contaminated clothing. Rinse SKIN with water/shower. |
P304 + P312 | IF INHALED: Call a POISON CENTER or doctor/physician if you feel unwell. |
P304 + P340 | IF INHALED: Remove victim to fresh air and Keep at rest in a position comfortable for breathing. |
P304 + P341 | IF INHALED: If breathing is difficult, remove victim to fresh air and keep at rest in a position comfortable for breathing. |
P305 + P351 + P338 | IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. |
P306 + P360 | IF ON CLOTHING: Rinse Immediately contaminated CLOTHING and SKIN with plenty of water before removing clothes. |
P307 + P311 | IF exposed: call a POISON CENTER or doctor/physician. |
P308 + P313 | IF exposed or concerned: Get medical advice/attention. |
P309 + P311 | IF exposed or if you feel unwell: call a POISON CENTER or doctor/physician. |
P332 + P313 | IF SKIN irritation occurs: Get medical advice/attention. |
P333 + P313 | IF SKIN irritation or rash occurs: Get medical advice/attention. |
P335 + P334 | Brush off loose particles from skin. Immerse in cool water/wrap in wet bandages. |
P337 + P313 | IF eye irritation persists: Get medical advice/attention. |
P342 + P311 | IF experiencing respiratory symptoms: call a POISON CENTER or doctor/physician. |
P370 + P376 | In case of fire: Stop leak if safe to Do so. |
P370 + P378 | In case of fire: |
P370 + P380 | In case of fire: Evacuate area. |
P370 + P380 + P375 | In case of fire: Evacuate area. Fight fire remotely due to the risk of explosion. |
P371 + P380 + P375 | In case of major fire and large quantities: Evacuate area. Fight fire remotely due to the risk of explosion. |
Storage | |
Code | Phrase |
P401 | |
P402 | Store in a dry place. |
P403 | Store in a well-ventilated place. |
P404 | Store in a closed container. |
P405 | Store locked up. |
P406 | Store in corrosive resistant/ container with a resistant inner liner. |
P407 | Maintain air gap between stacks/pallets. |
P410 | Protect from sunlight. |
P411 | |
P412 | Do not expose to temperatures exceeding 50 oC/ 122 oF. |
P413 | |
P420 | Store away from other materials. |
P422 | |
P402 + P404 | Store in a dry place. Store in a closed container. |
P403 + P233 | Store in a well-ventilated place. Keep container tightly closed. |
P403 + P235 | Store in a well-ventilated place. Keep cool. |
P410 + P403 | Protect from sunlight. Store in a well-ventilated place. |
P410 + P412 | Protect from sunlight. Do not expose to temperatures exceeding 50 oC/122oF. |
P411 + P235 | Keep cool. |
Disposal | |
Code | Phrase |
P501 | Dispose of contents/container to ... |
P502 | Refer to manufacturer/supplier for information on recovery/recycling |
Physical hazards | |
Code | Phrase |
H200 | Unstable explosive |
H201 | Explosive; mass explosion hazard |
H202 | Explosive; severe projection hazard |
H203 | Explosive; fire, blast or projection hazard |
H204 | Fire or projection hazard |
H205 | May mass explode in fire |
H220 | Extremely flammable gas |
H221 | Flammable gas |
H222 | Extremely flammable aerosol |
H223 | Flammable aerosol |
H224 | Extremely flammable liquid and vapour |
H225 | Highly flammable liquid and vapour |
H226 | Flammable liquid and vapour |
H227 | Combustible liquid |
H228 | Flammable solid |
H229 | Pressurized container: may burst if heated |
H230 | May react explosively even in the absence of air |
H231 | May react explosively even in the absence of air at elevated pressure and/or temperature |
H240 | Heating may cause an explosion |
H241 | Heating may cause a fire or explosion |
H242 | Heating may cause a fire |
H250 | Catches fire spontaneously if exposed to air |
H251 | Self-heating; may catch fire |
H252 | Self-heating in large quantities; may catch fire |
H260 | In contact with water releases flammable gases which may ignite spontaneously |
H261 | In contact with water releases flammable gas |
H270 | May cause or intensify fire; oxidizer |
H271 | May cause fire or explosion; strong oxidizer |
H272 | May intensify fire; oxidizer |
H280 | Contains gas under pressure; may explode if heated |
H281 | Contains refrigerated gas; may cause cryogenic burns or injury |
H290 | May be corrosive to metals |
Health hazards | |
Code | Phrase |
H300 | Fatal if swallowed |
H301 | Toxic if swallowed |
H302 | Harmful if swallowed |
H303 | May be harmful if swallowed |
H304 | May be fatal if swallowed and enters airways |
H305 | May be harmful if swallowed and enters airways |
H310 | Fatal in contact with skin |
H311 | Toxic in contact with skin |
H312 | Harmful in contact with skin |
H313 | May be harmful in contact with skin |
H314 | Causes severe skin burns and eye damage |
H315 | Causes skin irritation |
H316 | Causes mild skin irritation |
H317 | May cause an allergic skin reaction |
H318 | Causes serious eye damage |
H319 | Causes serious eye irritation |
H320 | Causes eye irritation |
H330 | Fatal if inhaled |
H331 | Toxic if inhaled |
H332 | Harmful if inhaled |
H333 | May be harmful if inhaled |
H334 | May cause allergy or asthma symptoms or breathing difficulties if inhaled |
H335 | May cause respiratory irritation |
H336 | May cause drowsiness or dizziness |
H340 | May cause genetic defects |
H341 | Suspected of causing genetic defects |
H350 | May cause cancer |
H351 | Suspected of causing cancer |
H360 | May damage fertility or the unborn child |
H361 | Suspected of damaging fertility or the unborn child |
H361d | Suspected of damaging the unborn child |
H362 | May cause harm to breast-fed children |
H370 | Causes damage to organs |
H371 | May cause damage to organs |
H372 | Causes damage to organs through prolonged or repeated exposure |
H373 | May cause damage to organs through prolonged or repeated exposure |
Environmental hazards | |
Code | Phrase |
H400 | Very toxic to aquatic life |
H401 | Toxic to aquatic life |
H402 | Harmful to aquatic life |
H410 | Very toxic to aquatic life with long-lasting effects |
H411 | Toxic to aquatic life with long-lasting effects |
H412 | Harmful to aquatic life with long-lasting effects |
H413 | May cause long-lasting harmful effects to aquatic life |
H420 | Harms public health and the environment by destroying ozone in the upper atmosphere |
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